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Chemistry of Heterocyclic Compounds

, Volume 54, Issue 10, pp 977–980 | Cite as

Synthesis and halocyclization of 4-methylquinolin-2(1H)-one N- and O-methallyl derivatives

  • Dmitry G. Kim
  • Evgeniya A. VershininaEmail author
  • Irina G. Ovchinnikova
  • Pavel A. Slepukhin
  • Marina A. Ezhikova
  • Mikhail I. Kodess
Article
  • 46 Downloads

The alkylation of 4-methylquinolin-2(1Н)-one with methallyl chloride gave a regioisomer mixture containing 1-methallyl-4-methylquinolin-2(1Н)-one and 2-methallyloxy-4-methylquinoline, which reacted with iodine and bromine and formed dihydrooxazolo[3,2-а]- quinolinium systems.

Keywords

dihydrooxazolo[3,2-а]quinolinium halides methallyl chloride 1-methallyl-4-methylquinolin-2(1Н)-one 2-methallyloxy-4-methylquinoline 4-methylquinolin-2(1Н)-one halocyclization 

Notes

This work was performed with financial support from the government of the Russian Federation (act No. 211 of March 16, 2013, contract No. 02.A03.21.0011) and within the framework of State contract (No. 4.9665.2017/8.9) on the equipment of the Collective Use Center “Spectroscopy and Analysis of Organic Compounds”.

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • Dmitry G. Kim
    • 1
  • Evgeniya A. Vershinina
    • 1
    Email author
  • Irina G. Ovchinnikova
    • 2
  • Pavel A. Slepukhin
    • 2
  • Marina A. Ezhikova
    • 2
  • Mikhail I. Kodess
    • 2
  1. 1.South Ural State University (National Research University)ChelyabinskRussia
  2. 2.I. Ya. Postovsky Institute of Organic SynthesisUral Branch of the Russian Academy of SciencesYkaterinburgRussia

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