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Chemistry of Heterocyclic Compounds

, Volume 54, Issue 6, pp 593–597 | Cite as

ZnO nanorod-catalyzed three-component reaction of euparin, aldehyde, and dialkyl acetylenedicarboxylate: green synthesis of chromene derivatives

  • Fatemeh Sheikholeslami-Farahani
  • Hossein Karami
  • Masoomeh Salimifard
  • Saeid Afshari Sharif Abad
  • Ali Akbar Eslami
Article

New chromene derivatives, 9H-furo[2,3-f]chromene-7,8-dicarboxylates, have been synthesized in high yields by a three-component reaction of euparin (isolated from Petasites hybridus), an aldehyde, and dialkyl acetylenedicarboxylate in the presence of PPh3 and catalytic amount of ZnO nanorods under solvent-free conditions at room temperature. ZnO nanorods showed a strong effect on improving the yield of the desired products. Chromene derivatives can be easily separated from the reaction mixture in a simple work-up, and the catalyst may be recovered and reused without considerable loss of activity.

Keywords

chromene dialkyl acetylenedicarboxylate euparin triphenylphosphine green synthesis solvent-free 

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • Fatemeh Sheikholeslami-Farahani
    • 1
  • Hossein Karami
    • 2
  • Masoomeh Salimifard
    • 2
  • Saeid Afshari Sharif Abad
    • 2
  • Ali Akbar Eslami
    • 2
  1. 1.Department of Chemistry, Firoozkooh BranchIslamic Azad UniversityFiroozkoohIran
  2. 2.Department of Chemistry, Qaemshahr BranchIslamic Azad UniversityQaemshahrIran

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