trans-1,3-Bis(Anthracen-9-Ylmethyl)Octahydro-Benzimidazoles: Synthesis and Study of Spectral Properties
The reaction between (±)-trans-cyclohexane-1,2-diamine and anthracene-9-carbaldehyde with a subsequent reduction of the condensation product gave N,N'-bis(anthracen-9-ylmethyl)cyclohexane-1,2-diamine. The interaction of this diamine with aldehydes was shown to produce octahydrobenz-imidazoles. The chemosensor properties of the obtained compounds were investigated, and a high affinity to Zn2+ cations was identified.
Keywordscyclohexane-1,2-diamine octahydrobenzimidazoles chemosensors cyclization fluorescence
This project received financial support from the Russian Foundation for Basic Research (project 12-03-31375 mol_a) and the Southern Federal University Development Program (project 213.01-24/2013-34).
- 7.I. E. Tolpygin, V. A. Bren, A. D. Dubonosov, V. I. Minkin, and V. P. Rybalkin, Zh. Org. Khim., 39, 1435 (2003). [Rus. J. Org. Chem., 39, 1364 (2003).]Google Scholar
- 8.I. E. Tolpygin, E. N. Shepelenko, Yu. V. Revinskii, A. V. Tsukanov, A. D. Dubonosov, V. A. Bren, and V. I. Minkin, Zh. Org. Khim., 45, 175 (2009). [Rus. J. Org. Chem., 45, 161 (2009).]Google Scholar
- 9.I. E. Tolpygin, Zh. Org. Khim., 48, 109 (2012). [Rus. J. Org. Chem., 48, 104 (2012).]Google Scholar
- 10.I. E. Tolpygin, Yu. V. Revinskii, A. G. Starikov, A. D. Dubonosov, V. A. Bren, and V. I. Minkin, Khim. Geterotsikl. Soedin., 1491 (2011). [Chem. Heterocycl. Compd., 47, 1230 (2012).]Google Scholar