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Chemistry of Heterocyclic Compounds

, Volume 50, Issue 1, pp 41–45 | Cite as

trans-1,3-Bis(Anthracen-9-Ylmethyl)Octahydro-Benzimidazoles: Synthesis and Study of Spectral Properties

  • I. E. Tolpygin
  • K. S. Tihomirova
  • O. S. Popova
  • O. G. Nikolaeva
  • Yu. V. Revinskii
  • A. D. Dubonosov
  • V. A. Bren
Article

The reaction between (±)-trans-cyclohexane-1,2-diamine and anthracene-9-carbaldehyde with a subsequent reduction of the condensation product gave N,N'-bis(anthracen-9-ylmethyl)cyclohexane-1,2-diamine. The interaction of this diamine with aldehydes was shown to produce octahydrobenz-imidazoles. The chemosensor properties of the obtained compounds were investigated, and a high affinity to Zn2+ cations was identified.

Keywords

cyclohexane-1,2-diamine octahydrobenzimidazoles chemosensors cyclization fluorescence 

Notes

This project received financial support from the Russian Foundation for Basic Research (project 12-03-31375 mol_a) and the Southern Federal University Development Program (project 213.01-24/2013-34).

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Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  • I. E. Tolpygin
    • 1
  • K. S. Tihomirova
    • 1
  • O. S. Popova
    • 1
  • O. G. Nikolaeva
    • 1
  • Yu. V. Revinskii
    • 2
  • A. D. Dubonosov
    • 2
  • V. A. Bren
    • 1
  1. 1.Scientific-Research Institute of Physical and Organic ChemistrySouthern Federal UniversityRostov-on-DonRussia
  2. 2.Southern Scientific CenterRussian Academy of SciencesRostov-on-DonRussia

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