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Chemistry of Heterocyclic Compounds

, Volume 48, Issue 7, pp 1098–1104 | Cite as

Sulfenyl halides in the synthesis of heterocycles. 4*. Heterocyclization in reactions of alkenes with sulfenylating reagents based on di(2-pyridyl) disulfide

  • A. V. BorisovEmail author
  • Zh. V. Matsulevich
  • V. K. Osmanov
  • G. N. Borisova
  • G. Z. Mammadova
  • A. M. Maharramov
  • V. N. Khrustalev
Article

Sulfenylating reagents have been obtained by the action of sulfuryl chloride or antimony pentachloride on di(2-pyridyl) disulfide. Their interaction with alkenes proceeds as addition-cyclization with ring closure by the nitrogen atom of the pyridine fragment of the sulfur-containing electrophile with the formation of 2,3-dihydro[1,3]thiazolo[3,2-a]pyridinium derivatives.

Keywords

alkenes di(2-pyridyl) disulfide sulfenyl chlorides heterocyclization 

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Copyright information

© Springer Science+Business Media New York 2012

Authors and Affiliations

  • A. V. Borisov
    • 1
    Email author
  • Zh. V. Matsulevich
    • 1
  • V. K. Osmanov
    • 1
  • G. N. Borisova
    • 1
  • G. Z. Mammadova
    • 2
  • A. M. Maharramov
    • 2
  • V. N. Khrustalev
    • 3
  1. 1.R. E. Aleeksev Nizhny Novgorod State Technical UniversityNizhny NovgorodRussia
  2. 2.Baku State UniversityBakuAzerbaijan
  3. 3.A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of SciencesMoscowRussia

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