Cellulose, due to its low cost, abundance, and biodegradability, has been considered a good choice of support gold nanoparticles (AuNPs). AuNPs based nanomaterials are efficient catalysts for many reactions, including the 4-nitrophenol (4-NP) reduction, which is used in many preparations of chemical and pharmaceutical industries and has toxic effects in living organisms. The cellulose film containing gold nanoparticles was prepared by spin coating a viscous solution of dissolved microcrystalline cellulose in 1-butyl-3-methylimidazolium chloride, followed by regeneration of the cellulose matrix as a film with water addition. Then, the as-prepared film was immersed in an aqueous dispersion of AuNPs, resulting in a red film containing AuNPs with diameters around 10 nm homogeneously dispersed in the polymeric matrix. This film showed great catalytic activity for the reduction of 4-NP to 4-aminophenol using NaBH4, and it was efficient during five cycles. The catalyst prepared in this study has the advantage of being easily isolated from the reaction medium, avoiding processes of centrifugation or filtration for isolation and reuse.
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Ahmed Zelekew O, Kuo DH (2016) A two-oxide nanodiode system made of double-layered p-type Ag2O@n-type TiO2 for rapid reduction of 4-nitrophenol. Phys Chem Chem Phys 18(6):4405–4414. https://doi.org/10.1039/c5cp07320k
Chen M, Kang H, Gong Y, Guo J, Zhang H, Liu R (2015) Bacterial cellulose supported gold nanoparticles with excellent catalytic properties. ACS Appl Mater Interfaces 7(39):21717–21726. https://doi.org/10.1021/acsami.5b07150
Ciolacu D, Ciolacu F, Popa VI (2011) Amorphous cellulose—structure and characterization. Cellul Chem Technol 45:13–21
Corma A, Garcia H (2008) Supported gold nanoparticles as catalysts for organic reactions. Chem Soc Rev 37(9):2096–2126. https://doi.org/10.1039/b707314n
Daniel MCM, Astruc D (2004) Gold nanoparticles: assembly, supramolecular chemistry, quantum-size related properties and applications toward biology. Catal Nanotechnol Chem Rev 104(1):293–346. https://doi.org/10.1021/cr030698
Dong F, Guo W, Park S-K, Ha C-S (2012) Controlled synthesis of novel cyanopropyl polysilsesquioxane hollow spheres loaded with highly dispersed Au nanoparticles for catalytic applications. Chem Commun 48(8):1108–1110. https://doi.org/10.1039/C1CC14831A
Eustis S, El-Sayed MA (2006) Why gold nanoparticles are more precious than pretty gold: Noble metal surface plasmon resonance and its enhancement of the radiative and nonradiative properties of nanocrystals of different shapes. Chem Soc Rev 35(3):209–217. https://doi.org/10.1039/b514191e
Gavillon R, Budtova T (2007) Kinetics of cellulose regeneration from cellulose–NaOH–water gels and comparison with cellulose-N-methylmorpholine-N-oxide-water solutions. Biomacromol 8(2):424–432. https://doi.org/10.1021/bm060376q
Ghosh P, Han G, De M, Kim CK, Rotello VM (2008) Gold nanoparticles in delivery applications. Adv Drug Deliv Rev 60(11):1307–1315. https://doi.org/10.1016/j.addr.2008.03.016
Gu J, Shi J, Xiong L, Chen H, Li L, Ruan M (2004) A new strategy to incorporate high density gold nanowires into the channels of mesoporous silica thin films by electroless deposition. Solid State Sci 6(7):747–752. https://doi.org/10.1016/j.solidstatesciences.2004.03.034
Herreros-López A, Hadad C, Yate L, Alshatwi AA, Vicentini N, Carofiglio T, Prato M (2016) Synthesis and catalytic activity of gold nanoparticles supported on dendrimeric nanocellulose hybrids. Eur J Org Chem 2016(19):3186–3192. https://doi.org/10.1002/ejoc.201600148
Huang X, El-Sayed MA (2010) Gold nanoparticles: optical properties and implementations in cancer diagnosis and photothermal therapy. J Adv Res 1(1):13–28. https://doi.org/10.1016/j.jare.2010.02.002
Kabashin AV, Meunier M (2003) Synthesis of colloidal nanoparticles during femtosecond laser ablation of gold in water. J Appl Phys 94(12):7941–7943. https://doi.org/10.1063/1.1626793
Kaboudin B, Khanmohammadi H, Kazemi F (2017) Polymer supported gold nanoparticles: synthesis and characterization of functionalized polystyrene-supported gold nanoparticles and their application in catalytic oxidation of alcohols in water. Appl Surf Sci 425:400–406. https://doi.org/10.1016/j.apsusc.2017.07.033
Klemm D, Heublein B, Fink HP, Bohn A (2005) Cellulose: fascinating biopolymer and sustainable raw material. Angewandte Chemie Int Ed 44(22):3358–3393. https://doi.org/10.1002/anie.200460587
Lam E, Hrapovic S, Majid E, Chong JH, Luong JHT (2012) Catalysis using gold nanoparticles decorated on nanocrystalline cellulose. Nanoscale 4(3):997. https://doi.org/10.1039/c2nr11558a
Li G, Jin R (2013) Catalysis by gold nanoparticles: carbon–carbon coupling reactions. Nanotechnol Rev 2(5):529–545. https://doi.org/10.1515/ntrev-2013-0020
Li J, Liu CY, Liu Y (2012) Au/graphene hydrogel: Synthesis, characterization and its use for catalytic reduction of 4-nitrophenol. J Mater Chem 22(17):8426–8430. https://doi.org/10.1039/c2jm16386a
Liu Zhiming, Li M, Turyanska L, Makarovsky O, Patanè A, Wu W, Mann S (2010) Self-assembly of electrically conducting biopolymer thin films by cellulose regeneration in gold nanoparticle aqueous dispersions. Chem Mater 22(8):2675–2680. https://doi.org/10.1021/cm1001863
Liu Zhen, Wang H, Li Z, Lu X, Zhang X, Zhang S, Zhou K (2011) Characterization of the regenerated cellulose films in ionic liquids and rheological properties of the solutions. Mater Chem Phys 128(1–2):220–227. https://doi.org/10.1016/j.matchemphys.2011.02.062
McFarland AD, Haynes CL, Mirkin CA, Van Duyne RP, Godwin HA (2004) Color My nanoworld. J Chem Educ 81(4):544A. https://doi.org/10.1021/ed081p544A
Niu T, Xu J, Xiao W, Huang J (2014) Cellulose-based catalytic membranes fabricated by deposition of gold nanoparticles on natural cellulose nanofibres. RSC Adv 4(10):4901–4904. https://doi.org/10.1039/c3ra44622k
Pang J, Wu M, Zhang Q, Tan X, Xu F, Zhang X, Sun R (2015) Comparison of physical properties of regenerated cellulose films fabricated with different cellulose feedstocks in ionic liquid. Carbohyd Polym 121:71–78. https://doi.org/10.1016/j.carbpol.2014.11.067
Park ED, Lee JS (1999) Effects of pretreatment conditions on CO oxidation over supported Au catalysts. J Catal 186(1):1–11. https://doi.org/10.1006/jcat.1999.2531
Pissuwan D, Valenzuela SM, Cortie MB (2006) Therapeutic possibilities of plasmonically heated gold nanoparticles. Trends Biotechnol 24(2):62–67. https://doi.org/10.1016/j.tibtech.2005.12.004
Saha S, Pal A, Kundu S, Basu S, Pal T (2010) Photochemical green synthesis of calcium-alginate-stabilized ag and au nanoparticles and their catalytic application to 4-nitrophenol reduction. Langmuir 26(4):2885–2893. https://doi.org/10.1021/la902950x
Wilkes JS, Levisky JA, Wilson RA, Hussey CL (1982) Dialkylimidazolium. Encycl Lubr Lubr 237(1980):374. https://doi.org/10.1007/978-3-642-22647-2_100172
Wu X, Lu C, Zhou Z, Yuan G, Xiong R, Zhang X (2014) Green synthesis and formation mechanism of cellulose nanocrystal-supported gold nanoparticles with enhanced catalytic performance. Environ Sci Nano 1(1):71–79. https://doi.org/10.1039/c3en00066d
Zhang L, Ruan D, Zhou J (2001) Structure and properties of regenerated cellulose films prepared from cotton linters in NaOH/urea aqueous solution. Ind Eng Chem Res 40:5923–5928. https://doi.org/10.1021/ie0010417
Zhang H, Fei C, Zhang D, Tang F (2007) Degradation of 4-nitrophenol in aqueous medium by electro-Fenton method. J Hazard Mater 145(1–2):227–232. https://doi.org/10.1016/j.jhazmat.2006.11.016
Zhang Z, Shao C, Zou P, Zhang P, Zhang M, Mu J et al (2011) In situ assembly of well-dispersed gold nanoparticles on electrospun silica nanotubes for catalytic reduction of 4-nitrophenol. Chem Commun 47(13):3906–3908. https://doi.org/10.1039/c0cc05693f
Zhu S, Wu Y, Chen Q, Yu Z, Wang C, Jin S et al (2006) Dissolution of cellulose with ionic liquids and its application: a mini-review. Green Chem 8(4):325–327. https://doi.org/10.1039/b601395c
Zhu J, Shen Y, Xie A, Qiu L, Zhang Q, Zhang S (2007) Photoinduced synthesis of anisotropic gold nanoparticles in room-temperature ionic liquid. J Phys Chem C 111(21):7629–7633. https://doi.org/10.1021/jp0711850
This study was financed in part by the Coordenação de Aperfeiçoamento de Pessoal de Nível Superior—Brasil (CAPES)—Finance Code 001. The authors gratefully acknowledge the financial support from FAPESP (Grant Number 2018/20826-4), professor Vera Constantino (IQ-USP) for the use of the Zeta potential equipment and Brazilian Nanotechnology National Laboratory (LNNano) for the XPS experiments (Project Number XPS - 24897).
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Cabreira, C.R., Camilo, F.F. Evaluation of catalytic activity of cellulose films decorated with gold nanoparticles in the reduction of 4-nitrophenol. Cellulose (2020). https://doi.org/10.1007/s10570-020-03049-1
- Regenerated cellulose films
- Gold nanoparticles