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Cellulose

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Construction of functional composite films originating from hemicellulose reinforced with poly(vinyl alcohol) and nano-ZnO

  • Xueqin ZhangEmail author
  • Wenhan Luo
  • Naiyu Xiao
  • Mingjie Chen
  • Chuanfu LiuEmail author
Original Research
  • 23 Downloads

Abstract

The aim of this study is to prepare functional hemicellulose (HC) films with flexibility, thermoplasticity and UV-shielding ability. HC was firstly esterified with vinyl benzoate and then reinforced with poly(vinyl alcohol) (PVA) and nano-zinc oxide (ZnO). After esterification, the solubility of benzoated HC (BH) increased, while the thermal stability decreased. Moreover, esterification could transform HC into crystalline nature and endow HC with tunable transition temperature (Tg). Adding equivalent mass of PVA and 1% ZnO increased the thermal stability of BH/PVA/ZnO films. XRD and DSC analyses showed the new crystalline structure and the decreased Tg of films, probably due to the interactions among BH, PVA and ZnO. From SEM, the cross sections of films were dense, rough, and were connected to form the network structure, promoting the uniform insertion of ZnO into the matrix. The films showed moderate tensile strength and good flexibility with the maximum elongation at break of 87.18%. In addition, the water vapor permeability (WVP) and oxygen permeability (OP) values of BH/PVA/ZnO film were 2.08 × 10−10 g/m s Pa and 0.95 cm3 μm/m2 d kPa, respectively. Moreover, the film with 1% ZnO exhibited excellent UV-shielding properties with the percentage blocking of UV-A and UV-B of 99.34% and 99.99%, respectively.

Graphic abstract

Keywords

Hemicellulose Poly(vinyl alcohol) Nano-ZnO Chemical modification Functional film 

Notes

Acknowledgments

This work was supported by the Fundamental Research Funds from the Zhongkai University of Agriculture and Engineering (KA190577803, KA190577806), the National Natural Science Foundation of China (31600477) and the Science and Technology Program of Guangzhou, China (201804010145).

Supplementary material

10570_2019_2878_MOESM1_ESM.docx (2.1 mb)
Supplementary material 1 (DOCX 2169 kb)

References

  1. Abdollahi M, Bigdeli P (2018) Reverse iodine transfer radical copolymerization of vinyl acetate and vinyl benzoate: a kinetic study. Polym Bull 75:1823–1841.  https://doi.org/10.1007/s00289-017-2130-z CrossRefGoogle Scholar
  2. Awan F, Islam MS, Ma YY, Yang C, Shi ZQ, Berry RM, Tam KC (2018) Cellulose nanocrystal–ZnO nanohybrids for controlling photocatalytic activity and UV protection in cosmetic formulation. ACS Omega 3:12403–12411.  https://doi.org/10.1021/acsomega.8b01881 CrossRefPubMedPubMedCentralGoogle Scholar
  3. Belmokaddem F-Z, Pinel C, Huber P, Petit-Conil M, Da Silva Perez D (2011) Green synthesis of xylan hemicellulose esters. Carbohydr Res 346:2896–2904.  https://doi.org/10.1016/j.carres.2011.10.012 CrossRefPubMedGoogle Scholar
  4. Cazón P, Velazquez G, Ramírez JA, Vázquez M (2017) Polysaccharide-based films and coatings for food packaging: a review. Food Hydrocolloid 68:136–148.  https://doi.org/10.1016/j.foodhyd.2016.09.009 CrossRefGoogle Scholar
  5. Cazón P, Vázquez M, Velazquez G (2019) Composite films with UV-barrier properties based on bacterial cellulose combined with chitosan and poly(vinyl alcohol): study of puncture and water interaction properties. Biomacromol 20:2084–2095.  https://doi.org/10.1021/acs.biomac.9b00317 CrossRefGoogle Scholar
  6. Chen MJ, Li RM, Zhang XQ, Feng J, Feng J, Liu CF, Shi QS (2017) Homogeneous transesterification of sugar cane bagasse toward sustainable plastics. ACS Sustain Chem Eng 5:360–366.  https://doi.org/10.1021/acssuschemeng.6b01735 CrossRefGoogle Scholar
  7. Farhat W et al (2018) Towards thermoplastic hemicellulose: chemistry and characteristics of poly-(ε-caprolactone) grafting onto hemicellulose backbones. Mater Des 153:298–307.  https://doi.org/10.1016/j.matdes.2018.05.013 CrossRefGoogle Scholar
  8. Fortunati E, Puglia D, Luzi F, Santulli C, Kenny JM, Torre L (2013) Binary PVA bio-nanocomposites containing cellulose nanocrystals extracted from different natural sources: Part I. Carbohydr Polym 97:825–836.  https://doi.org/10.1016/j.carbpol.2013.03.075 CrossRefPubMedGoogle Scholar
  9. Fu FY, Li LY, Liu LJ, Cai J, Zhang YP, Zhou JP, Zhang LN (2015) Construction of cellulose based ZnO nanocomposite films with antibacterial properties through one-step coagulation. ACS Appl Mater Interfaces 7:2597–2606.  https://doi.org/10.1021/am507639b CrossRefPubMedGoogle Scholar
  10. Fundador NGV, Enomoto-Rogers Y, Takemura A, Iwata T (2012a) Acetylation and characterization of xylan from hardwood kraft pulp. Carbohydr Polym 87:170–176.  https://doi.org/10.1016/j.carbpol.2011.07.034 CrossRefGoogle Scholar
  11. Fundador NGV, Enomoto-Rogers Y, Takemura A, Iwata T (2012b) Syntheses and characterization of xylan esters. Polymer 53:3885–3893.  https://doi.org/10.1016/j.polymer.2012.06.038 CrossRefGoogle Scholar
  12. Goksu EI, Karamanlioglu M, Bakir U, Yilmaz L, Yilmazer U (2007) Production and characterization of films from cotton stalk xylan. J Agric Food Chem 55:10685–10691.  https://doi.org/10.1021/jf071893i CrossRefPubMedGoogle Scholar
  13. Guo HB, He F, Gu B, Liang LY, Smith JC (2012) Time-dependent density functional theory assessment of UV absorption of benzoic acid derivatives. J Phys Chem A 116:11870–11879.  https://doi.org/10.1021/jp3084293 CrossRefPubMedGoogle Scholar
  14. Hameed N, Xiong R, Salim NV, Guo Q (2013) Fabrication and characterization of transparent and biodegradable cellulose/poly (vinyl alcohol) blend films using an ionic liquid. Cellulose 20:2517–2527.  https://doi.org/10.1007/s10570-013-0017-1 CrossRefGoogle Scholar
  15. Hansen NML, Plackett D (2008) Sustainable films and coatings from hemicelluloses: a review. Biomacromol 9:1493–1505.  https://doi.org/10.1021/bm800053z CrossRefGoogle Scholar
  16. Hinner LP, Wissner JL, Beurer A, Nebel BA, Hauer B (2016) Homogeneous vinyl ester-based synthesis of different cellulose derivatives in 1-ethyl-3-methyl-imidazolium acetate. Green Chem 18:6099–6107.  https://doi.org/10.1039/C6GC02005D CrossRefGoogle Scholar
  17. Ibn Yaich A, Edlund U, Albertsson A-C (2017) Transfer of biomatrix/wood cell interactions to hemicellulose-based materials to control water interaction. Chem Rev 117:8177–8207.  https://doi.org/10.1021/acs.chemrev.6b00841 CrossRefPubMedGoogle Scholar
  18. Indumathi MP, Saral Sarojini K, Rajarajeswari GR (2019) Antimicrobial and biodegradable chitosan/cellulose acetate phthalate/ZnO nano composite films with optimal oxygen permeability and hydrophobicity for extending the shelf life of black grape fruits. Int J Biol Macromol 132:1112–1120.  https://doi.org/10.1016/j.ijbiomac.2019.03.171 CrossRefPubMedGoogle Scholar
  19. Kačuráková M, Capek P, Sasinková V, Wellner N, Ebringerová A (2000) FT-IR study of plant cell wall model compounds: pectic polysaccharides and hemicelluloses. Carbohydr Polym 43:195–203.  https://doi.org/10.1016/S0144-8617(00)00151-X CrossRefGoogle Scholar
  20. Kakuchi R et al (2015) Efficient and rapid direct transesterification reactions of cellulose with isopropenyl acetate in ionic liquids. RSC Adv 5:72071–72074.  https://doi.org/10.1039/C5RA14408F CrossRefGoogle Scholar
  21. Kanmani P, Rhim JW (2014) Properties and characterization of bionanocomposite films preprared with various biopolymers and ZnO nanoparticles. Carbohydr Polym 106:190–199.  https://doi.org/10.1016/j.carbpol.2014.02.007 CrossRefPubMedGoogle Scholar
  22. Kurek M, Garofulic IE, Bakic MT, Scetar M, Uzelac VD, Galic K (2018) Development and evaluation of a novel antioxidant and pH indicator film based on chitosan and food waste sources of antioxidants. Food Hydrocolloid 84:238–246.  https://doi.org/10.1016/j.foodhyd.2018.05.050 CrossRefGoogle Scholar
  23. Labafzadeh SR, Helminen KJ, Kilpeläinen I, King AWT (2015) Synthesis of cellulose methylcarbonate in ionic liquid using dimethylcarhonate. Chemsuschem 8:77–81.  https://doi.org/10.1002/cssc.201402794 CrossRefPubMedGoogle Scholar
  24. Liu R et al (2019) Preparation of polyacrylic acid-grafted-acryloyl/hemicellulose (PAA-g-AH) hybrid films with high oxygen barrier performance. Carbohydr Polym 205:83–88.  https://doi.org/10.1016/j.carbpol.2018.10.031 CrossRefPubMedGoogle Scholar
  25. Lizundia E, Urruchi A, Vilas JL, León LM (2016) Increased functional properties and thermal stability of flexible cellulose nanocrystal/ZnO films. Carbohydr Polym 136:250–258.  https://doi.org/10.1016/j.carbpol.2015.09.041 CrossRefPubMedGoogle Scholar
  26. Mittal A, Garg S, Kohli D, Maiti M, Jana AK, Bajpai S (2016) Effect of cross linking of PVA/starch and reinforcement of modified barley husk on the properties of composite films. Carbohydr Polym 151:926–938.  https://doi.org/10.1016/j.carbpol.2016.06.037 CrossRefPubMedGoogle Scholar
  27. Mohanty AK, Misra M, Drzal LT (2002) Sustainable bio-composites from renewable resources: opportunities and challenges in the green materials world. J Polym Environ 10:19–26.  https://doi.org/10.1023/a:1021013921916 CrossRefGoogle Scholar
  28. Mun S, Kim HC, Ko H-U, Zhai LD, Kim JW, Kim J (2017) Flexible cellulose and ZnO hybrid nanocomposite and its UV sensing characteristics. Sci Technol Adv Mater 18:437–446.  https://doi.org/10.1080/14686996.2017.1336642 CrossRefPubMedPubMedCentralGoogle Scholar
  29. Niu X, Liu YT, Fang GG, Huang CB, Rojas OJ, Pan H (2018) Highly transparent, strong, and flexible films with modified cellulose nanofiber bearing UV shielding property. Biomacromol 19:4565–4575.  https://doi.org/10.1021/acs.biomac.8b01252 CrossRefGoogle Scholar
  30. Onwukamike KN, Grelier S, Grau E, Cramail H, Meier MAR (2018) Sustainable transesterification of cellulose with high oleic sunflower oil in a DBU-CO2 switchable solvent. ACS Sustain Chem Eng 6:8826–8835.  https://doi.org/10.1021/acssuschemeng.8b01186 CrossRefGoogle Scholar
  31. Pan JQ, Zhang XF, Zhao C, Xie SK, Zheng YY, Cui C, Li CR (2018) The flexible-transparent photosensitive films of cotton cellulose framework of carbon quantum dots/ZnO. Mater Lett 211:289–292.  https://doi.org/10.1016/j.matlet.2017.10.005 CrossRefGoogle Scholar
  32. Pereira PHF et al (2017) Wheat straw hemicelluloses added with cellulose nanocrystals and citric acid: effect on film physical properties. Carbohydr Polym 164:317–324.  https://doi.org/10.1016/j.carbpol.2017.02.019 CrossRefPubMedGoogle Scholar
  33. Petzold-Welcke K, Schwikal K, Daus S, Heinze T (2014) Xylan derivatives and their application potential: mini-review of own results. Carbohydr Polym 100:80–88.  https://doi.org/10.1016/j.carbpol.2012.11.052 CrossRefPubMedGoogle Scholar
  34. Roy HS, Mollah MYA, Islam MM, Susan MABH (2018) Poly(vinyl alcohol)–MnO2 nanocomposite films as UV-shielding materials. Polym Bull 75:5629–5643.  https://doi.org/10.1007/s00289-018-2355-5 CrossRefGoogle Scholar
  35. Sambandan DR, Rather D (2011) Sunscreen: an overview and update. J Am Acad Dermatol 64:748–758.  https://doi.org/10.1016/j.jaad.2010.01.005 CrossRefPubMedGoogle Scholar
  36. Scheller HV, Ulvskov P (2010) Hemicelluloses. Annu Rev Plant Biol 61:263–289.  https://doi.org/10.1146/annurev-arplant-042809-112315 CrossRefPubMedPubMedCentralGoogle Scholar
  37. Tsuchiya Y, Sumi K (1969) Thermal decomposition products of poly(vinyl alcohol). J Polym Sci Pol Chem 7:3151–3158.  https://doi.org/10.1002/pol.1969.150070302 CrossRefGoogle Scholar
  38. Vicente G, Martinez M, Aracil J (2004) Integrated biodiesel production: a comparison of different homogeneous catalysts systems. Bioresour Technol 92:297–305CrossRefGoogle Scholar
  39. Wang Y et al (2017) A novel UV-shielding and transparent polymer film: when bioinspired dopamine–melanin hollow nanoparticles join polymers. ACS Appl Mater Interfaces 9:36281–36289.  https://doi.org/10.1021/acsami.7b08763 CrossRefPubMedGoogle Scholar
  40. Xie WQ, Yu KX, Gong YX (2019) Preparation of fluorescent and antibacterial nanocomposite films based on cellulose nanocrystals/ZnS quantum dots/polyvinyl alcohol. Cellulose 26:2363–2373.  https://doi.org/10.1007/s10570-019-02245-y CrossRefGoogle Scholar
  41. Yu Z, Li BQ, Chu JY, Zhang PF (2018) Silica in situ enhanced PVA/chitosan biodegradable films for food packages. Carbohydr Polym 184:214–220.  https://doi.org/10.1016/j.carbpol.2017.12.043 CrossRefPubMedGoogle Scholar
  42. Yu J et al (2019) Contribution of hemicellulose to cellulose nanofiber-based nanocomposite films with enhanced strength, flexibility and UV-blocking properties. Cellulose 26:6023–6034.  https://doi.org/10.1007/s10570-019-02518-6 CrossRefGoogle Scholar
  43. Zhang JM, Wu J, Cao Y, Sang SM, Zhang J, He JS (2009) Synthesis of cellulose benzoates under homogeneous conditions in an ionic liquid. Cellulose 16:299–308.  https://doi.org/10.1007/s10570-008-9260-2 CrossRefGoogle Scholar
  44. Zhang XQ, Chen MJ, Liu CF, Sun RC (2014) Dual-component system dimethyl sulfoxide/LiCl as a solvent and catalyst for homogeneous ring-opening grafted polymerization of ε-caprolactone onto xylan. J Agric Food Chem 62:682–690.  https://doi.org/10.1021/jf4036047 CrossRefPubMedGoogle Scholar
  45. Zhang XQ, Zhang AP, Liu CF, Ren JL (2016) Per-O-acylation of xylan at room temperature in dimethylsulfoxide/N-methylimidazole. Cellulose 23:2863–2876.  https://doi.org/10.1007/s10570-016-0997-8 CrossRefGoogle Scholar
  46. Zhang XQ, Liu CF, Zhang AP, Sun RC (2018) Synergistic effects of graft polymerization and polymer blending on the flexibility of xylan-based films. Carbohydr Polym 181:1128–1135.  https://doi.org/10.1016/j.carbpol.2017.11.025 CrossRefPubMedGoogle Scholar

Copyright information

© Springer Nature B.V. 2019

Authors and Affiliations

  1. 1.College of Light Industry and Food ScienceZhongkai University of Agriculture and EngineeringGuangzhouChina
  2. 2.State Key Laboratory of Applied Microbiology Southern China, Guangdong Provincial Key Laboratory of Microbial Culture Collection and ApplicationGuangdong Institute of MicrobiologyGuangzhouChina
  3. 3.State Key Laboratory of Pulp and Paper EngineeringSouth China University of TechnologyGuangzhouChina

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