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Cellulose

, Volume 27, Issue 1, pp 441–453 | Cite as

Bio-based i-carrageenan aerogels as efficient adsorbents for heavy metal ions and acid dye from aqueous solution

  • Faten Hassan Hassan Abdellatif
  • Mohamed Mehawed AbdellatifEmail author
Original Research
  • 57 Downloads

Abstract

Iota-Carrageenan (i-carrageenan) was cross-linked with Polyamidoamine hyperbranched polymer generation 1 (PAMAM). The resulted hydrogels were dried using freeze-drying technique to give new bio-based i-carrageenan aerogels. These aerogels were characterized using FT-IR and their nitrogen contents were determined using Kjeldahl method. The morphology and the surface areas of the aerogels were investigated using scanning electron microscope and Brunauer–Emmett–Teller method, respectively. The ability of the aerogels to remediate different metal ions e.g. Cr(VI), Mn(II), Co(II), Cu(II), or Cd(II) and alphanol fast blue dye (acid dye) from aqueous medium was carefully investigated. The removal investigation was conducted without pH adjustment in case of metal ions and at pH 2 for acid dye. The aerogel with the higher nitrogen content (CAR4) exhibited the highest remediation efficiency of both metal ions and acid dye.

Keywords

Iota-Carrageenan Polyamidoamine Aerogels Heavy metal ions removal Acidic dye Cross-linking 

Notes

References

  1. Abdellatif FHH, Babin J, Arnal-Herault C, David L, Jonquieres A (2016) Grafting of cellulose acetate with ionic liquids for biofuel purification by a membrane process: influence of the cation. Carbohydr Polym 147:313–322.  https://doi.org/10.1016/j.carbpol.2016.04.008 CrossRefGoogle Scholar
  2. Abdellatif FHH, Babin J, Arnal-Herault C, David L, Jonquieres A (2018) Grafting cellulose acetate with ionic liquids for biofuel purification membranes: influence of the anion. Carbohydr Polym 196:176–186.  https://doi.org/10.1016/j.carbpol.2018.05.008 CrossRefGoogle Scholar
  3. Abo-Shosha MH, Fahmy HM, Hassan FH, Ashour AM, Khalil AA (2009) Tetracycline hydrate and gentamicine sulfate containing carboxymethylated cotton fabric suitable for moist wound healing dressings: properties and evaluation. J Ind Text 38:341–360.  https://doi.org/10.1177/1528083708098911 CrossRefGoogle Scholar
  4. Adams CI, Spaulding GH (1955) Determination of organic nitrogen by Kjeldahl method without distillation. Anal Chem 27:1003–1004.  https://doi.org/10.1021/ac60102a040 CrossRefGoogle Scholar
  5. Ahmed HM, Abdellatif MM, Ibrahim S, Abdellatif FHH (2019) Mini-emulsified copolymer/silica nanocomposite as effective binder and self-cleaning for textiles coating. Prog Org Coat 129:52–58.  https://doi.org/10.1016/j.porgcoat.2019.01.002 CrossRefGoogle Scholar
  6. Alnaief M, Obaidat R, Mashaqbeh H (2018) Effect of processing parameters on preparation of carrageenan aerogel microparticles. Carbohydr Polym 180:264–275.  https://doi.org/10.1016/j.carbpol.2017.10.038 CrossRefPubMedGoogle Scholar
  7. Al-Qahtani KM (2016) Water purification using different waste fruit cortexes for the removal of heavy metals. J Taibah Univ Med Sci 10:700–708.  https://doi.org/10.1016/j.jtusci.2015.09.001 CrossRefGoogle Scholar
  8. Bakarich SE, Balding P, Gorkin Iii R, Spinks GM (2014) Printed ionic-covalent entanglement hydrogels from carrageenan and an epoxy amine. RSC Adv 4:38088–38092.  https://doi.org/10.1039/c4ra07109c CrossRefGoogle Scholar
  9. Brunauer S, Emmett PH, Teller E (1938) Adsorption of gases in multimolecular layers. J Am Chem Soc 60:309–319CrossRefGoogle Scholar
  10. Chaisuwan T, Komalwanich T, Luangsukrerk S, Wongkasemjit S (2010) Removal of heavy metals from model wastewater by using polybenzoxazine aerogel. Desalination 256:108–114.  https://doi.org/10.1016/j.desal.2010.02.005 CrossRefGoogle Scholar
  11. Chen H, Wang X, Li J, Wang X (2015) Cotton derived carbonaceous aerogels for the efficient removal of organic pollutants and heavy metal ions. J Mater Chem A 3:6073–6081.  https://doi.org/10.1039/c5ta00299k CrossRefGoogle Scholar
  12. Das I, Borah JH, Sarma D, Hazarika S (2018) Synthesis of PAMAM dendrimer and its derivative PAMOL: determination of thermophysical properties by DFT. J Macromol Sci A 55:544–551CrossRefGoogle Scholar
  13. Demirkiran N (2015) Copper adsorption by natural manganese dioxide. Trans Nonferrous Met Soc China 25:647–653CrossRefGoogle Scholar
  14. Dodangeh M, Yousefi N, Mohammadian M (2015) Synthesis and functionalization of polyamidoamine dendrimers with thiazol derivatives to prepare novel disperse dyes and their application on polyethylene terephthalate (PET). Dyes Pigm 116:20–26CrossRefGoogle Scholar
  15. Ebisike K, Okoronkwo AE, Alaneme KK (2019) Adsorption of Cd (II) on chitosan–silica hybrid aerogel from aqueous solution. Environ Technol Innov 14:100337.  https://doi.org/10.1016/j.eti.2019.100337 CrossRefGoogle Scholar
  16. Fu F, Wang Q (2011) Removal of heavy metal ions from wastewaters: a review. J Environ Manag 92:407–418.  https://doi.org/10.1016/j.jenvman.2010.11.011 CrossRefGoogle Scholar
  17. García-González CA, Alnaief M, Smirnova I (2011) Polysaccharide-based aerogels—promising biodegradable carriers for drug delivery systems. Carbohydr Polym 86:1425–1438.  https://doi.org/10.1016/j.carbpol.2011.06.066 CrossRefGoogle Scholar
  18. Gregg SJ, Wing KSW, Salzberg HW (1967) Adsorption surface area and porosity. J Electrochem Soc 114:279CCrossRefGoogle Scholar
  19. Ibrahim NA, Eid BM, Abdellatif FHH (2018) Advanced materials and technologies for antimicrobial finishing of cellulosic textiles. In: Handbook of Renewable Materials for Coloration and Finishing. Wiley, Scrivener Publishing LLC, pp 303–356.  https://doi.org/10.1002/9781119407850.ch13.CrossRefGoogle Scholar
  20. Lei C et al (2019) Fabrication of metal–organic frameworks@cellulose aerogels composite materials for removal of heavy metal ions in water. Carbohydr Polym 205:35–41.  https://doi.org/10.1016/j.carbpol.2018.10.029 CrossRefPubMedGoogle Scholar
  21. Li D, Yang D, Wang Y, Guo Z, Xia Y, Sun S, Guo S (2016) Double-Helix structure in carrageenan–metal hydrogels: a general approach to porous metal sulfides/carbon aerogels with excellent sodium-ion storage angew. Chem Int Ed 55:15925–15928.  https://doi.org/10.1002/anie.201610301 CrossRefGoogle Scholar
  22. Li D, Jia Y, Chang G, Chen J, Liu H, Wang J, Hu Y, Xia Y, Yong D, Yao X (2018a) A defect-driven metal-free electrocatalyst for oxygen reduction in acidic electrolyte. Chem 4:2345–2356CrossRefGoogle Scholar
  23. Li J, Zuo K, Wu W, Xu Z, Yi Y, Jing Y, Dai H, Fang G (2018b) Shape memory aerogels from nanocellulose and polyethyleneimine as a novel adsorbent for removal of Cu(II) and Pb(II). Carbohydr Polym 196:376–384.  https://doi.org/10.1016/j.carbpol.2018.05.015 CrossRefPubMedGoogle Scholar
  24. Li D, Chang G, Zong L, Xue P, Wang Y, Xia Y, Lai C, Yong D (2019) From double-helix structured seaweed to S-doped carbon aerogel with ultra-high surface area for energy storage. Energy Storage Mater 17:22–30CrossRefGoogle Scholar
  25. Mikkonen KS, Parikka K, Ghafar A, Tenkanen M (2013) Prospects of polysaccharide aerogels as modern advanced food materials. Trends Food Sci Technol 34:124–136.  https://doi.org/10.1016/j.tifs.2013.10.00 CrossRefGoogle Scholar
  26. Nada AA, Abdellatif FHH, Ali EA, Abdelazeem RA, Soliman AAS, Abou-Zeid NY (2018) Cellulose-based click-scaffolds: synthesis, characterization and biofabrications. Carbohydr Polym 199:610–618.  https://doi.org/10.1016/j.carbpol.2018.07.049 CrossRefPubMedGoogle Scholar
  27. Tkalec G, Knez Ž, Novak Z (2015) Formation of polysaccharide aerogels in ethanol. RSC Adv 5:77362–77371.  https://doi.org/10.1039/c5ra14140k CrossRefGoogle Scholar
  28. Yingnakhon W, Srikulkit K (2013) A simple quaternization method of hyperbranched polyamidoamine polymer and antimicrobial activity evaluation of cationic hyperbranched polyamidoamine polymer. Asian J Chem 25:4009–4012CrossRefGoogle Scholar

Copyright information

© Springer Nature B.V. 2019

Authors and Affiliations

  • Faten Hassan Hassan Abdellatif
    • 1
  • Mohamed Mehawed Abdellatif
    • 2
    Email author
  1. 1.Pretreatment and Finishing of Cellulosic Fibers, Textile Research DivisionNational Research CentreDokki-GizaEgypt
  2. 2.Chemical Industries Division, Chemistry of Tanning Materials and Leather TechnologyNational Research CentreDokki-GizaEgypt

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