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Cellulose

, Volume 26, Issue 16, pp 8745–8757 | Cite as

Fabrication of sandwich-structured cellulose composite membranes for switchable infrared radiation

  • Bin Gu
  • Kaifeng Liang
  • Tao ZhangEmail author
  • Xuejie Yue
  • Fengxian Qiu
  • Dongya YangEmail author
  • Mingming Chen
Original Research
  • 93 Downloads

Abstract

Developing a feasible and efficient biomass-based membrane for energy-saving applications is critical for addressing greenhouse effect and energy crises. Herein, a sandwich-structured cellulose composite membrane with controllable thermal management properties was fabricated via the assembly of Ag nanoparticles/cellulose (ANPs/C), ultralong MnO2 nanowires (UMNWs), and MnO2 nanosheets/cellulose (MNSs/C). In this strategy, the UMNWs as building blocks were prepared by hydrothermal method. Then, the ANPs/C and MNSs/C were fabricated via magnetron sputtering and in situ growth method, respectively. Finally, the cellulose composite membrane (CCM) was fabricated via vacuum-filtration of cotton cellulose (CC), UMNWs and MNSs/C suspension, and subsequently the CC surfaces were covered with the ANPs by magnetron sputtering. The sandwich-structured CCM exhibits Janus infrared radiation properties due the asymmetrical surface structure and chemical compositions. The ANPs layer has high infrared reflectivity of 91.6%, however, the MNSs/C layer shows the low infrared reflectivity with 62.7%. The results indicate that the Janus sandwich CCM not only can efficiently reflect infrared heat back toward the body, in order to achieve highly thermal insulating under low temperature environment, but also can achieve highly passive cooling under high temperature environment. In addition, the CCM exhibits excellent antibacterial properties due to presence of ANPs, which is beneficial to enhance the lifespan of the personal thermal management membrane. The present work may give some insight to prepare sandwich-structured membranes with controllable thermal management properties for application in wearable textiles.

Graphic abstract

Keywords

Cellulose membrane Thermal management Thermal insulating Passive cooling Antibacterial properties 

Notes

Acknowledgments

This work was financially supported by National Natural Science Foundation of China (21706100 and 21878132), Natural Science Foundation of Jiangsu Province (BK20160500, BK20161362 and BK20160491), State Key Laboratory of Pollution Control and Resource Reuse Foundation (No. PCRRF18003), Scientific Research Foundation for Advanced Talents, Jiangsu University (15JDG142), Youth Talent Cultivation Program of Jiangsu University, High-Level Personnel Training Project of Jiangsu Province (BRA2016142), Natural Science Foundation of Hebei Province (B2019108017) and Society Development Fund of Zhenjiang (SH2018009).

Supplementary material

10570_2019_2653_MOESM1_ESM.docx (1.7 mb)
Supplementary material 1 (DOCX 1762 kb)

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Copyright information

© Springer Nature B.V. 2019

Authors and Affiliations

  1. 1.School of Chemistry and Chemical EngineeringJiangsu UniversityZhenjiangChina
  2. 2.Institute of Green Chemistry and Chemical TechnologyJiangsu UniversityZhenjiangChina
  3. 3.Department of PhysicsJiangsu UniversityZhenjiangChina

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