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Cellulose

, Volume 26, Issue 6, pp 4175–4190 | Cite as

Functionalized nanofibrous coating on cotton fabrics

  • Olga Gavrilenko
  • Xin WangEmail author
Original Research
  • 96 Downloads

Abstract

A nanofibrous polyurethane coating was achieved by direct electrospinning of nanofibers onto the surface of padded fabrics followed by functionalisation with a water/oil repellent. As a comparison, a conventional knife method was also applied to coat the polyurethane onto the padded cotton fabrics. The obtained coated fabrics were examined by SEM, FTIR, and for thickness, water contact angle and air permeability. It was found that an interconnected nanofibrous structure has formed over the surface cotton fibers due to the binder’s effect. The nanofibrous coating on the surface of cotton fabrics brings in enhanced hydrophobicity with better permeability than the knife coated bulky membrane. The generation of a nanofibrous surface on textiles provides a platform for tailoring the surface with multiple functions towards next generation performance textiles.

Keywords

Cotton Nanofibrous coating Electrospinning Water contact angle 

Notes

Acknowledgments

The research was funded by the Cotton Research and Development Corporation (Grant No. RMIT1702). The authors acknowledge the facilities, and the scientific and technical assistance of Microscopy & Microanalysis Research Facility at RMIT University.

References

  1. Ahn HW, Park CH, Chung SE (2010) Waterproof and breathable properties of nanoweb applied clothing. Text Res J 81:1438–1447.  https://doi.org/10.1177/0040517510392462 Google Scholar
  2. Chen L, Bromberg L, Schreuder-Gibson H, Walker J, Hatton TA, Rutledge GC (2009) Chemical protection fabrics via surface oximation of electrospun polyacrylonitrile fiber mats. J Mater Chem 19:2432–2438.  https://doi.org/10.1039/B818639A CrossRefGoogle Scholar
  3. Faccini M, Vaquero C, Amantia D (2012) Development of protective clothing against nanoparticle based on electrospun nanofibers. J Nanomater.  https://doi.org/10.1155/2012/892894 Google Scholar
  4. Gibson P, Schreuder-Gibson H, Rivin D (2001) Transport properties of porous membranes based on electrospun nanofibers. Colloid Surf A 187–188:469–481.  https://doi.org/10.1016/S0927-7757(01)00616-1 CrossRefGoogle Scholar
  5. Gorji M, Bagherzadeh R, Fashandi H (2017) Electrospun nanofibers in protective clothing. In: Afshari M (ed) Electrospun nanofibers, 1st edn. Woodhead Publishing, Cambridge, pp 571–598CrossRefGoogle Scholar
  6. Graham K, Gogins M, Schreuder-Gibson H (2003) Incorporation of electrospun nanofibers into functional structures. In: International nonwovens technical conference, Baltimore, MarylandGoogle Scholar
  7. Greiner A, Wendorff JH (2007) Electrospinning: a fascinating method for the preparation of ultrathin fibers. Angew Chem Int Edit 46:5670–5703.  https://doi.org/10.1002/anie.200604646 CrossRefGoogle Scholar
  8. Hearle JWS (2007) Physical structure and properties of cotton. In: Gordon S, Hsieh YL (eds) Cotton. Woodhead Publishing, Cambridge, pp 35–67CrossRefGoogle Scholar
  9. Heikkilae P, Sipilae A, Peltola M, Harlin A, Taipale A (2007) Electrospun PA-66 coating on textile surfaces. Text Res J 77:864–870.  https://doi.org/10.1177/0040517507078241 CrossRefGoogle Scholar
  10. Hong KA, Yoo HS, Kim E (2014) Effect of waterborne polyurethane coating on the durability and breathable waterproofing of electrospun nanofiber web-laminated fabrics. Text Res J 85:160–170.  https://doi.org/10.1177/0040517514542141 CrossRefGoogle Scholar
  11. Jin S, Park Y, Park CH (2015) Preparation of breathable and superhydrophobic polyurethane electrospun webs with silica nanoparticles. Text Res J 86:1816–1827.  https://doi.org/10.1177/0040517515617417 CrossRefGoogle Scholar
  12. Kang YK, Park CH, Kim J, Kang TJ (2007) Application of electrospun polyurethane web to breathable water-proof fabrics. Fiber Polym 8:564–570.  https://doi.org/10.1007/BF02875881 CrossRefGoogle Scholar
  13. Kaur S, Barhate R, Sundarrajan S, Matsuura T, Ramakrishna S (2011) Hot pressing of electrospun membrane composite and its influence on separation performance on thin film composite nanofiltration membrane. Desalination 279:201–209.  https://doi.org/10.1016/j.desal.2011.06.009 CrossRefGoogle Scholar
  14. Lee S, Obendorf SK (2007a) Transport properties of layered fabric systems based on electrospun nanofibers. Fiber Polym 8:501–506.  https://doi.org/10.1007/BF02875872 CrossRefGoogle Scholar
  15. Lee S, Obendorf SK (2007b) Use of electrospun nanofiber web for protective textile materials as barriers to liquid penetration. Text Res J 77:696–702.  https://doi.org/10.1177/0040517507080284 CrossRefGoogle Scholar
  16. McHale G, Aqil S, Shirtcliffe NJ, Newton MI, Erbil HY (2005) Analysis of droplet evaporation on a superhydrophobic surface. Langmuir 21:11053–11060.  https://doi.org/10.1021/la0518795 CrossRefGoogle Scholar
  17. Sumin L, Kimura D, Lee KH, Park JC, Kim IS (2009a) The effect of laundering on the thermal and water transfer properties of mass-produced laminated nanofiber web for use in wear. Text Res J 80:99–105.  https://doi.org/10.1177/0040517508102308 CrossRefGoogle Scholar
  18. Sumin L, Kimura D, Yokoyama A, Lee KH, Park JC, Kim IS (2009b) The effects of laundering on the mechanical properties of mass-produced nanofiber web for use in wear. Text Res J 79:1085–1090.  https://doi.org/10.1177/0040517508101622 CrossRefGoogle Scholar
  19. Tuteja A et al (2007) Designing superoleophobic surfaces. Science 318:1618–1622.  https://doi.org/10.1126/science.1148326 CrossRefGoogle Scholar

Copyright information

© Springer Nature B.V. 2019

Authors and Affiliations

  1. 1.School of Fashion and TextilesRMIT UniversityMelbourneAustralia

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