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Cellulose

pp 1–14 | Cite as

Capacitance performance boost of cellulose-derived carbon nanofibers via carbon and silver nanoparticles

  • Hamdam Gaminian
  • Majid MontazerEmail author
  • Addie Bahi
  • Muzaffer Karaaslan
  • Frank Ko
Original Research
  • 15 Downloads

Abstract

Carbon nanofibers (CNFs) have attracted much attention as effective materials for energy storage devices. Here, silver nanoparticles (AgNPs) were in situ synthesized on the cellulose nanofibers containing vapor grown carbon nanofibers (VGCNFs) for producing carbon nanofibers with desirable properties toward electrochemical applications. Carbon nanofibers were fabricated by electrospinning of cellulose acetate solution containing 0.5 wt% VGCNFs followed by deacetylation and carbonization. Dopamine as a carbon source with high amine content was introduced as poly-functional compound that served as a reducing, adhesive, binding and stabilizing agent for production of silver nanoparticles as well as forming a carbon layer with high nitrogen content on CNF surfaces after heat-treatment. The carbon nanofibers were characterized by scanning electron microscopy (SEM), X-ray diffraction, X-ray photoelectron spectroscopy, energy-dispersive X-ray (EDX), Raman spectroscopy and thermogravimetric examinations (TGA). TGA results demonstrated that dopamine increases thermal stability of cellulose nanofibers, causing higher carbon yield for the final product. Also, EDX pattern and SEM images confirmed the presence of Ag nanoparticles with the uniform distribution and average size of 30 nm. The low cost filler (VGCNFs) and AgNPs were used to improve the electrical properties while dopamine enhanced the pseudocapacitance effects. The final carbon nanofibers containing VGCNFs, Ag and nitrogen exhibited electrical conductivity of 6.41 S cm−1 and specific capacitance of 216 F g−1, about 4 times higher than pure CNFs. The CNFs derived from electrospun cellulose containing conductive metal (Ag), non-metal (VGCNFs) nanoparticles and also nitrogen can be applied as an electrode for high-performance supercapacitors.

Graphical abstract

Keywords

Carbon nanofiber Electrospinning N-doped VGCNFs/Ag/carbon nanocomposites Polydopamine Supercapacitor 

Notes

References

  1. Al-saleh MH (2009) Effect of shear mixing conditions on EMI shielding effectiveness and electrical properties of VGCNF filled thermoplastic. Carbon 47:2–22CrossRefGoogle Scholar
  2. Byrne N, Silva RD, Ma Y, Sixta H, Hummel M (2018) Enhanced stabilization of cellulose-lignin hybrid filaments for carbon fiber production. Cellulose 25:723–733CrossRefGoogle Scholar
  3. Cardoso P, Silva J, Klosterman D, Covas JA, Van Hattum FWJ, Simoes R, Lanceros-mendez S (2012) The role of disorder on the AC and DC electrical conductivity of vapour grown carbon nanofibre/epoxy composites. Compos Sci Technol 72:243–247CrossRefGoogle Scholar
  4. Chand S (2000) Carbon fibers for composites. J Mater Sci 35:1303–1313CrossRefGoogle Scholar
  5. Deng L, Young RJ, Kinloch IA, Abdelkader AM, Holmes SM, De Haro-Del R, David A, Eichhorn SJ (2013a) Supercapacitance from cellulose and carbon nanotube nanocomposite fibers. ACS Appl Mater Interfaces 5:9983–9990CrossRefGoogle Scholar
  6. Deng L, Young RJ, Kinloch IA, Zhu Y, Eichhorn SJ (2013b) Carbon nanofibres produced from electrospun cellulose nanofibres. Carbon 58:66–75CrossRefGoogle Scholar
  7. Gaminian H, Montazer M (2017) Decorating silver nanoparticles on electrospun cellulose nanofibers through a facile method by dopamine and ultraviolet irradiation. Cellulose 24:3179–3190CrossRefGoogle Scholar
  8. Gaminian H, Montazer M (2018) Carbon black enhanced conductivity, carbon yield and dye adsorption of sustainable cellulose derived carbon nanofibers. Cellulose 25:5227–5240CrossRefGoogle Scholar
  9. Ismagilov ZR, Shalagina AE, Yu O, Ischenko AV, Kibis LS, Boronin AI, Chesalov Kochubey Y A D I, Romanenko AI, Anikeeva OB, Buryakov TI, Tkachev E (2009) Structure and electrical conductivity of nitrogen-doped carbon nanofibers. Carbon 47:1922–1929CrossRefGoogle Scholar
  10. Kalambate PK, Dar RA, Karna SP, Srivastava AK (2015) High performance supercapacitor based on graphene-silver nanoparticles-polypyrrole nanocomposite coated on glassy carbon electrode. J Power Sour 276:262–270CrossRefGoogle Scholar
  11. Kang KS, Cho KY, Lim HK, Kim J (2008) Investigation of surface morphology of cellulose acetate micro-mould after deacetylation. J Phys D Appl Pys 41:195403CrossRefGoogle Scholar
  12. Kilzer FJ, Broido A (1965) Speculations on the nature of cellulose pyrolysis. Pyrodynamics 2:151–163Google Scholar
  13. Kim B, Yang KS, Woo H (2011) Preparation and electrochemical properties of carbon nanofiber composite dispersed with silver nanoparticles using polyacrylonitrile and β-Cyclodextrin. J Nanosci Nanotechnol 11:7193–7197CrossRefGoogle Scholar
  14. Konwarh R, Karak N, Misra M (2013) Electrospun cellulose acetate nanofibers: the present status and gamut of biotechnological applications. Biotechnol Adv 31:421–437CrossRefGoogle Scholar
  15. Kuzmenko V, Naboka O, Haque M, Staaf H, Goransson G, Gatenholm P, Peter Enoksson P (2015a) Capacitive effects of nitrogen doping on cellulose-derived carbon nanofibers. Mater Chem Phys 160:59–65CrossRefGoogle Scholar
  16. Kuzmenko V, Naboka O, Haque M, Staaf H, Goransson G, Gatenholm P, Enoksson P (2015b) Sustainable carbon nanofibers/nanotubes composites from cellulose as electrodes for supercapacitors. Energy 90:1490–1496CrossRefGoogle Scholar
  17. Lei C, Han F, Li D, Li WC, Sun Q, Zhang XQ, Lu AH (2013) Dopamine as the coating agent and carbon precursor for the fabrication of N-doped carbon coated Fe3O4 composites as superior lithium ion anodes. Nanoscale 5:1168–1175CrossRefGoogle Scholar
  18. Li F, Kang W, Cheng B, Dong Y (2015) Preparation and catalytic behavior of hollow Ag/carbon nano fibers. Catal Commun 69:150–153CrossRefGoogle Scholar
  19. Lie JA, Ha M (2005) Carbon membranes from cellulose and metal loaded cellulose. Carbon 43:2600–2607CrossRefGoogle Scholar
  20. Liu Y, Ai K, Lu L (2014a) Polydopamine and its derivative materials: synthesis and promising applications in energy, environmental, and biomedical fields. Chem Rev 114:5057–5115CrossRefGoogle Scholar
  21. Liu Y, Qin W, Wang Q, Liu R, Liu H (2014b) Glassy carbon nanofibers from electrospun cellulose nanofiber. J Mater Sci 50:563–569CrossRefGoogle Scholar
  22. Peng S, Gao F, Zeng D, Peng C, Chen Y, Li M (2018) Synthesis of Ag-Fe3O4 nanoparticles supported on polydopamine-functionalized porous cellulose acetate microspheres: catalytic and antibacterial applications. Cellulose 25:4771–4782CrossRefGoogle Scholar

Copyright information

© Springer Nature B.V. 2019

Authors and Affiliations

  • Hamdam Gaminian
    • 1
  • Majid Montazer
    • 1
    Email author
  • Addie Bahi
    • 2
  • Muzaffer Karaaslan
    • 3
  • Frank Ko
    • 2
  1. 1.Department of Textile EngineeringAmirkabir University of Technology, Functional Fibrous Structures and Environmental Enhancement (FFSEE)TehranIran
  2. 2.Department of Materials EngineeringThe University of British ColumbiaVancouverCanada
  3. 3.Advanced Renewable Materials Lab, Department of Wood ScienceUniversity of British ColumbiaVancouverCanada

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