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Cellulose

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Surface modification of TEMPO-oxidized cellulose nanofibrils for composites to give color change in response to pH level

  • Nanang Masruchin
  • Byung-Dae Park
  • Jung Myoung Lee
Original Paper
  • 59 Downloads

Abstract

This study aimed to modify the surface of cellulose nanofibrils (CNFs) prepared by TEMPO-mediated oxidation via two approaches: esterification and amination for further reaction with activated bromocresol green (BCG) to prepare CNF-BCG composites capable of changing color to pH level. Both the esterified and aminated CNFs were reacted with the activated BCG to obtain the composites of CNF-BCG1 and CNF-BCG2, respectively. Then, these composites were exposed to different pH levels to observe any color changes. Fourier transform infrared (FTIR) spectroscopy, thermogravimetry analysis (TGA), and UV–Vis spectroscopy were employed to characterize the modified CNFs and CNF-BCG composites. FTIR spectra showed that CNFs have been esterified or aminated, and the modified CNFs had been successfully reacted with the activated BCG to form CNF-BCG1 and CNF-BCG2, respectively. TGA results also supported this result with a greater thermal stability of both CNF-BCG composites than those of the CNFs. The CNF-BCG1 became yellow below pH 2 while it became green above pH 5. Although these CNF-BCG composites showed color changes to relevant pH levels, the CNF-BCG1 had more distinctive color changes than that of the CNF-BCG2. These results suggested that the esterification of CNFs was a better route to the reaction with the activated BCG for the color change, showing a possibility of using the CNF-BCG1 composites for colorimetric application.

Graphical abstract

Keywords

Cellulose nanofibrils Surface modification Bromocresol green Color change pH 

Notes

Acknowledgments

This work was financially supported by Kyungpook National University Bokhyeon Research Fund, 2017.

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

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Copyright information

© Springer Nature B.V. 2018

Authors and Affiliations

  1. 1.Department of Wood and Paper SciencesKyungpook National UniversityDaeguRepublic of Korea
  2. 2.Research Center for BiomaterialsIndonesian Institute of Sciences (LIPI)BogorIndonesia
  3. 3.Institute of Agricultural Science and TechnologyKyungpook National UniversityDaeguRepublic of Korea

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