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Cellulose

, Volume 25, Issue 8, pp 4819–4830 | Cite as

AQC functionalized CNCs/PVA-co-PE composite nanofibrous membrane with flower-like microstructures for photo-induced multi-functional protective clothing

  • Qing Zhu
  • Yuxia Jin
  • Gang Sun
  • Kelu Yan
  • Dong Wang
Original Paper
  • 155 Downloads

Abstract

The protective textiles with multifunctional properties such as pollutants capture, antibacterial property, detoxification, and self-cleaning ability are highly demanded for soldiers, medical staff and field workers. To achieve multifunctional properties while maintaining the wearing comfort of protective textiles remains a challenge. PVA-co-PE nanofiber membrane has found promising applications in filtering particles due to its large specific surface area. However, due to its limited hydrophilicity, the surface functionalization of nanofiber membrane is difficult. Cellulose Nano-Crystals (CNCs) possessing abundant hydroxyl groups were used to modify the surfaces of PVA-co-PE nanofiber membranes to facilitate the surface functionalization. The photoactive substance of AQC was subsequently grafted onto the CNCs modified PVA-co-PE nanofiber membrane. Depending on the surface chemical structures of nanofiber membranes, the AQC on the nanofiber membrane showed different morphologies and ordered structures. The AQC/CNCs functionalized PVA-co-PE nanofiber membrane demonstrated excellent antibacterial property after 5 min UV exposure, as well as the performance of degrading chemicals. Furthermore, the super-hydrophilic property of the functionalized membrane enables the wearing comfort. The super hydrophilic AQC/CNCs functionalized membrane with multi-functions can be widely applied in the protective clothing in the near future.

Keywords

PVA-co-PE CNCs AQC Antibacterial property Chemicals degradation Protective textile 

Notes

Acknowledgments

The authors appreciate a lot to China Scholarship Council, Dr. Li and PhD students Shitan Wang and Zhiteng Chen in Colorado State University. The authors also appreciate a lot to National Program on Key Research Project (Grant No. 2016 YFC0400504), National Nature Science Foundation (51403166), National Science and Technology support program (2015BAE01B00) and Creative research group of Hubei province (2015CFA028).

Supplementary material

10570_2018_1881_MOESM1_ESM.docx (2.3 mb)
Supplementary material 1 (DOCX 2379 kb)

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Copyright information

© Springer Science+Business Media B.V., part of Springer Nature 2018

Authors and Affiliations

  1. 1.College of Chemistry, Chemical Engineering and BiotechnologyDonghua UniversityShanghaiChina
  2. 2.Department of Design and MerchandisingColorado State UniversityFort CollinsUSA
  3. 3.Division of Textiles and ClothingUniversity of CaliforniaDavisUSA
  4. 4.National Engineering Research Center for Dyeing and Finishing of TextilesShanghaiChina
  5. 5.Key Laboratory of Hubei ProvinceWuhan Textile UniversityWuhanChina

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