Cellulose

pp 1–10 | Cite as

Wettability-switchable bacterial cellulose/polyhemiaminal nanofiber aerogels for continuous and effective oil/water separation

Original Paper
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Abstract

Wettability-switchable bacterial cellulose/polyhemiaminal nanofiber aerogels were successfully prepared by a facile in situ polymerization of paraformaldehyde and 4,4′-diaminodiphenyl ether. The resultant aerogels displayed an interconnected porous structure, superior porosity, low density as well as hydrophobic–oleophilic properties. The aerogels could not only quickly and efficiently absorb the variety of oils or organic solvents from water, but also completely release the adsorbates in acid aqueous solutions by the aid of wettability switch (from hydrophobicity–oleophilicity to underwater superoleophobicity). Furthermore, the aerogels can continuously collect oils both on the water surface and in water-in-oil emulsions by a peristaltic pump.

Keywords

Bacterial cellulose Polyhemiaminal Nanofiber aerogels Wettability-switch Oil/water separation 

Notes

Acknowledgments

This work is supported by the innovation team foundation of Education Department of Sichuan Province (No. 15TD0014).

Supplementary material

10570_2018_1770_MOESM1_ESM.pdf (427 kb)
Supplementary material 1 (PDF 427 kb)

Supplementary material 2 (WMV 158 kb)

Supplementary material 3 (WMV 2244 kb)

Supplementary material 4 (WMV 41057 kb)

Supplementary material 5 (WMV 23479 kb)

References

  1. Alcocer-Márquez LF, Palacios-Alquisira J (2017) Poly(hexahydrotriazine) membranes prepared by coupling reaction between diamines and aldehydes. In: Maciel-Cerda A (ed) Membranes: materials, simulations, and applications. Springer, Cham, pp 3–10.  https://doi.org/10.1007/978-3-319-45315-6_1 CrossRefGoogle Scholar
  2. Cervin NT, Aulin C, Larsson PT, Wågberg L (2012) Ultra porous nanocellulose aerogels as separation medium for mixtures of oil/water liquids. Cellulose 19:401–410.  https://doi.org/10.1007/s10570-011-9629-5 CrossRefGoogle Scholar
  3. Du R, Zheng Z, Mao N, Zhang N, Hu W, Zhang J (2015) Fluorosurfactants-directed preparation of homogeneous and hierarchical-porosity cmp aerogels for gas sorption and oil cleanup. Adv Sci 2:1400006.  https://doi.org/10.1002/advs.201400006 CrossRefGoogle Scholar
  4. García JM, Jones GO, Virwani K, McCloskey BD, Boday DJ, ter Huurne GM, Horn HW, Coady DJ, Bintaleb AM, Alabdulrahman AMS, Alsewailem F, Almegren HAA, Hedrick JL (2014) Recyclable, strong thermosets and organogels via paraformaldehyde condensation with diamines. Science 344:732–735.  https://doi.org/10.1126/science.1251484 CrossRefGoogle Scholar
  5. Ge Q, Amy GL, Chung T-S (2017) Forward osmosis for oily wastewater reclamation: multi-charged oxalic acid complexes as draw solutes. Water Res 122:580–590.  https://doi.org/10.1016/j.watres.2017.06.025 CrossRefGoogle Scholar
  6. Gupta S, Tai N-H (2016) Carbon materials as oil sorbents: a review on the synthesis and performance. J Mater Chem A 4:1550–1565.  https://doi.org/10.1039/C5TA08321D CrossRefGoogle Scholar
  7. Heath L, Thielemans W (2010) Cellulose nanowhisker aerogels. Green Chem 12:1448–1453.  https://doi.org/10.1039/C0GC00035C CrossRefGoogle Scholar
  8. Hoepfner S, Ratke L, Milow B (2008) Synthesis and characterisation of nanofibrillar cellulose aerogels. Cellulose 15:121–129.  https://doi.org/10.1007/s10570-007-9146-8 CrossRefGoogle Scholar
  9. Korhonen JT, Kettunen M, Ras RHA, Ikkala O (2011) Hydrophobic nanocellulose aerogels as floating, sustainable, reusable, and recyclable oil absorbents. ACS Appl Mater Interfaces 3:1813–1816.  https://doi.org/10.1021/am200475b CrossRefGoogle Scholar
  10. Laitinen O, Suopajärvi T, Österberg M, Liimatainen H (2017) Hydrophobic, superabsorbing aerogels from choline chloride-based deep eutectic solvent pretreated and silylated cellulose nanofibrils for selective oil removal. ACS Appl Mater Interfaces 9:25029–25037.  https://doi.org/10.1021/acsami.7b06304 CrossRefGoogle Scholar
  11. Li Z, Zhou X, Pei C (2010) Synthesis and characterization of MPS-g-PLA copolymer and its application in surface modification of bacterial cellulose. Int J Polym Anal Charact 15:199–209.  https://doi.org/10.1080/10236661003681222 CrossRefGoogle Scholar
  12. Li Z, Qiu J, Pei C (2016) Recyclable and transparent bacterial cellulose/hemiaminal dynamic covalent network polymer nanocomposite films. Cellulose 23:2449–2455.  https://doi.org/10.1007/s10570-016-0956-4 CrossRefGoogle Scholar
  13. Li L, Li B, Sun H, Zhang J (2017a) Compressible and conductive carbon aerogels from waste paper with exceptional performance for oil/water separation. J Mater Chem A 5:14858–14864.  https://doi.org/10.1039/C7TA03511J CrossRefGoogle Scholar
  14. Li Z, Qiu J, Yuan S, Luo Q, Pei C (2017b) Rapidly degradable and sustainable polyhemiaminal aerogels for self-driven efficient separation of oil/water mixture. Ind Eng Chem Res 56:6508–6514.  https://doi.org/10.1021/acs.iecr.7b00312 CrossRefGoogle Scholar
  15. Liu C-Y, Zhong G-J, Huang H-D, Li Z-M (2014a) Phase assembly-induced transition of three dimensional nanofibril- to sheet-networks in porous cellulose with tunable properties. Cellulose 21:383–394.  https://doi.org/10.1007/s10570-013-0096-z CrossRefGoogle Scholar
  16. Liu F, Ma M, Zang D, Gao Z, Wang C (2014b) Fabrication of superhydrophobic/superoleophilic cotton for application in the field of water/oil separation. Carbohydr Polym 103:480–487.  https://doi.org/10.1016/j.carbpol.2013.12.022 CrossRefGoogle Scholar
  17. Liu H, Geng B, Chen Y, Wang H (2017) Review on the aerogel-type oil sorbents derived from nanocellulose. ACS Sustain Chem Eng 5:49–66.  https://doi.org/10.1021/acssuschemeng.6b02301 CrossRefGoogle Scholar
  18. Lopes TD, Riegel-Vidotti IC, Grein A, Tischer CA, Faria-Tischer P (2014) Bacterial cellulose and hyaluronic acid hybrid membranes: production and characterization. Int J Biol Macromol 67:401–408.  https://doi.org/10.1016/j.ijbiomac.2014.03.047 CrossRefGoogle Scholar
  19. Lu J, Xu D, Wei J, Yan S, Xiao R (2017) Superoleophilic and flexible thermoplastic polymer nanofiber aerogels for removal of oils and organic solvents. ACS Appl Mater Interfaces 9:25533–25541.  https://doi.org/10.1021/acsami.7b07004 CrossRefGoogle Scholar
  20. Mulyadi A, Zhang Z, Deng Y (2016) Fluorine-free oil absorbents made from cellulose nanofibril aerogels. ACS Appl Mater Interfaces 8:2732–2740.  https://doi.org/10.1021/acsami.5b10985 CrossRefGoogle Scholar
  21. Sai H, Fu R, Xing L, Xiang J, Li Z, Li F, Zhang T (2015) Surface modification of bacterial cellulose aerogels’ web-like skeleton for oil/water separation. ACS Appl Mater Interfaces 7:7373–7381.  https://doi.org/10.1021/acsami.5b00846 CrossRefGoogle Scholar
  22. Shahidul Islam M, Tanaka M (2004) Impacts of pollution on coastal and marine ecosystems including coastal and marine fisheries and approach for management: a review and synthesis. Mar Pollut Bull 48:624–649.  https://doi.org/10.1016/j.marpolbul.2003.12.004 CrossRefGoogle Scholar
  23. Si Y, Fu Q, Wang X, Zhu J, Yu J, Sun G, Ding B (2015) Superelastic and superhydrophobic nanofiber-assembled cellular aerogels for effective separation of oil/water emulsions. ACS Nano 9:3791–3799.  https://doi.org/10.1021/nn506633b CrossRefGoogle Scholar
  24. Sun F, Liu W, Dong Z, Deng Y (2017) Underwater superoleophobicity cellulose nanofibril aerogel through regioselective sulfonation for oil/water separation. Chem Eng J 330:774–782.  https://doi.org/10.1016/j.cej.2017.07.142 CrossRefGoogle Scholar
  25. Wang Y, Yadav S, Heinlein T, Konjik V, Breitzke H, Buntkowsky G, Schneider JJ, Zhang K (2014) Ultra-light nanocomposite aerogels of bacterial cellulose and reduced graphene oxide for specific absorption and separation of organic liquids. RSC Adv 4:21553–21558.  https://doi.org/10.1039/C4RA02168A CrossRefGoogle Scholar
  26. Wang H, Wang E, Liu Z, Gao D, Yuan R, Sun L, Zhu Y (2015) A novel carbon nanotubes reinforced superhydrophobic and superoleophilic polyurethane sponge for selective oil–water separation through a chemical fabrication. J Mater Chem A 3:266–273.  https://doi.org/10.1039/C4TA03945A CrossRefGoogle Scholar
  27. Wei X, Huang T, J-h Y, Zhang N, Wang Y, Z-w Z (2017) Green synthesis of hybrid graphene oxide/microcrystalline cellulose aerogels and their use as superabsorbents. J Hazard Mater 335:28–38.  https://doi.org/10.1016/j.jhazmat.2017.04.030 CrossRefGoogle Scholar
  28. Wu ZY, Li C, Liang HW, Chen JF, Yu SH (2013) Ultralight, flexible, and fire-resistant carbon nanofiber aerogels from bacterial cellulose. Angew Chem Int Ed 52:2925–2929.  https://doi.org/10.1002/anie.201209676 CrossRefGoogle Scholar
  29. Wu Z, Li Y, Zhang L, Zhong Y, Xu H, Mao Z, Wang B, Sui X (2017) Thiol-ene click reaction on cellulose sponge and its application for oil/water separation. RSC Advances 7:20147–20151.  https://doi.org/10.1039/C7RA00847C CrossRefGoogle Scholar
  30. Xiao S, Gao R, Lu Y, Li J, Sun Q (2015) Fabrication and characterization of nanofibrillated cellulose and its aerogels from natural pine needles. Carbohyd Polym 119:202–209.  https://doi.org/10.1016/j.carbpol.2014.11.041 CrossRefGoogle Scholar
  31. Xue Z, Wang S, Lin L, Chen L, Liu M, Feng L, Jiang L (2011) A novel superhydrophilic and underwater superoleophobic hydrogel-coated mesh for oil/water separation. Adv Mater 23:4270–4273.  https://doi.org/10.1002/adma.201102616 CrossRefGoogle Scholar
  32. Zhang Z, Sebe G, Rentsch D, Zimmermann T, Tingaut P (2014) Ultralightweight and flexible silylated nanocellulose sponges for the selective removal of oil from water. Chem Mater 26:2659–2668.  https://doi.org/10.1021/cm5004164 CrossRefGoogle Scholar
  33. Zhou S, Liu P, Wang M, Zhao H, Yang J, Xu F (2016) Sustainable, reusable, and superhydrophobic aerogels from microfibrillated cellulose for highly effective oil/water separation. ACS Sustain Chem Eng 4:6409–6416.  https://doi.org/10.1021/acssuschemeng.6b01075 CrossRefGoogle Scholar
  34. Zhu H, Chen D, Li N, Xu Q, Li H, He J, Lu J (2015) Graphene foam with switchable oil wettability for oil and organic solvents recovery. Adv Funct Mater 25:597–605.  https://doi.org/10.1002/adfm.201403864 CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media B.V., part of Springer Nature 2018

Authors and Affiliations

  1. 1.State Key Laboratory Cultivation Base for Nonmetal Composites and Functional MaterialsSouthwest University of Science and TechnologyMianyangPeople’s Republic of China
  2. 2.School of Materials Science and EngineeringSouthwest University of Science and TechnologyMianyangPeople’s Republic of China

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