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Cellulose

, Volume 24, Issue 2, pp 989–1000 | Cite as

A comparative study for oil-absorbing performance of octadecyltrichlorosilane treated Calotropis gigantea fiber and kapok fiber

  • Yian ZhengEmail author
  • Enjuan Cao
  • Lixin Tu
  • Aiqin Wang
  • Huimin Hu
Original Paper

Abstract

A hydrophobic layer was formed on smooth surfaces of Calotropis gigantea fiber (CGF) and kapok fiber (KF) by adsorption of octadecyltrichlorosilane (OTS) from a toluene solution and then a comparative study was carried out on the basis of various characterizations and oil-absorbing performances for the two natural plant fibers. The resulting OTS-CGF and OTS-KF exhibit outstanding hydrophobic–oleophilic property and an enhancement in the oil-absorbing capacity for engine oil, soybean oil and kerosene. Moreover, the fibers can be utilized for rapid and selective removal of oil spills on the water surface. Compared to KF, CGF seems to be acid-resistant during the hydrolysis process of OTS, with the result that the oil-absorbing capacity exhibits no significant decrease after ten cycles. Eventually, CGF-based material can be further developed for oil–water separation, demonstrating its potential as a promising alternative for treatment of oil-containing wastewaters.

Keywords

Calotropis gigantea fiber Kapok fiber Octadecyltrichlorosilane Oil-absorbing performance Oil–water separation 

Notes

Acknowledgments

The authors thank for the joint support of the National Natural Science Foundation of China (No. 21477135), the Fundamental Research Funds for the Central Universities (No. lzujbky-2015-127), and the Hui-Chun Chin and Tsung-Dao Lee Chinese Undergraduate Research Endowment (No. JZH0028).

Supplementary material

10570_2016_1155_MOESM1_ESM.docx (4.7 mb)
Supplementary material 1 (DOCX 4863 kb)

Supplementary material 2 (MOV 1325 kb)

Supplementary material 3 (MOV 857 kb)

References

  1. Abdullah MA, Rahmah AU, Man Z (2010) Physicochemical and sorption characteristics of Malaysian Ceiba pentandra (L.) Gaertn. as a natural oil sorbent. J Hazard Mater 177:683–691CrossRefGoogle Scholar
  2. Ali N, El-Harbawi M, Jabal AA, Yin C-Y (2012) Characteristics and oil sorption effectiveness of kapok fibre, sugarcane bagasse and rice husks: oil removal suitability matrix. Environ Technol 33:481–486CrossRefGoogle Scholar
  3. Annunciado TR, Sydenstricker THD, Amico SC (2005) Experimental investigation of various vegetable fibers as sorbent materials for oil spills. Mar Pollut Bull 50:1340–1346CrossRefGoogle Scholar
  4. Ashori A, Bahreini Z (2009) Evaluation of Calotropis gigantea as a promising raw material for fiber-reinforced composite. J Compos Mater 43:1297–1304CrossRefGoogle Scholar
  5. Babu ARS, Karki SS (2011) Anti-convulsant activity of various extracts of leaves of Calotropis gigantea Linn against seizure induced models. Int J Pharm Pharm Sci 3:200–203Google Scholar
  6. Bastani D, Safekordi A, Alihosseini A, Taghikhani V (2006) Study of oil sorption by expanded perlite at 298.15 K. Sep Purif Technol 52:295–300CrossRefGoogle Scholar
  7. Bi H, Xie X, Yin K, Zhou Y, Wan S, He L, Xu F, Banhart F, Sun L, Ruoff R (2012) Spongy graphene as a highly efficient and recyclable sorbent for oils and organic solvents. Adv Funct Mater 22:4421–4425CrossRefGoogle Scholar
  8. Cha K-H, Kim D-E (2001) Investigation of the tribological behavior of octadecyltrichlorosilane deposited on silicon. Wear 251:1169–1176CrossRefGoogle Scholar
  9. Chen Q, Zhao T, Wang M, Wang J (2013) Studies of the fibre structure and dyeing properties of Calotropis gigantea, kapok and cotton fibres. Color Technol 129:448–453CrossRefGoogle Scholar
  10. Chen L, Du R, Zhang J, Yi T (2015) Density controlled oil uptake and beyond: from carbon nanotubes to graphene nanoribbon aerogels. J Mater Chem A 3:20547–20553CrossRefGoogle Scholar
  11. Choi H-M (1992) Natural sorbents in oil spill cleanup. Environ Sci Technol 26:772–776CrossRefGoogle Scholar
  12. Deschamps G, Caruel H, Borredon M-E, Albasi C, Riba J-P, Bonnin C, Vignoles C (2003a) Oil removal from water by sorption on hydrophobic cotton fibers. 2. Study of sorption properties in dynamic mode. Environ Sci Technol 37:5034–5039CrossRefGoogle Scholar
  13. Deschamps G, Caruel H, Borredon M-E, Bonnin C, Vignoles C (2003b) Oil removal from water by selective sorption on hydrophobic cotton fibers. 1. Study of sorption properties and comparison with other cotton fiber-based sorbents. Environ Sci Technol 37:1013–1015CrossRefGoogle Scholar
  14. Deshmukha PT, Fernandes J, Atul A, Toppo E (2009) Wound healing activity of Calotropis gigantea root bark in rats. J Ethnopharmacol 125:178–181CrossRefGoogle Scholar
  15. Dong T, Xu G, Wang F (2015a) Oil spill cleanup by structured natural sorbents made from cattail fibers. Ind Crop Prod 76:25–33CrossRefGoogle Scholar
  16. Dong T, Xu G, Wang F (2015b) Adsorption and adhesiveness of kapok fiber to different oils. J Hazard Mater 296:101–111CrossRefGoogle Scholar
  17. Dong T, Wang F, Xu G (2015c) Sorption kinetics and mechanism of various oils into kapok assembly. Ind Crop Prod 91:230–237Google Scholar
  18. Duan B, Gao H, He M, Zhang L (2014) Hydrophobic modification on surface of chitin sponges for highly effective separation of oil. ACS Appl Mater Interfaces 6:19933–19942CrossRefGoogle Scholar
  19. Erdman MD, Erdman BA (1981) Calotropis procera as a source of plant hydrocarbons. Econ Bot 35:467–472CrossRefGoogle Scholar
  20. Gui X, Wei J, Wang K, Cao A, Zhu H, Jia Y, Shu Q, Wu D (2010) Carbon nanotube sponges. Adv Mater 22:617–621CrossRefGoogle Scholar
  21. Hu H, Zhao Z, Gogotsi Y, Qiu J (2014) Compressible carbon nanotube–graphene hybrid aerogels with superhydrophobicity and superoleophilicity for oil sorption. Environ Sci Technol Lett 1:214–220CrossRefGoogle Scholar
  22. Hui B, Li Y, Huang Q, Li G, Li J, Cai L, Yu H (2015a) Fabrication of smart coatings based on wood substrates with photoresponsive behavior and hydrophobic performance. Mater Des 84:277–284Google Scholar
  23. Hui B, Wu D, Huang Q, Cai L, Li G, Li J, Zhao G (2015b) Photoresponsive and wetting performances of sheet-like nanostructures of tungsten trioxide thin films grown on wood surfaces. RSC Adv 5:73566–73574CrossRefGoogle Scholar
  24. Inagaki M, Kawahara A, Konno H (2002) Sorption and recovery of heavy oils using carbonized fir fibers and recycling. Carbon 40:105–111CrossRefGoogle Scholar
  25. Jin Y, Jiang P, Ke Q, Cheng F, Zhu Y, Zhang Y (2015) Superhydrophobic and superoleophilic polydimethylsiloxane-coated cotton for oil–water separation process: an evidence of the relationship between its loading capacity and oil absorption. J Hazard Mater 300:175–181CrossRefGoogle Scholar
  26. Ke Q, Jin Y, Jiang P, Yu J (2014) Oil/water separation performances of superhydrophobic and superoleophilic sponges. Langmuir 30:13137–13142CrossRefGoogle Scholar
  27. Khosravi M, Azizian S (2015) Synthesis of a novel highly oleophilic and highly hydrophobic sponge for rapid oil spill cleanup. ACS Appl Mater Interfaces 7:25326–25333CrossRefGoogle Scholar
  28. Li D, Zhu FZ, Li JY, Na P, Wang N (2013) Preparation and characterization of cellulose fibers from corn straw as natural oil sorbents. Ind Eng Chem Res 52:516–524CrossRefGoogle Scholar
  29. Lim T, Huang X (2007a) Evaluation of kapok (Ceiba pentandra (L.) Gaertn.) as a natural hollow hydrophobic–oleophilic fibrous sorbent for oil spill cleanup. Chemosphere 66:955–963CrossRefGoogle Scholar
  30. Lim T, Huang X (2007b) Evaluation of hydrophobicity/oleophilicity of kapok and its performance in oily water filtration: comparison of raw and solvent-treated fibers. Ind Crop Prod 26:125–134CrossRefGoogle Scholar
  31. Liu F, Ma M, Zang D, Gao Z, Wang C (2014) Fabrication of superhydrophobic/superoleophilic cotton for application in the field of water/oil separation. Carbohydr Polym 103:480–487CrossRefGoogle Scholar
  32. Meng Y, Young TM, Liu P, Contescu CI, Huang B, Wang S (2015) Ultralight carbon aerogel from nanocellulose as a highly selective oil absorption material. Cellulose 22:435–447CrossRefGoogle Scholar
  33. Mwaikambo LY (2001) The determination of porosity and cellulose content of plant fibers by density methods. J Mater Sci Lett 20:2095–2096CrossRefGoogle Scholar
  34. Mysore D, Viraragavan T, Jin Y (2005) Treatment of oily waters using vermiculite. Water Res 39:2643–2653CrossRefGoogle Scholar
  35. Nourbakhsh A (2009) Giant milkweed (Calotropis persica) fibers-a potential reinforcement agent for thermoplastics composites. J Reinf Plast Compos 28:2143–2149CrossRefGoogle Scholar
  36. Pan Y, Shi K, Peng C, Wang W, Liu Z, Ji X (2014) Evaluation of hydrophobic polyvinyl-alcohol formaldehyde sponges as absorbents for oil spill. ACS Appl Mater Interfaces 6:8651–8659CrossRefGoogle Scholar
  37. Paul JH, Hollander D, Coble P, Daly KL, Murasko S, English D, Basso J, Delaney J, McDaniel L, Kovach CW (2013) Toxicity and mutagenicity of gulf of Mexico waters during and after the deepwater horizon oil spill. Environ Sci Technol 47:9651–9659CrossRefGoogle Scholar
  38. Pham VH, Dickerson JH (2014) Superhydrophobic silanized melamine sponges as high efficiency oil absorbent materials. ACS Appl Mater Interfaces 6:14181–14188CrossRefGoogle Scholar
  39. Phoo ZWMM, Razon LF, Knothe G, Ilham Z, Goembira F, Madrazo CF, Roces SA, Saka S (2015) Evaluation of Indian milkweed (Calotropis gigantea) seed oil as alternative feedstock for biodiesel. Ind Crop Prod 54:226–232CrossRefGoogle Scholar
  40. Qiu S, Yin H, Zheng J, Jiang B, Wu M, Wu W (2014) A biomimetic 3D ordered multimodal porous carbon with hydrophobicity for oil–water separation. Mater Lett 133:40–43CrossRefGoogle Scholar
  41. Sai H, Fu R, Xing L, Xiang J, Li Z, Li F, Zhang T (2015) Surface modification of bacterial cellulose aerogels’ web-like skeleton for oil/water separation. ACS Appl Mater Interfaces 7:7373–7381CrossRefGoogle Scholar
  42. Sakthivel JC, Mukhopadhyay S, Palanisamy NK (2005) Some studies on Mudar fibers. J Ind Text 35:63–76CrossRefGoogle Scholar
  43. Seal S, Sakthivel T, Reid D, Goldstein I, Hench L (2013) Hydrophobic high surface area zeolites derived from fly ash for oil spill remediation. Environ Sci Technol 47:5843–5850CrossRefGoogle Scholar
  44. Singh V, Jinka S, Hake K, Parameswaran S, Kendall RJ, Ramkumar S (2014) Novel natural sorbent for oil spill cleanup. Ind Eng Chem Res 53:11954–11961CrossRefGoogle Scholar
  45. Syed S, Alhazzaa MI, Asif M (2011) Treatment of oily water using hydrophobic nano-silica. Chem Eng J 167:99–103CrossRefGoogle Scholar
  46. Tansel B, Pascual B (2011) Removal of emulsified fuel oils from brackish and pond water by dissolved air flotation with and without polyelectrolyte use: pilotscale investigation for estuarine and near shore applications. Chemosphere 85:1182–1186CrossRefGoogle Scholar
  47. Tjandra R, Lui G, Veilleux A, Broughton J, Chiu G, Yu A (2015) Introduction of an enhanced binding of reduced graphene oxide to polyurethane sponge for oil absorption. Ind Eng Chem Res 54:3657–3663CrossRefGoogle Scholar
  48. Tripp CP, Hair ML (1992) An infrared study of the reaction of octadecyltrichlorosilane with silica. Langmuir 8:1120–1126CrossRefGoogle Scholar
  49. Tuntawiroon N, Samootsakorn P, Theeraraj G (1984) The environmental implications of the use of Calotropis gigantea as a textile fabric. Agric Ecosyst Environ 11:203–212CrossRefGoogle Scholar
  50. Wang J, Zheng Y, Kang Y, Wang A (2013) Investigation of oil sorption capability of PBMA/SiO2 coated kapok fiber. Chem Eng J 223:632–637CrossRefGoogle Scholar
  51. Wu L, Li L, Li B, Zhang J, Wang A (2015) Magnetic, durable, and superhydrophobic polyurethane@Fe3O4@SiO2@fluoropolymer sponges for selective oil absorption and oil/water separation. ACS Appl Mater Interfaces 7:4936–4946CrossRefGoogle Scholar
  52. Xiong S, Long H, Tang G, Wan J, Li H (2015) The management in response to marine oil spill from ships in China: a systematic review. Mar Pollut Bull 96:7–17CrossRefGoogle Scholar
  53. Yang Y, Tong Z, Ngai T, Wang C (2014) Nitrogen-rich and fire-resistant carbon aerogels for the removal of oil contaminants from water. ACS Appl Mater Interfaces 6:6351–6360CrossRefGoogle Scholar
  54. Zadaka-Amir D, Bleiman N, Mishael YG (2013) Sepiolite as an effective natural porous adsorbent for surface oil-spill. Microporous Mesoporous Mater 169:153–159CrossRefGoogle Scholar
  55. Zang D, Liu F, Zhang M, Gao Z, Wang C (2015) Novel superhydrophobic and superoleophilic sawdust as a selective oil sorbent for oil spill cleanup. Chem Eng Res Des 102:34–41CrossRefGoogle Scholar
  56. Zhang A, Chen M, Du C, Guo H, Bai H, Li L (2013) Poly(dimethylsiloxane) oil absorbent with a three-dimensionally interconnected porous structure and swellable skeleton. ACS Appl Mater Interfaces 5:10201–10206CrossRefGoogle Scholar
  57. Zhang Z, Sèbe G, Rentsch D, Zimmermann T, Tingaut P (2014) Ultralightweight and flexible silylated nanocellulose sponges for the selective removal of oil from water. Chem Mater 26:2659–2668CrossRefGoogle Scholar
  58. Zhang N, Jiang W, Wang T, Gu J, Zhong S, Zhou S, Xie T, Fu J (2015) Facile preparation of magnetic poly(styrene-divinylbenzene) foam and its application as an oil absorbent. Ind Eng Chem Res 54:11033–11039CrossRefGoogle Scholar
  59. Zheng Y, Wang J, Zhu Y, Wang A (2015) Research and application of kapok fiber as an absorbing material: a mini review. J Environ Sci 27:21–32CrossRefGoogle Scholar
  60. Zheng Y, Zhu Y, Wang A, Hu H (2016) Potential of Calotropis gigantea fiber as an absorbent for removal of oil from water. Ind Crop Prod 83:387–390CrossRefGoogle Scholar
  61. Zhu H, Qiu S, Jiang W, Wu D, Zhang C (2011) Evaluation of electrospun polyvinyl chloride/polystyrene fibers as sorbent materials for oil spill cleanup. Environ Sci Technol 45:4527–4531CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media Dordrecht 2016

Authors and Affiliations

  • Yian Zheng
    • 1
    • 2
    Email author
  • Enjuan Cao
    • 1
  • Lixin Tu
    • 1
  • Aiqin Wang
    • 3
  • Huimin Hu
    • 4
  1. 1.Gansu Key Laboratory for Environmental Pollution Prediction and Control, College of Earth and Environmental SciencesLanzhou UniversityLanzhouChina
  2. 2.Zhongwei High-tech Institute of Lanzhou UniversityZhongweiChina
  3. 3.Center of Eco-materials and Green Chemistry, Lanzhou Institute of Chemical PhysicsChinese Academy of SciencesLanzhouChina
  4. 4.Shanghai Magic Tree Biotechnology Co., Ltd.ShanghaiChina

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