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Cellulose

, Volume 23, Issue 6, pp 3569–3576 | Cite as

One-pot functionalization of cellulose nanocrystals with various cationic groups

  • Latifah Jasmani
  • Samuel Eyley
  • Christina Schütz
  • Hans Van Gorp
  • Steven De Feyter
  • Wim Thielemans
Original Paper

Abstract

After successful cationization of cellulose nanocrystals (CNCs) to produce pyridinium-grafted-CNCs, a variety of different cationic CNCs were prepared using a similar procedure, thus unlocking access to a wide variety of cationized cellulose nanocrystals through a simple one-pot reaction. In this study, cationic CNCs were prepared through the use of 4-(1-bromoethyl)benzoic acid or 4-bromomethylbenzoic acid, p-toluenesulfonyl chloride, CNCs, and two different amines, 1-methylimidazole and 4-dimethylaminopyridine. The amines acted as both the base catalyst for the esterification and the nucleophile to form the cationic charge. This method offers a versatile and straightforward route to prepare a variety of different cationic nanocrystals and therefore tailor their interaction with their environment.

Keywords

Cellulose nanocrystals Cationization Surface modification One-pot reaction 

Notes

Acknowledgments

LJ would like to thank the Malaysian government for a Ministry of Science, Technology and Innovation Fellowship (mosti/bmi/taji-3/2 jilid). WT, SE and CS thank Research Foundation—Flanders (FWO) for funding under the Odysseus Grant (G.0C60.13N). WT also thanks KU Leuven (Grant OT/14/072), the Engineering and Science Physical Sciences Research Council (ESPRC, Grant EP/J015687/1) and the Province of West-Vlaanderen (Provincial Chair in Advanced Materials) for financial support. HVG and SDF acknowledge support by KU Leuven internal funds.

Supplementary material

10570_2016_1052_MOESM1_ESM.pdf (463 kb)
Supplementary material 1 (pdf 463 KB)

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Copyright information

© Springer Science+Business Media Dordrecht 2016

Authors and Affiliations

  1. 1.School of ChemistryUniversity of NottinghamNottinghamUK
  2. 2.Renewable Materials and Nanotechnology Research GroupKU Leuven Campus Kulak KortrijkKortrijkBelgium
  3. 3.Molecular Imaging and PhotonicsKU LeuvenLeuvenBelgium

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