Approximate solution of the autocatalytic hydrolysis of cellulose
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Depolymerization of cellulose in homogeneous acidic medium is analyzed on the basis of autocatalytic model of hydrolysis with a positive feedback of acid production from the degraded biopolymer. The normalized number of scissions per cellulose chain, S(t)/n° = 1 − C(t)/C0, follows a sigmoid behavior with reaction time t, and the cellulose concentration C(t) decreases exponentially with a linear and cubic time dependence, C(t) = C0exp[−at − bt3], where a and b are model parameters easier determined from data analysis.
KeywordsCellulose Depolymerization Acid hydrolysis Ageing Autocatalytic kinetics
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