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Extraction of cellulose and preparation of nanocellulose from sisal fibers

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Abstract

In this work a study on the feasibility of extracting cellulose from sisal fiber, by means of two different procedures was carried out. These processes included usual chemical procedures such as acid hydrolysis, chlorination, alkaline extraction, and bleaching. The final products were characterized by means of Thermogravimetric Analysis (TGA), Infrared Spectroscopy (FTIR), X-Ray Diffraction (XRD), Differential Scanning Calorimetry (DSC) and Scanning Electronic Microscopy (SEM). The extraction procedures that were used led to purified cellulose. Advantages and disadvantages of both procedures were also analyzed. Finally, nanocellulose was produced by the acid hydrolysis of obtained cellulose and characterized by Atomic Force Microscopy (AFM).

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References

  • Alvarez VA, Vazquez A (2006) Influence of fiber chemical modification procedure on the mechanical properties and water absorption of MaterBi/Sisal fiber composites. Compos Part A: Appl S 37(10):1672–1680

    Article  CAS  Google Scholar 

  • Baird MS, Hamlin JD, O’Sullivan, Whiting A (2006) An insight into the mechanism of the cellulose dyeing process: molecular modelling and simulations of cellulose and its interactions with water, urea, aromatic azo-dyes and aryl ammonium compounds. Dyes Pigments, (in Press), It was not actualized

  • Bhatnagar A, Sain M (2005) Processing of cellulose nanofiber-reinforced composites. J Reinf Plast Comp 24(12):1259–1269

    Article  CAS  Google Scholar 

  • Benziman M, Haigler CH, Brown RMJ, White AR, Cooper KM (1980) Cellulose biogenesis: polymerization and crystallization are coupled processes in Acetobacter xylinum. National Academy of Science, USA, p 4

    Google Scholar 

  • Bledzki A-K, Gassan J (1999) Composites reinforced with cellulose based fibres. Prog Polym Sci 24:221–275

    Article  CAS  Google Scholar 

  • Chattopadhyay H, Sarkar PB (1946) A New Method for the Estimation of Cellulose. Proc Natl Inst Sci India 12(1):23–46

    CAS  Google Scholar 

  • Cyras VP, Vallo C, Kenny JM, Vazquez A (2004) Effect of the chemical treatment on the mechanical properties of the PCL/starch and sisal fiber composites. J Compos Mater 38(16):512–520

    Google Scholar 

  • Deraman M, Zakaria S, Murshidi JA (2001) Estimation of crystallinity and cryistallite size of cellulose in benzylated fibres of oil palm empty fruit bunches by X-Ray Diffraction. J Appl Phys 40:311–315

    Google Scholar 

  • Doraiswammy I, Chellamani P (1993) Pineapple-leaf fibers. Text Progr 24(1):1–37

    Article  Google Scholar 

  • García-Jaldon G, Dupeyre D, Vignon MR (1998) Fibers from semi-retted hemp bundles by steam explosion treatment. Biomass Bioenerg 14:251–260

    Article  Google Scholar 

  • Goodger EM (1976) Hydrocarbon fuels, production, properties and performance of liquids and gases. Macmillan, London, p 120

    Google Scholar 

  • Itoh T, Brown RMJ (1984) The assembly of cellulose microfibrils in Valonia macrophysa. Planta 160:372–381

    Article  Google Scholar 

  • Lojewska J, Miskowiec P, Lojewski T, Pronienwicz LM (2005) Cellulose oxidative and hydrolytic degradation: in situ FTIR approach. Polym Degrad Stab 88:512–520

    Article  CAS  Google Scholar 

  • Mwaikambo LY, Ansell MP (2002) Chemical modification of hemp, sisal, jute, and kapok fibers by alkalization. J Appl Polym Sci 84:2222–2234

    Article  CAS  Google Scholar 

  • Nelson ML, O’Connor RT (1964) Relation of certain infrared bands to cellulose crystallinity and crystal lattice type. Part II: a new infrared ratio for estimation of crystallinity in celluloses I and II. J Appl Polym Sci 8(3):1328–1341

    Google Scholar 

  • Oh SY, Yoo DI, Shin Y, Seo G (2005) FTIR analysis of cellulose treated with sodium hydroxide and carbon dioxide. Carbohyd Res 340:417–428

    Article  CAS  Google Scholar 

  • Reddy N, Yang Y (2005) Structure and properties of high quality natural cellulose fiber from cornstalks. Polymer 46(15):5494–5500

    Article  CAS  Google Scholar 

  • Rong MZ, Zhang MQ, Lui Y, Yang GC, Zeng HM (2001) The effect of fiber treatment on the mechanical properties of unidirectional sisal-reinforced epoxi composites. Compos Sci Technol 61:1437–1447

    Article  CAS  Google Scholar 

  • Rowell RM, Young RA, Rowell JK (eds) (1996) Paper and composites from agro-based resources. Lewis Publishers, Boca Raton, Florida

    Google Scholar 

  • Samir M, Alloin F, Paillet M, Dufresne A (2004) Tangling effect in fibrillated cellulose reinforced nanocomposites. Macromolecules 37:4313–4316

    Article  CAS  Google Scholar 

  • Sarkar PB, Mazumdar AK, Pal KB (1948) The hemicelluloses of jute fibre. J Tex Inst 39(T44):44–58

    Google Scholar 

  • Hon DNS (ed) (1996) Chemical modification of lignocellulosic materials. Marcel Dekker, Inc., New York

  • Sun RC, Sun XF (2002) Fractional and structural characterization of hemicelluloses isolated by alkali and alkaline peroxide from barley straw. Carbohyd Polym 49:415–423

    Article  CAS  Google Scholar 

  • Sun XF, Sun RC, Su Y, Sun JX (2004) Comparative study of crude and purified cellulose from wheat straw. J Agric Food Chem 52:839–847

    Article  CAS  Google Scholar 

  • Vignon MR, Heux L, Malainine ME, Mahrouz M (2004) Arabinan-cellulose composite in Opuntia ficus-indica prickly pear spines Carbohyd Res 339(1):123–131

    Google Scholar 

  • Yang H, Yan R, Chen H, Dong Ho L, Zheng C (2007) Characteristics of hemicellulose, cellulose and lignin pyrolysis. Fuel, (in press)

Download references

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Correspondence to Analia Vázquez.

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Morán, J.I., Alvarez, V.A., Cyras, V.P. et al. Extraction of cellulose and preparation of nanocellulose from sisal fibers. Cellulose 15, 149–159 (2008). https://doi.org/10.1007/s10570-007-9145-9

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  • DOI: https://doi.org/10.1007/s10570-007-9145-9

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