Catalysis Surveys from Asia

, Volume 20, Issue 1, pp 53–58 | Cite as

Poisoning Deactivation of Mesoporous Titanosilicate-Supported WO3 During Metathesis of Butene to Propene

  • Derun Hua
  • Shengli Chen
  • Zheng Zhou
  • Xinning Lu
  • Jian Li
Article
First Online:

Abstract

Deactivation by poisoning is studied in the metathesis of 2-butene to propene on mesoporous titanosilicate-supported WO3 (WO3/MTS–9), for which we focus on the effect of polar organic oxygenates on the activity of the catalyst. It is found that deactivation is strongly influenced by these oxygenates in feedstock, and the rate of deactivation increases with the increase of the polarity of the organic oxygenates. The deactivation by poisoning is reversible. The deactivation catalyst can be recovered by treatment in a nitrogen atmosphere at a high temperature.

Keywords

Deactivation Metathesis Poisoning 
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Notes

Acknowledgments

The authors are grateful for the financial supports from the National Natural Science Foundation of China (No. 21466001).

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Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  • Derun Hua
    • 1
    • 2
  • Shengli Chen
    • 2
  • Zheng Zhou
    • 3
  • Xinning Lu
    • 1
  • Jian Li
    • 1
  1. 1.College of Chemistry and Chemical EngineeringGannan Normal UniversityJiangxiChina
  2. 2.State Key Laboratory of Heavy Oil, College of Chemical Science and EngineeringChina University of PetroleumBeijingPeople’s Republic of China
  3. 3.Natural Gas Processing Plant of SINOPEC Zhongyuan Oilfield BranchPuyangChina

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