Catalysis Surveys from Asia

, Volume 19, Issue 1, pp 17–24 | Cite as

Low-Temperature Synthesis of Ruddlesden–Popper Type Layered Perovskite LaxCa3−xMn2O7 for Methane Combustion

Article
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Abstract

In comparison to the conventional high temperature (≥1,300 °C) preparation conditions, a series of Ruddlesden–Popper (R–P) type layered perovskite LaxCa3−xMn2O7 (x = 0.8, 1.0, 1.2, 1.5, 2.0, 2.5, and 3.0) were synthesized at 700 °C by an improved method based on the strategy involving the “inductive effect of Cl”. XRD results revealed the unitary R–P type layered perovskite structure in the samples of x = 0.8, 1.0, 1.2, and 3.0. While in the samples of x = 1.5, 2.0, and 2.5, the layered perovskite phase and lanthanum oxide phase coexisted, which resulted in their poor redox properties. XPS and H2-TPR results demonstrated that the redox properties of LaxCa3−xMn2O7 were correlated with its structural integrity and purity and influenced by the x value. The sample of x = 1.2 gave the highest methane combustion activity with T 50 = 449 °C, and the sample of x = 2.0 showed the lowest activity with T 50 = 538 °C, which was in accordance with the XPS and H2-TPR results. The specific surface areas of LaxCa3−xMn2O7 depended on the x value monotonically, and the sample of x = 0.8 presented the highest surface area value (33.59 m2 g−1).

Keywords

Ruddlesden–Popper type layered perovskite LaxCa3-xMn2O7 Methane Catalytic combustion 
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Supplementary material

10563_2014_9178_MOESM1_ESM.docx (171 kb)
Supplementary material 1 (DOCX 170 kb)

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Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  1. 1.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical PhysicsChinese Academy of SciencesLanzhouPeople’s Republic of China
  2. 2.University of Chinese Academy of SciencesBeijingPeople’s Republic of China

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