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Catalysis Letters

, Volume 149, Issue 12, pp 3304–3311 | Cite as

Effect of Mono-, Di-, and Triethylene Glycol on the Sulfidation Behavior of NiMo(P)/Al2O3 Hydrotreating Catalysts

  • A. L. NuzhdinEmail author
  • G. A. Bukhtiyarova
  • P. E. Plyusnin
  • A. A. Porsin
  • V. I. Bukhtiyarov
Article
  • 79 Downloads

Abstract

The effect of ethylene glycol (EG), diethylene glycol (DEG), and triethylene glycol (TEG) on the sulfidation behavior of phosphate-doped NiMo/Al2O3 hydrotreating catalysts has been investigated. The catalyst prepared with DEG shows a higher activity in the hydrodesulphurization of straight-run gas oil than other catalysts due to more efficient sulfidation at the low-temperature stage.

Graphic Abstract

Keywords

Heterogeneous catalysis Environmental catalysis Hydrodesulfurization Phosphate-doped NiMo/Al2O3 catalyst Sulfidation Ethylene glycol Diethylene glycol Triethylene glycol Dimethyl disulfide Thermogravimetric analysis 

Notes

Acknowledgements

The authors are grateful to Dr. I. V. Deliy for assistance in this study. The work was supported by the Ministry of Education and Science of the Russian Federation, Project No. 14.575.21.0128, Unique Identification Number RFMEFI57517X0128.

Supplementary material

10562_2019_2898_MOESM1_ESM.docx (3 mb)
Supplementary material 1 (DOCX 3078 kb)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  • A. L. Nuzhdin
    • 1
    Email author
  • G. A. Bukhtiyarova
    • 1
    • 2
  • P. E. Plyusnin
    • 2
    • 3
  • A. A. Porsin
    • 1
  • V. I. Bukhtiyarov
    • 1
    • 2
  1. 1.Boreskov Institute of Catalysis SB RASNovosibirskRussia
  2. 2.Novosibirsk National Research UniversityNovosibirskRussia
  3. 3.Nikolaev Institute of Inorganic Chemistry SB RASNovosibirskRussia

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