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Journey on Greener Pathways via Synthesis of Pd/KB Polymeric Nanocomposite as a Recoverable Catalyst for the Ligand-Free Oxidative Hydroxylation of Phenylboronic Acid and Suzuki–Miyaura Coupling Reaction in Green Solvents

  • Bahareh Feizi Mohazzab
  • Babak Jaleh
  • Mahmoud Nasrollahzadeh
  • Zahra Issaabadi
Article
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Abstract

This paper reports a new and straightforward technique for the preparation of catalytically active palladium nanoparticle (Pd NPs) supported on the polymer surface derived from virgin polythene (Kaldnes Bio media filter) (Pd/KB nanocomposite). The morphology, structure and composition of Pd/KB nanocomposite were characterized by SEM, TEM, XRD, EDX and UV–Vis spectroscopy. The as-prepared catalyst presented excellent catalytic activity for the ligand-free oxidative hydroxylation of phenylboronic acid and Suzuki–Miyaura coupling reaction in water and ethanol as green solvents. In addition, the catalyst could be easily separated from the reaction mixture and reused four times with no loss of activity. The advantages of this eco-friendly protocol are using the cheap, clean, and nontoxic precursors, simple reaction setup, high yield of products and elimination of ligand and homogeneous catalysts.

Graphical Abstract

Keywords

Pd/KB nanocomposite Kaldnes Bio media filter Recoverable catalyst Hydroxylation Suzuki–Miyaura 

Notes

Acknowledgements

We gratefully acknowledge from the Iranian Nano Council, Bu-Ali Sina University and University of Qom for the support of this work.

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • Bahareh Feizi Mohazzab
    • 1
  • Babak Jaleh
    • 1
  • Mahmoud Nasrollahzadeh
    • 2
  • Zahra Issaabadi
    • 2
  1. 1.Department of Physics, Faculty of ScienceBu-Ali Sina UniversityHamedanIran
  2. 2.Department of Chemistry, Faculty of ScienceUniversity of QomQomIran

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