Hydrodenitrogenation of Quinoline and Decahydroquinoline Over a Surface Nickel Phosphosulfide Phase

  • Song Tian
  • Xiang Li
  • Anjie Wang
  • Yongying Chen
  • Huateng Li
  • Yongkang Hu
Article
  • 45 Downloads

Abstract

The hydrodenitrogenation (HDN) of quinolone (Q) and decahydroquinoline (DHQ) over a Ni2P catalyst prepared by the reduction of a conventional phosphate precursor and a surface nickel phosphosulfide phase (Ni2P–S) obtained by the reduction of Ni2P2S6 were studied. A reaction network of the HDN of Q over Ni2P was proposed. Both the hydrogenation and C–N bond cleavage activities of Ni2P were enhanced after the introduction of sulfur. The surface sulfur species of Ni2P–S changed significantly after the HDN of DHQ. The thiolate or thiol species were detected as the major sulfur-containing species in the surface of the spent Ni2P–S catalyst.

Graphical Abstract

Keywords

Ni2Nickel phosphosulfide phase Quinoline Decahydroquinoline Hydrodenitrogenation Hydrogenation C–N bond cleavage 

Notes

Acknowledgements

This work was financially supported by the Natural Science Foundation of China (21473017 and 21673029), the United Funds of NSFC-Liaoning (U1508205), and the Liaoning Provincial Natural Science Foundation of China (201602158).

Supplementary material

10562_2018_2370_MOESM1_ESM.doc (841 kb)
Supplementary material 1 (DOC 841 KB)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • Song Tian
    • 1
    • 2
  • Xiang Li
    • 1
    • 2
    • 3
  • Anjie Wang
    • 1
    • 2
    • 3
  • Yongying Chen
    • 1
    • 2
  • Huateng Li
    • 4
  • Yongkang Hu
    • 1
    • 2
  1. 1.State Key Laboratory of Fine Chemicals, School of Chemical EngineeringDalian University of TechnologyDalianPeople’s Republic of China
  2. 2.Liaoning Key Laboratory of Petrochemical Technology and EquipmentsDalian University of TechnologyDalianPeople’s Republic of China
  3. 3.Penn State and Dalian University of Technology Joint Center for Energy Research (JCER)Dalian University of TechnologyDalianPeople’s Republic of China
  4. 4.School of Chemistry and Chemical EngineeringUniversity of JinanJinanPeople’s Republic of China

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