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Catalysis Letters

, Volume 148, Issue 4, pp 1162–1168 | Cite as

Iron Catalyzed CO2 Activation with Organosilanes

  • Tamara Jurado-Vázquez
  • Juventino J. García
Article

Abstract

Iron nanoparticles generated in situ from [Fe3(CO)12] catalyzed CO2 reduction in the presence of Et3SiH as a reductant and tetrabutylammonium fluoride as a promoter to yield silyl formate (1s) under relatively mild reaction conditions. Additionally, when CO2 hydrosilylation was carried out in water, the product of CO2 reduction was formic acid. Additionally, a similar reaction using [Fe3(CO)12] as a catalytic precursor, PhSiH3 as a reductant, and CO2 in the presence of amines allowed the immediate formation of ureas at room temperature. Here, CO2 acted as a C1 building block for value-added products.

Graphical Abstract

Keywords

Carbon dioxide Reduction Silane Formate Iron Nanoparticles Urea Catalysis 

Notes

Acknowledgements

We thank CONACYT 178265 and PAPIIT-DGAPA-UNAM 202516 for their financial support of this work. T. J-V. thanks CONACYT (583731) for graduate studies grant. We also thank Dr. Alma Arévalo for her technical assistance.

Supplementary material

10562_2018_2305_MOESM1_ESM.pdf (547 kb)
Supplementary material 1 (PDF 546 KB)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Facultad de QuímicaUniversidad Nacional Autónoma de MéxicoMexico CityMexico

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