Catalysis Letters

, Volume 147, Issue 9, pp 2247–2259 | Cite as

Surface Organometallic Chemistry: Paving the Way Beyond Well-Defined Supported Organometallics and Single-Site Catalysis

  • Christophe Copéret
  • Alexey Fedorov
  • Pavel A. Zhizhko
Article

Abstract

The molecular approach to single-site and nanoparticle-based heterogeneous catalysts relies on a stringent control over the surface chemistry, enabled by the judicious choice of dehydroxylated supports and tailored organometallic precursors. Aided by the advanced characterization methods, the field of surface organometallic chemistry (SOMC) has provided molecular-level insights into the mechanism and the nature of active sites of various industrial catalysts. The development of SOMC over the last decades yielded supported catalysts outperforming their homogeneous precursors and provided design principles for catalyst development. Applying the rational structure-activity approach of homogeneous catalysis to the surface species leads to further advances of SOMC, including functional materials for sustainable chemistry, energy storage and imaging, to mention just a few.

Graphical Abstract

Keywords

Heterogeneous catalysis Petrochemical catalysis Reaction intermediates  (MAS)NMR Spectroscopy and general characterization 

References

  1. 1.
    Somorjai GA, Li Y (2010) Introduction to surface chemistry and catalysis. 2nd edn. John Wiley & Sons, Inc., Hoboken, New JerseyGoogle Scholar
  2. 2.
    Ertl G (2009) Reactions at solid surfaces. John Wiley & Sons, Inc., HobokenCrossRefGoogle Scholar
  3. 3.
    Ertl G (1990) Angew Chem Int Ed 29:1219CrossRefGoogle Scholar
  4. 4.
    Chiusoli GP, Maitlis PM (eds) (2006) Metal-catalysis in industrial organic processes. The Royal Society of Chemistry, CambridgeGoogle Scholar
  5. 5.
    Bhaduri S, Mukesh D (2002) Homogeneous catalysis: mechanisms and industrial applications. John Wiley & Sons, Inc, New YorkGoogle Scholar
  6. 6.
    Parshall GW, Ittel SD (1992) Homogeneous catalysis: the applications and chemistry of catalysis by soluble transition metal complexes, 2nd edn. John Wiley & Sons Inc, New YorkGoogle Scholar
  7. 7.
    Candlin JP, Thomas H (1974) Adv Chem Ser 132:212CrossRefGoogle Scholar
  8. 8.
    Ballard DGH (1975) J Polym Sci Polym Chem 13:2191CrossRefGoogle Scholar
  9. 9.
    Yermakov YI (1976) Catal Rev Sci Eng 13:77CrossRefGoogle Scholar
  10. 10.
    Yermakov YI, Kuznetsov BN, Zakharov VA (1981) Catalysis by supported complexes. Elsevier, AmsterdamGoogle Scholar
  11. 11.
    Basset JM, Choplin A (1983) J Mol Catal 21:95CrossRefGoogle Scholar
  12. 12.
    Iwasawa Y (1987) Adv Catal 35:187Google Scholar
  13. 13.
    Gates BC, Lamb HH (1989) J Mol Catal 52:1CrossRefGoogle Scholar
  14. 14.
    Copéret C, Chabanas M, Petroff Saint-Arroman R, Basset J-M (2003) Angew Chem Int Ed 42:156CrossRefGoogle Scholar
  15. 15.
    Basset JM, Candy JP, Copéret C (2007) Surface organometallic chemistry. In: Crabtree RH, Mingos DMP (eds) Comprehensive organometallic chemistry III, Elsevier, Oxford, p 499CrossRefGoogle Scholar
  16. 16.
    Copéret C, Comas-Vives A, Conley MP, Estes DP, Fedorov A, Mougel V, Nagae H, Núñez-Zarur F, Zhizhko PA (2016) Chem Rev 116:323CrossRefGoogle Scholar
  17. 17.
    Pelletier JDA, Basset J-M (2016) Acc Chem Res 49:664CrossRefGoogle Scholar
  18. 18.
    Anwander R (2001) Chem Mater 13:4419CrossRefGoogle Scholar
  19. 19.
    Liang Y, Anwander R (2013) Dalton Trans 42:12521CrossRefGoogle Scholar
  20. 20.
    Wegener SL, Marks TJ, Stair PC (2012) Acc Chem Res 45:206CrossRefGoogle Scholar
  21. 21.
    Stalzer MM, Delferro M, Marks TJ (2015) Catal Lett 145:3CrossRefGoogle Scholar
  22. 22.
    Serna P, Gates BC (2014) Acc Chem Res 47:2612CrossRefGoogle Scholar
  23. 23.
    Rimoldi M, Mezzetti A (2014) Catal Sci Technol 4:2724CrossRefGoogle Scholar
  24. 24.
    Coperet C (2007) Dalton Trans 5498Google Scholar
  25. 25.
    Popoff N, Mazoyer E, Pelletier J, Gauvin RM, Taoufik M (2013) Chem Soc Rev 42:9035CrossRefGoogle Scholar
  26. 26.
    Jarupatrakorn J, Tilley TD (2002) J Am Chem Soc 124:8380CrossRefGoogle Scholar
  27. 27.
    Ruddy DA, Tilley TD (2007) Chem Commun 3350Google Scholar
  28. 28.
    Thornburg NE, Thompson AB, Notestein JM (2015) ACS Catal 5:5077CrossRefGoogle Scholar
  29. 29.
    Maschmeyer T, Rey F, Sankar G, Thomas JM (1995) Nature 378:159CrossRefGoogle Scholar
  30. 30.
    Fujdala KL, Tilley TD (2003) J Catal 216:265CrossRefGoogle Scholar
  31. 31.
    Zhuravlev LT (2000) Colloids Surf A 173:1CrossRefGoogle Scholar
  32. 32.
    Schrock RR, DePue RT, Feldman J, Yap KB, Yang DC, Davis WM, Park L, DiMare M, Schofield M (1990) Organometallics 9:2262CrossRefGoogle Scholar
  33. 33.
    Lopez LPH, Schrock RR (2004) J Am Chem Soc 126:9526CrossRefGoogle Scholar
  34. 34.
    Arndt S, Schrock RR, Müller P (2007) Organometallics 26:1279CrossRefGoogle Scholar
  35. 35.
    Lopez LPH, Schrock RR, Müller P (2008) Organometallics 27:3857CrossRefGoogle Scholar
  36. 36.
    Blanc F, Coperet C, Thivolle-Cazat J, Basset JM, Lesage A, Emsley L, Sinha A, Schrock RR (2006) Angew Chem Int Ed 45:1216CrossRefGoogle Scholar
  37. 37.
    Wegener SL, Kim H, Marks TJ, Stair PC (2011) J Phys Chem Lett 2:170CrossRefGoogle Scholar
  38. 38.
    Kulkarni A, Lobo-Lapidus RJ, Gates BC (2010) Chem Commun 46:5997CrossRefGoogle Scholar
  39. 39.
    Holmes SA, Quignard F, Choplin A, Teissier R, Kervennal J (1998) J Catal 176:173CrossRefGoogle Scholar
  40. 40.
    Yang Q, Copéret C, Li C, Basset J-M (2003) New J Chem 27:319CrossRefGoogle Scholar
  41. 41.
    Sensarma S, Bouh AO, Scott SL, Alper H (2003) J Mol Catal A 203:145CrossRefGoogle Scholar
  42. 42.
    Nicholas CP, Ahn H, Marks TJ (2003) J Am Chem Soc 125:4325CrossRefGoogle Scholar
  43. 43.
    Finch WC, Gillespie RD, Hedden D, Marks TJ (1990) J Am Chem Soc 112:6221CrossRefGoogle Scholar
  44. 44.
    Dahmen KH, Hedden D, Burwell RL, Marks TJ (1988) Langmuir 4:1212CrossRefGoogle Scholar
  45. 45.
    Jezequel M, Dufaud V, Ruiz-Garcia MJ, Carrillo-Hermosilla F, Neugebauer U, Niccolai GP, Lefebvre F, Bayard F, Corker J, Fiddy S, Evans J, Broyer J-P, Malinge J, Basset J-M (2001) J Am Chem Soc 123:3520CrossRefGoogle Scholar
  46. 46.
    Millot N, Soignier S, Santini CC, Baudouin A, Basset JM (2006) J Am Chem Soc 128:9361CrossRefGoogle Scholar
  47. 47.
    Amor Nait Ajjou J, Scott SL (2000) J Am Chem Soc 122:8968CrossRefGoogle Scholar
  48. 48.
    Zakharov VA, Yermakov YI (1979) Catal Rev Sci Eng 19:67CrossRefGoogle Scholar
  49. 49.
    Blanc F, Berthoud R, Salameh A, Basset JM, Coperet C, Singh R, Schrock RR (2007) J Am Chem Soc 129:8434CrossRefGoogle Scholar
  50. 50.
    Blanc F, Thivolle-Cazat J, Basset JM, Coperet C, Hock AS, Tonzetich ZJ, Schrock RR (2007) J Am Chem Soc 129:1044CrossRefGoogle Scholar
  51. 51.
    Rendon N, Berthoud R, Blanc F, Gajan D, Maishal T, Basset JM, Coperet C, Lesage A, Emsley L, Marinescu SC, Singh R, Schrock RR (2009) Chem Eur J 15:5083CrossRefGoogle Scholar
  52. 52.
    Conley MP, Mougel V, Peryshkov DV, Forrest WP Jr, Gajan D, Lesage A, Emsley L, Coperet C, Schrock RR (2013) J Am Chem Soc 135:19068CrossRefGoogle Scholar
  53. 53.
    Conley MP, Forrest WP, Mougel V, Coperet C, Schrock RR (2014) Angew Chem Int Ed 53:14221CrossRefGoogle Scholar
  54. 54.
    Mougel V, Pucino M, Copéret C (2015) Organometallics 34:551CrossRefGoogle Scholar
  55. 55.
    Mougel V, Copéret C (2015) ACS Catal 5:6436CrossRefGoogle Scholar
  56. 56.
    Mougel V, Santiago CB, Zhizhko PA, Bess EN, Varga J, Frater G, Sigman MS, Coperet C (2015) J Am Chem Soc 137:6699CrossRefGoogle Scholar
  57. 57.
    Pucino M, Mougel V, Schowner R, Fedorov A, Buchmeiser MR, Copéret C (2016) Angew Chem Int Ed 55:4300CrossRefGoogle Scholar
  58. 58.
    Grekov D, Bouhoute Y, Szeto KC, Merle N, De Mallmann A, Lefebvre F, Lucas C, Del Rosal I, Maron L, Gauvin RM, Delevoye L, Taoufik M (2016) Organometallics 35:2188CrossRefGoogle Scholar
  59. 59.
    Merle N, Le Quéméner F, Bouhoute Y, Szeto KC, De Mallmann A, Barman S, Samantaray MK, Delevoye L, Gauvin RM, Taoufik M, Basset JM (2017) J Am Chem Soc 139:2144CrossRefGoogle Scholar
  60. 60.
    Chabanas M, Baudouin A, Coperet C, Basset JM, Lukens W, Lesage A, Hediger S, Emsley L (2003) J Am Chem Soc 125:492CrossRefGoogle Scholar
  61. 61.
    Chabanas M, Coperet C, Basset JM (2003) Chem Eur J 9:971CrossRefGoogle Scholar
  62. 62.
    Solans-Monfort X, Clot E, Coperet C, Eisenstein O (2005) J Am Chem Soc 127:14015CrossRefGoogle Scholar
  63. 63.
    Poater A, Solans-Monfort X, Clot E, Coperet C, Eisenstein O (2007) J Am Chem Soc 129:8207CrossRefGoogle Scholar
  64. 64.
    Singh R, Schrock RR, Müller P, Hoveyda AH (2007) J Am Chem Soc 129:12654CrossRefGoogle Scholar
  65. 65.
    Mougel V, Chan K-W, Siddiqi G, Kawakita K, Nagae H, Tsurugi H, Mashima K, Safonova O, Copéret C (2016) ACS Cent Sci 2:569CrossRefGoogle Scholar
  66. 66.
    Copéret C, Estes DP, Larmier K, Searles K (2016) Chem Rev 116:8463CrossRefGoogle Scholar
  67. 67.
    Basset J-M, Coperet C, Soulivong D, Taoufik M, Cazat JT (2010) Acc Chem Res 43:323CrossRefGoogle Scholar
  68. 68.
    Conley MP, Delley MF, Siddiqi G, Lapadula G, Norsic S, Monteil V, Safonova OV, Coperet C (2014) Angew Chem Int Ed 53:1872CrossRefGoogle Scholar
  69. 69.
    Delley MF, Nunez-Zarur F, Conley MP, Comas-Vives A, Siddiqi G, Norsic S, Monteil V, Safonova OV, Coperet C (2014) Proc Natl Acad Sci USA 111:11624CrossRefGoogle Scholar
  70. 70.
    Estes DP, Siddiqi G, Allouche F, Kovtunov KV, Safonova OV, Trigub AL, Koptyug IV, Copéret C (2016) J Am Chem Soc 138:14987CrossRefGoogle Scholar
  71. 71.
    Searles K, Siddiqi G, Safonova OV, Copéret C (2017) Chem Sci 8:2661CrossRefGoogle Scholar
  72. 72.
    Allouche F, Lapadula G, Siddiqi G, Lukens WW, Maury O, Le Guennic B, Pointillart F, Dreiser J, Mougel V, Cador O, Copéret C (2017) ACS Cent Sci 3:244CrossRefGoogle Scholar
  73. 73.
    Lapadula G, Bourdolle A, Allouche F, Conley MP, del Rosal I, Maron L, Lukens WW, Guyot Y, Andraud C, Brasselet S, Copéret C, Maury O, Andersen RA (2014) Chem Mater 26:1062CrossRefGoogle Scholar
  74. 74.
    Lapadula G, Trummer D, Conley MP, Steinmann M, Ran YF, Brasselet S, Guyot Y, Maury O, Decurtins S, Liu SX, Coperet C (2015) Chem Mater 27:2033CrossRefGoogle Scholar
  75. 75.
    McDaniel MP (2010) Adv Catal 53:123Google Scholar
  76. 76.
    Przhevalskaya LK, Shvets VA, Kazansky VB (1975) J Catal 39:363CrossRefGoogle Scholar
  77. 77.
    Myers DL, Lunsford JH (1986) J Catal 99:140CrossRefGoogle Scholar
  78. 78.
    Floryan L, Borosy AP, Núñez-Zarur F, Comas-Vives A, Copéret C (2017) J Catal 346:50CrossRefGoogle Scholar
  79. 79.
    Amakawa K, Sun L, Guo C, Hävecker M, Kube P, Wachs IE, Lwin S, Frenkel AI, Patlolla A, Hermann K, Schlögl R, Trunschke A (2013) Angew Chem Int Ed 52:13553CrossRefGoogle Scholar
  80. 80.
    Delley MF, Silaghi M-C, Nuñez-Zarur F, Kovtunov KV, Salnikov OG, Estes DP, Koptyug IV, Comas-Vives A, Copéret C (2017) Organometallics 36:234CrossRefGoogle Scholar
  81. 81.
    Conley MP, Delley MF, Nunez-Zarur F, Comas-Vives A, Coperet C (2015) Inorg Chem 54:5065CrossRefGoogle Scholar
  82. 82.
    Yermakov Y, Zakharov V (1975) Adv Catal 24:173Google Scholar
  83. 83.
    Mol JC (1999) Catal Today 51:289CrossRefGoogle Scholar
  84. 84.
    Valla M, Wischert R, Comas-Vives A, Conley MP, Verel R, Copéret C, Sautet P (2016) J Am Chem Soc 138:6774CrossRefGoogle Scholar
  85. 85.
    Salameh A, Joubert J, Baudouin A, Lukens W, Delbecq F, Sautet P, Basset JM, Coperet C (2007) Angew Chem Int Ed 46:3870CrossRefGoogle Scholar
  86. 86.
    Lwin S, Keturakis C, Handzlik J, Sautet P, Li Y, Frenkel AI, Wachs IE (2015) ACS Catal 5:1432CrossRefGoogle Scholar
  87. 87.
    Wischert R, Laurent P, Copéret C, Delbecq F, Sautet P (2012) J Am Chem Soc 134:14430CrossRefGoogle Scholar
  88. 88.
    Valla M, Stadler D, Mougel V, Copéret C (2016) Angew Chem Int Ed 55:1124CrossRefGoogle Scholar
  89. 89.
    Margossian T, Larmier K, Kim SM, Krumeich F, Fedorov A, Chen P, Muller CR, Coperet C (2017) J Am Chem Soc 139:6919CrossRefGoogle Scholar
  90. 90.
    Baudouin D, Margossian T, Rodemerck U, Webb PB, Veyre L, Krumeich F, Candy J-P, Thieuleux C, Copéret C (2017) ChemCatChem 9:586CrossRefGoogle Scholar
  91. 91.
    Lappert M, Protchenko A, Power P, Seeber A (2008) Metal amide chemistry. John Wiley & Sons, Ltd, New YorkCrossRefGoogle Scholar
  92. 92.
    Oakton E, Vile G, Levine DS, Zocher E, Baudouin D, Perez-Ramirez J, Coperet C (2014) Dalton Trans 43:15138CrossRefGoogle Scholar
  93. 93.
    Gajan D, Guillois K, Delichere P, Basset JM, Candy JP, Caps V, Coperet C, Lesage A, Emsley L (2009) J Am Chem Soc 131:14667CrossRefGoogle Scholar
  94. 94.
    Furman K, Baudouin D, Margossian T, Sabnis KD, Cui Y, Ribeiro FH, Copéret C (2015) J Catal 324:9CrossRefGoogle Scholar
  95. 95.
    Héroguel F, Siddiqi G, Detwiler MD, Zemlyanov DY, Safonova OV, Copéret C (2015) J Catal 321:81CrossRefGoogle Scholar
  96. 96.
    Heroguel F (2014) Controlled growth and interfaces of supported metal nanoparticles from late transition metal siloxides. PhD Thesis, ETH. ZürichGoogle Scholar
  97. 97.
    Alphazan T, Bonduelle-Skrzypczak A, Legens C, Gay A-S, Boudene Z, Girleanu M, Ersen O, Copéret C, Raybaud P (2014) ACS Catal 4:4320CrossRefGoogle Scholar
  98. 98.
    Fujdala KL, Drake IJ, Bell AT, Tilley TD (2004) J Am Chem Soc 126:10864CrossRefGoogle Scholar
  99. 99.
    Roussey A, Gentile P, Lafond D, Martinez E, Jousseaume V, Thieuleux C, Coperet C (2013) J Mater Chem C 1:1583CrossRefGoogle Scholar
  100. 100.
    Larmier K, Liao W-C, Tada S, Lam E, Verel R, Bansode A, Urakawa A, Comas-Vives A, Copéret C (2017) Angew Chem Int Ed 56:2318CrossRefGoogle Scholar
  101. 101.
    Comas-Vives A, Larmier K, Coperet C (2017) Chem Commun 53:4296CrossRefGoogle Scholar
  102. 102.
    Rhodes MD, Bell AT (2005) J Catal 233:198CrossRefGoogle Scholar
  103. 103.
    Rhodes MD, Pokrovski KA, Bell AT (2005) J Catal 233:210CrossRefGoogle Scholar
  104. 104.
    Hagemeyer A, Volpe A (eds) (2014) Modern applications of high throughput R&D in heterogeneous catalysis. Bentham eBooks, SharjahGoogle Scholar
  105. 105.
    Estes DP, Bittner C, Àrias Ò, Casey M, Fedorov A, Tamm M, Copéret C (2016) Angew Chem Int Ed 55:13960CrossRefGoogle Scholar
  106. 106.
    Engl PS, Fedorov A, Copéret C, Togni A (2016) Organometallics 35:887CrossRefGoogle Scholar
  107. 107.
    Fedorov A, Liu H-J, Lo H-K, Copéret C (2016) J Am Chem Soc 138:16502CrossRefGoogle Scholar
  108. 108.
    Salnikov OG, Liu H-J, Fedorov A, Burueva DB, Kovtunov KV, Coperet C, Koptyug IV (2017) Chem Sci 8:2426CrossRefGoogle Scholar
  109. 109.
    Wind RA, Duijvestijn MJ, van der Lugt C, Manenschijn A, Vriend J (1985) Prog Nucl Magn Reson Spectrosc 17:33CrossRefGoogle Scholar
  110. 110.
    Bajaj VS, Farrar CT, Hornstein MK, Mastovsky I, Vieregg J, Bryant J, Eléna B, Kreischer KE, Temkin RJ, Griffin RG (2003) J Magn Reson 160:85CrossRefGoogle Scholar
  111. 111.
    Hu K-N, Yu H-h, Swager TM, Griffin RG (2004) J Am Chem Soc 126:10844CrossRefGoogle Scholar
  112. 112.
    Rossini AJ, Zagdoun A, Lelli M, Lesage A, Copéret C, Emsley L (2013) Acc Chem Res 46:1942CrossRefGoogle Scholar
  113. 113.
    Lelli M, Gajan D, Lesage A, Caporini MA, Vitzthum V, Mieville P, Heroguel F, Rascon F, Roussey A, Thieuleux C, Boualleg M, Veyre L, Bodenhausen G, Coperet C, Emsley L (2011) J Am Chem Soc 133:2104CrossRefGoogle Scholar
  114. 114.
    Lesage A, Lelli M, Gajan D, Caporini MA, Vitzthum V, Miéville P, Alauzun J, Roussey A, Thieuleux C, Mehdi A, Bodenhausen G, Coperet C, Emsley L (2010) J Am Chem Soc 132:15459CrossRefGoogle Scholar
  115. 115.
    Kubicki DJ, Casano G, Schwarzwalder M, Abel S, Sauvee C, Ganesan K, Yulikov M, Rossini AJ, Jeschke G, Coperet C, Lesage A, Tordo P, Ouari O, Emsley L (2016) Chem Sci 7:550CrossRefGoogle Scholar
  116. 116.
    Kobayashi T, Perras FA, Slowing II, Sadow AD, Pruski M (2015) ACS Catal 5:7055CrossRefGoogle Scholar
  117. 117.
    Copéret C, Liao W-C, Gordon C, Ong T-C (2017) J Am Chem Soc. doi:10.1021/jacs.6b12981
  118. 118.
    Valla M, Rossini AJ, Caillot M, Chizallet C, Raybaud P, Digne M, Chaumonnot A, Lesage A, Emsley L, van Bokhoven JA, Copéret C (2015) J Am Chem Soc 137:10710CrossRefGoogle Scholar
  119. 119.
    Mouat AR, George C, Kobayashi T, Pruski M, van Duyne RP, Marks TJ, Stair PC (2015) Angew Chem Int Ed 54:13346CrossRefGoogle Scholar
  120. 120.
    Gunther WR, Michaelis VK, Caporini MA, Griffin RG, Román-Leshkov Y (2014) J Am Chem Soc 136:6219CrossRefGoogle Scholar
  121. 121.
    Wolf P, Valla M, Rossini AJ, Comas-Vives A, Núñez-Zarur F, Malaman B, Lesage A, Emsley L, Copéret C, Hermans I (2014) Angew Chem Int Ed 53:10179CrossRefGoogle Scholar
  122. 122.
    Wolf P, Valla M, Núñez-Zarur F, Comas-Vives A, Rossini AJ, Firth C, Kallas H, Lesage A, Emsley L, Copéret C, Hermans I (2016) ACS Catal 6:4047CrossRefGoogle Scholar
  123. 123.
    Wolf P, Liao W-C, Ong T-C, Valla M, Harris JW, Gounder R, van der Graaff WNP, Pidko EA, Hensen EJM, Ferrini P, Dijkmans J, Sels B, Hermans I, Copéret C (2016) Helv Chim Acta 99:916CrossRefGoogle Scholar
  124. 124.
    Kobayashi T, Singappuli-Arachchige D, Wang Z, Slowing II, Pruski M (2017) Phys Chem Chem Phys 19:1781CrossRefGoogle Scholar
  125. 125.
    Johnson RL, Perras FA, Kobayashi T, Schwartz TJ, Dumesic JA, Shanks BH, Pruski M (2016) Chem Commun 52:1859CrossRefGoogle Scholar
  126. 126.
    Piveteau L, Ong T-C, Rossini AJ, Emsley L, Copéret C, Kovalenko MV (2015) J Am Chem Soc 137:13964CrossRefGoogle Scholar
  127. 127.
    Berruyer P, Lelli M, Conley MP, Silverio DL, Widdifield CM, Siddiqi G, Gajan D, Lesage A, Copéret C, Emsley L (2017) J Am Chem Soc 139:849CrossRefGoogle Scholar
  128. 128.
    Ong T-C, Liao W-C, Mougel V, Gajan D, Lesage A, Emsley L, Copéret C (2016) Angew Chem Int Ed 55:4743CrossRefGoogle Scholar
  129. 129.
    Frenken J, Groot I (eds) (2017) Operando research in heterogeneous catalysis. Springer series in chemical physics, vol 114. Springer International Publishing, ChamGoogle Scholar
  130. 130.
    Lwin S, Wachs IE (2014) ACS Catal 4:2505CrossRefGoogle Scholar
  131. 131.
    Weckhuysen BM (2002) Chem Commun 97Google Scholar
  132. 132.
    Botavina M, Barzan C, Piovano A, Braglia L, Agostini G, Martra G, Groppo E (2017) Catal Sci Technol 7:1690CrossRefGoogle Scholar
  133. 133.
    Hoffmann F, Froba M (2011) Chem Soc Rev 40:608CrossRefGoogle Scholar
  134. 134.
    Mizoshita N, Tani T, Inagaki S (2011) Chem Soc Rev 40:789CrossRefGoogle Scholar
  135. 135.
    Conley MP, Copéret C, Thieuleux C (2014) ACS Catal 4:1458CrossRefGoogle Scholar
  136. 136.
    Mathey L, Alphazan T, Valla M, Veyre L, Fontaine H, Enyedi V, Yckache K, Danielou M, Kerdiles S, Guerrero J, Barnes JP, Veillerot M, Chevalier N, Mariolle D, Bertin F, Durand C, Berthe M, Dendooven J, Martin F, Thieuleux C, Grandidier B, Coperet C (2015) J Phys Chem C 119:13750CrossRefGoogle Scholar
  137. 137.
    Alphazan T, Mathey L, Schwarzwälder M, Lin T-H, Rossini AJ, Wischert R, Enyedi V, Fontaine H, Veillerot M, Lesage A, Emsley L, Veyre L, Martin F, Thieuleux C, Copéret C (2016) Chem Mater 28:3634CrossRefGoogle Scholar
  138. 138.
    Rendón N, Bourdolle A, Baldeck PL, Le Bozec H, Andraud C, Brasselet S, Coperet C, Maury O (2011) Chem Mater 23:3228CrossRefGoogle Scholar
  139. 139.
    Delley MF, Lapadula G, Núñez-Zarur F, Comas-Vives A, Kalendra V, Jeschke G, Baabe D, Walter MD, Rossini AJ, Lesage A, Emsley L, Maury O, Copéret C (2017) J Am Chem Soc. doi:10.1021/jacs.7b02179
  140. 140.
    Rascon F, Wischert R, Coperet C (2011) Chem Sci 2:1449CrossRefGoogle Scholar
  141. 141.
    Karol FJ, Karapinka GL, Wu C, Dow AW, Johnson RN, Carrick WL (1972) J Polym Sci A-1 10:2621CrossRefGoogle Scholar
  142. 142.
    Somorjai GA, Li Y (2011) Proc Natl Acad Sci USA 108:917CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2017

Authors and Affiliations

  • Christophe Copéret
    • 1
  • Alexey Fedorov
    • 1
  • Pavel A. Zhizhko
    • 1
    • 2
  1. 1.Department of Chemistry and Applied BiosciencesETH ZürichZürichSwitzerland
  2. 2.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussia

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