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Palladium-Catalyzed Direct Ortho C–O bond construction of Azobenzenes with Iodobenzene diacetate via C–H Activation

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Abstract

Abstract

A method of direct synthesis of ortho-acyloxylated azoarenes via palladium-catalyzed C–H bond activation was developed. The reaction proceeded was smoothly at room temprature and have better yield in shorter times. The obtained ortho-acyloxylated azoarenes could be efficiently converted into 2-hydroxyazobenzenes in good yields through a hydrolysis process.

Graphical Abstract

Many various ortho-acyloxylated azoarenes were obtained in moderate to high yields by palladium-catalyzed direct C(sp2)-H acyloxylation of aromatic azo compounds with PhI(OAc)2

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Acknowledgements

This work was supported by the Zhejiang Provincial Natural Science Foundation of China (No. LZ13B020001) and Projects of Medical and Health Technology Development Program in Shandong Province (No. 2015WS0102).

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Authors and Affiliations

  1. Pharmacy College, Taishan Medical University, Tai’an, 271016, China

    Xiaopan Fu, Zhenjiang Wei, Chengcai Xia & Kai Wang

  2. College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou, 310036, China

    Chao Shen, Jun Xu, Yong Yang & Pengfei Zhang

  3. College of Biology and Environmental Engineering, Zhejiang Shuren University, Hangzhou, 310015, China

    Chao Shen

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  1. Xiaopan Fu
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Correspondence to Chengcai Xia.

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Fu, X., Wei, Z., Xia, C. et al. Palladium-Catalyzed Direct Ortho C–O bond construction of Azobenzenes with Iodobenzene diacetate via C–H Activation. Catal Lett 147, 400–406 (2017). https://doi.org/10.1007/s10562-016-1955-7

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  • DOI: https://doi.org/10.1007/s10562-016-1955-7

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