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Catalysis Letters

, Volume 146, Issue 3, pp 564–569 | Cite as

Achiral Cyclopentadienone Iron Tricarbonyl Complexes Embedded in Streptavidin: An Access to Artificial Iron Hydrogenases and Application in Asymmetric Hydrogenation

  • Delphine S. Mérel
  • Sylvain Gaillard
  • Thomas R. Ward
  • Jean-Luc Renaud
Article

Abstract

We report on the synthesis of biotinylated (cyclopentadienone)iron tricarbonyl complexes, the in situ generation of the corresponding streptavidin conjugates and their application in asymmetric hydrogenation of imines and ketones.

Graphical Abstract

Keywords

Homogeneous catalysis Hydrogenation Bio-inspired Asymmetric catalysis 

Notes

Acknowledgments

We gratefully acknowledge financial support from the “Ministère de la Recherche et des Nouvelles Technologies” for PhD grant for D.S.M., CNRS (Centre National de la Recherche Scientifique), the “Région Basse-Normandie”, the « CRUNCH » interregional network and the European Union (FEDER funding), and the LABEX SynOrg (ANR-11-LABX-0029). ERDF fundings (AI-Chem & INTERREG IVa program) are gratefully acknowledged for financial support.

Supplementary material

10562_2015_1681_MOESM1_ESM.pdf (15.6 mb)
Supplementary material 1 (PDF 15951 kb)

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Copyright information

© Springer Science+Business Media New York 2016

Authors and Affiliations

  1. 1.Normandie UniversityCaenFrance
  2. 2.Laboratoire de Chimie Moléculaire et ThioorganiqueUniversity of Caen Basse NormandieCaenFrance
  3. 3.CNRS, UMR 6507CaenFrance
  4. 4.Department of ChemistryUniversity of BaselBaselSwitzerland

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