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Catalysis Letters

, Volume 145, Issue 2, pp 511–518 | Cite as

Hydrogenolysis of a γ-Acetylated Lignin Model Compound with a Ruthenium–Xantphos Catalyst

  • Adam Wu
  • Jean Michel Lauzon
  • Brian R. JamesEmail author
Article

Abstract

Catalytic hydrogenolysis of a γ-acetylated dimer lignin model compound is effected using a Ru–xantphos catalyst. Mechanistic investigations show mono-aryl degradation products are generated from the β-O-4 substrate as well as a terminal alkene ketone dimer (bis-aryl) that further dimerizes to a tetra-aryl product. Preliminary results using an acetylated kraft lignin as a substrate are also discussed.

Graphical Abstract

Keywords

Acetylated lignin Hydrogenolysis Ruthenium Xantphos Lignin degradation 

Notes

Acknowledgments

We thank the NSERC Lignoworks Network for funding, Weyerhaeuser Co (Seattle, WA, USA) for supplying the acetylated lignin, and a reviewer for constructive comments.

Supplementary material

10562_2014_1401_MOESM1_ESM.docx (3.1 mb)
Supplementary material 1 (DOCX 3,163 kb)

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Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  1. 1.Department of ChemistryUniversity of British ColumbiaVancouverCanada

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