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Catalysis Letters

, Volume 144, Issue 9, pp 1487–1493 | Cite as

Photoelectrochemical Properties of CuCrO2: Characterization of Light Absorption and Photocatalytic H2 Production Performance

  • Yi Ma
  • Xin Zhou
  • Quanbao Ma
  • Anton Litke
  • Peng Liu
  • Yi Zhang
  • Can Li
  • Emiel J. M. Hensen
Article

Abstract

CuCrO2 delafossite was prepared by the solid-state reaction between Cr2O3 and Cu2O at high temperature (900–1100 °C). The materials were characterized by XRD, X-ray photoelectron, Raman and UV–Vis spectroscopy and transmission electron microscopy. The visible light absorption of the p-type semiconductor increased with increasing calcination temperature. First principles density functional theory calculations were used to compute the density of states and distinguish between Cr3+ d–d transitions and the charge separation electron transitions, which cannot be distinguished in CuCrO2 by UV–Vis spectroscopy. Photocathodes were prepared by depositing the as-prepared CuCrO2 on an FTO substrate by electrophoresis. The resulting cathodic photocurrents under visible light irradiation increased with increasing calcination temperature. CuCrO2 is a photostable semiconductor unlike Cu2O. Photocatalytic H2 production in ethanol/water mixtures shows that the resulting materials are active in water splitting. Co-catalysts substantially increase the activity, the most preferred one is Pt with an order of magnitude increase in performance.

Graphical Abstract

Keywords

Photocatalysis Photoelectrochemistry CuCrO2 H2 production Co-catalysts 

Notes

Acknowledgments

The authors acknowledge the financial support for this work from the Strategic Scientific Alliances Program between China and the Netherlands (2008DFB50130; 08-PSA-M-01).

Supplementary material

10562_2014_1318_MOESM1_ESM.docx (615 kb)
Supplementary material 1 (DOCX 615 kb)

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Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  • Yi Ma
    • 1
    • 2
  • Xin Zhou
    • 2
  • Quanbao Ma
    • 1
  • Anton Litke
    • 1
  • Peng Liu
    • 1
  • Yi Zhang
    • 1
  • Can Li
    • 2
  • Emiel J. M. Hensen
    • 1
  1. 1.Inorganic Materials Chemistry, Schuit Institute of CatalysisEindhoven University of TechnologyEindhovenThe Netherlands
  2. 2.State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Dalian National Laboratory for Clean EnergyChinese Academy of SciencesDalianPeople’s Republic of China

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