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Catalysis Letters

, Volume 144, Issue 8, pp 1407–1410 | Cite as

Enantioselective Ammonolysis of Phenylglycine Methyl Ester with Lipase–Pluronic Nanoconjugate in Tertiary Butanol

  • Xiaoling Wu
  • Rui Wang
  • Yifei Zhang
  • Jun GeEmail author
  • Zheng LiuEmail author
Article

Abstract

Asymmetrical ammonolysis of (R)- and (S)-phenylglycine methyl ester was carried out by using a lipase (CALB)–polymer (Pluronic) nanoconjugate as the catalyst, displaying a 11-fold increased catalytic rate compared to the free CALB in tertiary butanol.

Graphical Abstract

The asymmetrical ammonolysis of (R)- and (S)-phenylglycine methyl ester was accomplished using a lipase–Pluronic nanoconjugate, displaying a 11-fold higher catalytic rate compared to the free lipase.

Keywords

Enzymatic catalysis Nanoparticles Enzymes 

Notes

Acknowledgment

This work was supported by the National Natural Science Foundation of China under the Grant Number of 21206082 and 21036003.

Supplementary material

10562_2014_1289_MOESM1_ESM.doc (27 kb)
Supplementary material 1 (DOC 26 kb)

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Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  1. 1.Department of Chemical EngineeringTsinghua UniversityBeijingChina

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