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Catalysis Letters

, Volume 144, Issue 1, pp 104–111 | Cite as

Homogeneous Catalytic Oxidation of Olefins with Hydrogen Peroxide in the Presence of a Manganese-Substituted Polyoxomolybdate

  • Tiago A. G. Duarte
  • Isabel C. M. S. Santos
  • Mário M. Q. Simões
  • M. Graça P. M. S. Neves
  • Ana M. V. Cavaleiro
  • José A. S. Cavaleiro
Article

Abstract

[PMo11Mn(H2O)O39]5− is used as catalyst in the homogeneous oxidation of cis-cyclooctene, cyclohexene, styrene, and geraniol with H2O2 in acetonitrile. Oxidation of cis-cyclooctene gives only cyclooctene oxide; cyclohexene-1,2-diol is the main product for cyclohexene; styrene is preferentially oxidized to benzaldehyde; a TOF almost as high as 28800 h−1 is reached for geraniol oxidation.

Graphical Abstract

Keywords

Polyoxomolybdate Homogeneous catalysis Oxidation Hydrogen peroxide Olefins 

Notes

Acknowledgments

Thanks are due to Fundação para a Ciência e a Tecnologia (FCT, Portugal), European Union, QREN, FEDER and COMPETE for funding the QOPNA research unit (project PEst-C/QUI/UI0062/2011) and CICECO (PEst-C/CTM/LA0011/2011).

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Copyright information

© Springer Science+Business Media New York 2013

Authors and Affiliations

  • Tiago A. G. Duarte
    • 1
  • Isabel C. M. S. Santos
    • 1
  • Mário M. Q. Simões
    • 1
  • M. Graça P. M. S. Neves
    • 1
  • Ana M. V. Cavaleiro
    • 2
  • José A. S. Cavaleiro
    • 1
  1. 1.QOPNA, Departamento de QuímicaUniversidade de AveiroAveiroPortugal
  2. 2.CICECO, Departamento de QuímicaUniversidade de AveiroAveiroPortugal

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