Catalysis Letters

, Volume 142, Issue 3, pp 313–318 | Cite as

Chemical Vapor Deposition of Pd(C3H5)(C5H5) to Synthesize Pd@MOF-5 Catalysts for Suzuki Coupling Reaction

  • Mingming Zhang
  • Jingchao Guan
  • Bingsen Zhang
  • Dangsheng Su
  • Christopher T. Williams
  • Changhai Liang
Article
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Accepted:

Abstract

The highly porous metal organic framework MOF-5 was loaded with the metal–organic compound [Pd(C3H5)(C5H5)] by metal–organic chemical vapor deposition (MOCVD) method. The inclusion compound [Pd(C3H5)(C5H5)]@MOF-5 was characterized by powder X-ray diffraction (PXRD), Fourier-transform infrared (FT-IR) spectroscopy, and solid-state nuclear magnetic resonance spectroscopy. It was found that the host lattice of MOF-5 remained intact upon precursor insertion. The –C3H5 ligand in the precursor is easier to lose due to the interaction between palladium and the benzenedicarboxylate linker in MOF-5, providing a possible explanation for the irreversibility of the precursor adsorption. Pd nanoparticles of about 2–5 nm in size was formed inside the cavities of MOF-5 by hydrogenolysis of the inclusion compound [Pd(C3H5)(C5H5)]@MOF-5 at room temperature. N2 sorption of the obtained material confirmed that high surface area was retained. In the Suzuki coupling reaction the Pd@MOF-5 materials showed a good activity in the first catalytic run. However, the crystal structure of MOF-5 was completely destroyed during the following reaction runs, as confirmed by PXRD, which caused a big loss of the activity.

Graphical Abstract

The embedding of palladium nanoparticles into the metal organic framework MOF-5 has been successfully prepared by MOCVD method, and been used as catalyst for Suzuki reaction. The prepared Pd@MOF-5 had a very high BET surface area with Pd particles in size of 2–5 nm. The Pd@MOF-5 was used as a heterogeneous catalyst for the Suzuki coupling reaction and achieved a good activity. Open image in new window

Keywords

MOF-5 Palladium MOCVD Suzuki coupling 
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Notes

Acknowledgments

We gratefully acknowledge the financial support provided by the National Natural Science Foundation of China (No. 21073023). C.T.W. thanks Dalian University of Technology for a “Seasky” professorship.

References

  1. 1.
    Bauer CA, Timofeeva TV, Settersten TB, Patterson BD, Liu VH, Simmons BA, Allendorf MD (2007) J Am Chem Soc 129:7136CrossRefGoogle Scholar
  2. 2.
    Chen B, Yang Y, Zapata F, Lin G, Qian G, Lobkovsky EB (2007) Adv Mater 19:1693CrossRefGoogle Scholar
  3. 3.
    Horcajada P, Serre C, Vallet-Regí M, Sebban M, Taulelle F, Férey G (2006) Angew Chem Int Ed 45:5974CrossRefGoogle Scholar
  4. 4.
    Mueller U, Schubert M, Teich F, Puetter H, Schierle-Arndt K, Pastré J (2006) J Mater Chem 16:626CrossRefGoogle Scholar
  5. 5.
    Cho SH, Ma B, Nguyen ST, Hupp JT, Albrecht-Schmitt TE (2006) Chem Commun 24:2563CrossRefGoogle Scholar
  6. 6.
    Llabrés i Xamena FX, Abad A, Corma A, Garcia H (2007) J Catal 250:294CrossRefGoogle Scholar
  7. 7.
    Llabrés i Xamena FX, Xamena FX, Corma A, Garcia H (2007) J Phys Chem C 111:80CrossRefGoogle Scholar
  8. 8.
    Alaerts L, Seguin E, Poelman H, Thibault-Starzyk F, Jacobs PA, De Vos DE (2006) Chem Eur J 12:7353CrossRefGoogle Scholar
  9. 9.
    Opelt S, Türk S, Dietzsch E, Henschel A, Kaskel S, Klemm E (2008) Catal Commun 9:1286CrossRefGoogle Scholar
  10. 10.
    Sabo M, Henschel A, Fröede H, Klemm E, Kaskel S (2007) J Mater Chem 17:3827CrossRefGoogle Scholar
  11. 11.
    Schröder F, Esken D, Cokoja M, van den Berg MWE, Lebedev OI, Tendeloo GV, Walaszek B, Buntkowsky G, Limbach H, Chaudret B, Fischer RA (2008) J Am Chem Soc 130:6119CrossRefGoogle Scholar
  12. 12.
    Hermes S, Schröder MK, Schmid R, Khodeir L, Muhler M, Tissler A, Fischer RW, Fischer RA (2005) Angew Chem Int Ed 44:6237CrossRefGoogle Scholar
  13. 13.
    Perles LJ, Iglesias M, Martin-Luengo MA, Monge MA, Ruiz-Valero C, Snejko N (2005) Chem Mater 17:5837CrossRefGoogle Scholar
  14. 14.
    Schlichte K, Kratzke T, Kaskel S (2004) Microporous Mesoporous Mater 73:81CrossRefGoogle Scholar
  15. 15.
    Gao SX, Zhao N, Shu MH, Che SA (2010) Appl Catal A 388:196CrossRefGoogle Scholar
  16. 16.
    Miyaura N, Suzuki A (1995) Chem Rev 95:2457CrossRefGoogle Scholar
  17. 17.
    Stanforth SP (1998) Tetrahedron 54:263CrossRefGoogle Scholar
  18. 18.
    Han J, Liu Y, Guo R (2009) J Am Chem Soc 131:2060CrossRefGoogle Scholar
  19. 19.
    Li HL, Eddaoudi M, O’Keeffe M, Yaghi OM (1999) Nature 402:276CrossRefGoogle Scholar
  20. 20.
    Tranchemontagne DJ, Hunt JR, Yaghi OM (2008) Tetrahedron 64:8553CrossRefGoogle Scholar
  21. 21.
    Dent WT, Long R, Wilkinson AJ (1964) J Chem Soc 8:1585Google Scholar
  22. 22.
    Shaw BL (1960) Proc Chem Soc 7:247Google Scholar
  23. 23.
    Müller M, Lebedev OI, Fischer RA (2008) J Mater Chem 18:5274CrossRefGoogle Scholar
  24. 24.
    Jasmina H, Morten B, Unni O (2007) J Am Chem Soc 129:3612CrossRefGoogle Scholar
  25. 25.
    Wan Y, Wang H, Zhao Q, Klingstedt O, Terasaki O, Zhao D (2009) J Am Chem Soc 131:4541CrossRefGoogle Scholar
  26. 26.
    Esken D, Zhang XN, Lebedev OI, Schröder F, Fischer RA (2009) J Mater Chem 19:1314–1319CrossRefGoogle Scholar
  27. 27.
    Moddeman WE, Bowling WC, Carter DC, Grove DR (1988) Surf Interface Anal 11:317CrossRefGoogle Scholar
  28. 28.
    Sakurada O, Takahashi H, Taga M (1980) Bunseki Kagaku 38:407CrossRefGoogle Scholar
  29. 29.
    Tressaud A, Khairoun S, Touhara H, Watanabe NZ (1986) Anorg Allg Chem 291:540Google Scholar
  30. 30.
    Budhani RC, Banerjee A, Goel TC, Chopra KL (1983) J Noncryst Solids 55:93CrossRefGoogle Scholar
  31. 31.
    Turner S, Lebedev OI, Schröder F, Esken D, Fischer RA, Tendeloo GV (2008) Chem Mater 20:5622CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2012

Authors and Affiliations

  • Mingming Zhang
    • 1
  • Jingchao Guan
    • 1
  • Bingsen Zhang
    • 2
  • Dangsheng Su
    • 2
  • Christopher T. Williams
    • 3
  • Changhai Liang
    • 1
  1. 1.Laboratory of Advanced Materials and Catalytic EngineeringDalian University of TechnologyDalianChina
  2. 2.Department of Inorganic ChemistryFritz Haber Institute of the Max Planck SocietyBerlinGermany
  3. 3.Department of Chemical EngineeringUniversity of South CarolinaColumbiaUSA

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