Catalysis Letters

, Volume 141, Issue 7, pp 931–938 | Cite as

Preparation of Co/SiO2 Using Several Glycols for Enhanced Fischer-Tropsch Synthesis Activity and Dispersion of Co0 Nanoparticles with Unique Co0 Particle Size Effect

  • Naoto Koizumi
  • Shigenobu Suzuki
  • Satoshi Niiyama
  • Takayoshi Shindo
  • Muneyoshi Yamada
Article

Abstract

Co/SiO2 catalysts with highly dispersed Co0 and reducible Co were prepared by impregnation using an aqueous solution of Co nitrate containing ethylene glycol or its homologs. Addition of glycols enhanced FTS activity by a factor of 4. Particle size of Co0 decreased from 30 to below 6 nm, while TOF of the catalysts was independent of the Co0 particle size.

Graphical Abstract

Keywords

Fischer-Tropsch synthesis Co/SiO2 Glycol Co0 particle size effect 

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Copyright information

© Springer Science+Business Media, LLC 2011

Authors and Affiliations

  • Naoto Koizumi
    • 1
    • 4
  • Shigenobu Suzuki
    • 1
  • Satoshi Niiyama
    • 1
  • Takayoshi Shindo
    • 2
  • Muneyoshi Yamada
    • 3
  1. 1.Department of Applied Chemistry, Graduate School of EngineeringTohoku UniversitySendaiJapan
  2. 2.Department of Engineering in Applied Chemistry, Graduate School of Engineering and Resource ScienceAkita UniversityAkitaJapan
  3. 3.Akita National College of TechnologyAkitaJapan
  4. 4.Earth and Mineral Sciences Energy InstituteThe Pennsylvania State UniversityUniversity ParkUSA

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