Catalysis Letters

, Volume 137, Issue 3–4, pp 141–149 | Cite as

Synergistic Coupling of the Redox Properties of Supports and Cobalt Oxide Co3O4 for the Complete Oxidation of Volatile Organic Compounds

  • Frédéric Wyrwalski
  • Jean-Marc Giraudon
  • Jean-François Lamonier
Article

Abstract

Cobalt catalysts supported on metal oxides (CeO2, TiO2 and Al2O3) were prepared to investigate the effects of the support for the complete oxidation of propene, a model volatile organic compound of hydrocarbon type. The presence of ethylenediamine during the preparation of Co/metal oxides was also studied and compared with a conventionally prepared catalyst. Addition of an aqueous solution of ethylenediamine to a cobalt nitrate solution had a promotional effect on the catalytic performance of the solids. More activated oxygen species are available for propene oxidation due to the highest cobalt dispersion obtained when ethylenediamine is used during the synthesis. But the activation of oxygen species and the reducibility of the catalyst depend on the support used. The Co/CeO2 catalysts, synthesized by two protocols, presented the highest propene oxidation activity from the series due to the highest synergistic coupling of the redox properties of CeO2 and Co3O4.

Graphical Abstract

Keywords

VOC oxidation Cobalt oxides Support effect Ethylenediamine 

References

  1. 1.
    Guillemot M, Mijoin J, Mignard S, Magnoux P (2007) Appl Catal B: Environ 75:249CrossRefGoogle Scholar
  2. 2.
    Chi-Sheng Wu J, Chang T-Y (1998) Catal Today 44:111CrossRefGoogle Scholar
  3. 3.
    Giraudon J-M, Elhachimi A, Leclercq G (2008) Appl Catal B: Environ 84:251CrossRefGoogle Scholar
  4. 4.
    Lamonier J-F, Boutoundou A-B, Gennequin C, Pérez-Zurita M, Siffert S, Aboukais A (2007) Catal Lett 118:165CrossRefGoogle Scholar
  5. 5.
    Carpentier J, Siffert S, Lamonier J-F, Laversin H, Aboukaïs A (2007) J Porous Mater 14:103CrossRefGoogle Scholar
  6. 6.
    Kim SC, Shim WG (2009) Appl Catal B: Environ 92:429CrossRefGoogle Scholar
  7. 7.
    Liotta LF, Ousmane M, Di Carlo G, Pantaleo G, Deganello G, Marci G, Retailleau L, Giroir-Fendler A (2008) Appl Catal A: Gen 347:81CrossRefGoogle Scholar
  8. 8.
    Labaki M, Lamonier J-F, Siffert S, Zhilinskaya EA, Aboukaïs A (2003) Colloid Surf A 227:63CrossRefGoogle Scholar
  9. 9.
    Mu Z, Li JJ, Du MH, Hao ZP, Qiao SZ (2008) Catal Commun 9:1874CrossRefGoogle Scholar
  10. 10.
    Terribile D, Trovarelli A, de Leitenburg C, Primavera A, Dolcetti G (1999) Catal Today 47:133CrossRefGoogle Scholar
  11. 11.
    Kraum M, Baerns M (1999) Appl Catal A: Gen 186:189CrossRefGoogle Scholar
  12. 12.
    Khodakov AY, Lynch J, Bazin D, Rebours B, Zanier N, Moisson B, Chaumette P (1997) J Catal 168:16CrossRefGoogle Scholar
  13. 13.
    Enache DI, Roy-Auberger M, Revel R (2004) Appl Catal A: Gen 268:51CrossRefGoogle Scholar
  14. 14.
    Hilmen AM, Schanke D, Hanssen KF, Holmen A (1999) Appl Catal A: Gen 186:169CrossRefGoogle Scholar
  15. 15.
    Jacobs G, Das TK, Zhang Y, Li J, Racoillet G, Davis BH (2002) Appl Catal A: Gen 233:263CrossRefGoogle Scholar
  16. 16.
    van de Loosdrecht J, van der Haar M, van der Kraan AM, van Dillen AJ, Geus JW (1997) Appl Catal A: Gen 150:365CrossRefGoogle Scholar
  17. 17.
    Hou XD, Wang YZ, Zhao YX (2008) Catal Lett 123:321CrossRefGoogle Scholar
  18. 18.
    Tang CW, Wang CB, Chien SH (2009) Catal Lett 131:76CrossRefGoogle Scholar
  19. 19.
    Kang M, Song MW, Lee CH (2003) Appl Catal A: Gen 251:143CrossRefGoogle Scholar
  20. 20.
    Liotta LF, Di Carlo G, Pantaleo G, Deganello G (2007) Appl Catal B: Environ 70:314CrossRefGoogle Scholar
  21. 21.
    Wyrwalski F, Lamonier J-F, Pérez-Zurita M, Siffert S, Aboukaïs A (2006) Catal Lett 108:87CrossRefGoogle Scholar
  22. 22.
    Chien C-C, Chuang W-P, Huang T-J (1995) Appl Catal A: Gen 131:73CrossRefGoogle Scholar
  23. 23.
    Liotta L, Ousmane M, Di Carlo G, Pantaleo G, Deganello G, Boreave A, Giroir-Fendler A (2009) G. Catal Lett 127:270CrossRefGoogle Scholar
  24. 24.
    Malet P, Caballero A (1988) 1988. J Chem Soc, Faraday Trans 1(84):2369Google Scholar
  25. 25.
    Monti DAM, Baiker A (1983) J Catal 83:323CrossRefGoogle Scholar
  26. 26.
    Cseri T, Békássy S, Kenessey G, Liptay G, Figueras F (1996) Thermochim Acta 288:137CrossRefGoogle Scholar
  27. 27.
    Poul L, Jouini N, Fievet F (2000) Chem Mater 12:3123CrossRefGoogle Scholar
  28. 28.
    Wyrwalski F, Lamonier J-F, Siffert S, Aboukaïs A (2007) Appl Catal B: Environ 70:393CrossRefGoogle Scholar
  29. 29.
    Norkus E, Vaškelis A, Grigucevičienė A, Rozovskis G, Reklaitis J, Norkus P (2001) Transition Met Chem 26:465CrossRefGoogle Scholar
  30. 30.
    Yao HC, Yao YFY (1984) J Catal 86:254CrossRefGoogle Scholar
  31. 31.
    Zhu H, Qin Z, Shan W, Shen W, Wang J (2004) J Catal 225:267CrossRefGoogle Scholar
  32. 32.
    Luo M-F, Hou Z-Y, Yuan X-X, Zheng X-M (1998) Catal Lett 50:205CrossRefGoogle Scholar
  33. 33.
    Conner WC, Falconer JL (2002) Chem Rev 95:759CrossRefGoogle Scholar
  34. 34.
    Wang W-J, Chen Y-W (1991) Appl Catal A: Gen 77:223CrossRefGoogle Scholar
  35. 35.
    Sergent N, Lamonier J-F, Aboukaïs A (2000) Chem Mater 12:3830CrossRefGoogle Scholar
  36. 36.
    Dow WP, Huang TJ (1994) J Catal 147:322CrossRefGoogle Scholar
  37. 37.
    Labaki M, Siffert S, Lamonier J-F, Zhilinskaya EA, Aboukaïs A (2003) Appl Catal B: Environ 43:261CrossRefGoogle Scholar
  38. 38.
    Trovarelli A (1996) Catal Rev: Sci Eng 38:439CrossRefGoogle Scholar
  39. 39.
    Wrobel G, Lamonier C, Bennani A, D’Huysser A, Aboukaïs A (1996) J Chem Soc, Faraday Trans 92:2001CrossRefGoogle Scholar
  40. 40.
    Jongsomjit B, Sakdamnuson C, Praserthdam P (2005) Mater Chem Phys 89:395CrossRefGoogle Scholar
  41. 41.
    Bowker M (2006) Curr Opin Solid State Mater Sci 10:153CrossRefGoogle Scholar
  42. 42.
    Wang L, Sakurai M, Kameyama H (2009) J Hazard Mater 167:399CrossRefGoogle Scholar
  43. 43.
    Li J, Zhan X, Zhang Y, Jacobs G, Das T, Davis BH (2002) Appl Catal A: Gen 228:203CrossRefGoogle Scholar
  44. 44.
    Naydenov A, Stoyanova R, Mehandjiev D (1995) J Mol Catal A: Chem 98:9CrossRefGoogle Scholar
  45. 45.
    Bunluesin T, Gorte RJ, Graham GW (1997) Appl Catal B: Environ 14:105CrossRefGoogle Scholar
  46. 46.
    Agarwal SK, Spivey JJ, Butt JB (1992) Appl Catal A: Gen 81:239CrossRefGoogle Scholar
  47. 47.
    Cunningham DAH, Kobayashi T, Kamijo N, Haruta M (1994) Catal Lett 25:257CrossRefGoogle Scholar
  48. 48.
    Grillo F, Natile MM, Glisenti A (2004) Appl Catal B: Environ 48:267CrossRefGoogle Scholar
  49. 49.
    Xie XW, Li Y, Liu ZQ, Haruta M, Shen WJ (2009) Nature 458:746CrossRefGoogle Scholar
  50. 50.
    Drago RS, Jurczyk K, Singh DJ, Young V (1995) Appl Catal B: Environ 6:155CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2010

Authors and Affiliations

  • Frédéric Wyrwalski
    • 1
    • 2
    • 3
  • Jean-Marc Giraudon
    • 1
    • 2
    • 4
  • Jean-François Lamonier
    • 1
    • 2
    • 4
  1. 1.Univ Lille Nord de FranceLilleFrance
  2. 2.CNRS UMR8181, Unité de Catalyse et Chimie du Solide (UCCS)Villeneuve d’AscqFrance
  3. 3.UArtoisLensFrance
  4. 4.USTLVilleneuve d’AscqFrance

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