Catalysis Letters

, Volume 135, Issue 1–2, pp 62–67 | Cite as

Effect of High Pressure Sulfidation on the Structure of Sulfide Sites of Hydrotreatment Catalysts

  • Laetitia Oliviero
  • Laurence Mariey
  • Marc Antoine Lélias
  • Sébastien Aiello
  • Jacob van Gestel
  • Françoise Maugé
Article

Abstract

The effect of high-pressure sulfidation on (Co)Mo/Al2O3 catalysts was studied by means of IR spectroscopy of adsorbed CO and thiophene hydrodesulfurization (HDS). A new IR cell, called CellEx, was designed in order to characterize catalysts sulfided in situ under H2S/H2 flow with pressure varying from 0.1 up to 4.0 MPa. On Mo/Al2O3, high sulfidation pressure changes neither the HDS rate nor the MoS2 site concentration. Conversely on CoMo catalyst, sulfidation under high pressure leads to a marked increase of the thiophene HDS activity and of the Co-promoted site concentration as well as to some changes in the local structure of CoMoS sites.

Graphical Abstract

Study of CoMo catalyst, in the new IR cell, CellEX that allows in situ sulfidation under high-pressure, shows that sulfidation pressure increases HDS activity in parallel to the CoMoS concentration.

Keywords

Hydrotreatment Thiophene HDS IR spectroscopy Carbon monoxide Sulfidation Sulfidation pressure 

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Copyright information

© Springer Science+Business Media, LLC 2010

Authors and Affiliations

  • Laetitia Oliviero
    • 1
  • Laurence Mariey
    • 1
  • Marc Antoine Lélias
    • 1
    • 2
  • Sébastien Aiello
    • 1
  • Jacob van Gestel
    • 1
  • Françoise Maugé
    • 1
  1. 1.Laboratoire Catalyse et Spectrochimie, ENSICAENUniversité de CaenCaenFrance
  2. 2.Axens—Usine de SalindresSalindresFrance

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