Catalysis Letters

, Volume 131, Issue 1–2, pp 129–134 | Cite as

Enhancement of Catalytic Activity on Pd/C and Te–Pd/C During the Oxidative Dehydrogenation of Sodium Lactate to Pyruvate in an Aqueous Phase Under Pressurized Oxygen

  • Shigeru Sugiyama
  • Tetsuo Kikumoto
  • Haruki Tanaka
  • Keizo Nakagawa
  • Ken-Ichiro Sotowa
  • Keiko Maehara
  • Yoshiyuki Himeno
  • Wataru Ninomiya
Article
First Online:
Received:
Revised:
Accepted:

Abstract

The oxidative dehydrogenation of sodium lactate to sodium pyruvate in an aqueous phase proceeded favorably using Pd/C and that doped with Te at 358 K with no adjustment in solution pH under pressurized oxygen, although previous reports had stated that this reaction would not proceed using Pd/C while Pd/C doped with either Pb, Bi or Te showed the activity at atmospheric pressure, 363 K, and a pH of 8.

Keywords

Oxidative dehydrogenation Sodium lactate and pyruvate Pd/C High pressure conditions 
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Notes

Acknowledgments

This work was funded by Grants-in-Aid for Scientific Research (A) KAKENHI 20241020 to SS. The EXAFS study was performed with the approval of the Photon Factory Advisory Committee of the High-Energy Research Organization (Proposal 2007G007).

References

  1. 1.
    Corma A, Iborra S, Velty A (2007) Chem Rev 107:2411CrossRefGoogle Scholar
  2. 2.
    Erlenmeyer E (1881) Ber Dtsch Chem Ges 14:320CrossRefGoogle Scholar
  3. 3.
    Ai M, Ohdan K (1997) Appl Catal A 165:461CrossRefGoogle Scholar
  4. 4.
    Ai M, Ohdan K (2000) J Mol Catal A 159:19CrossRefGoogle Scholar
  5. 5.
    Ai M (2002) Appl Catal A 234:235CrossRefGoogle Scholar
  6. 6.
    Sugiyama S, Shigemoto N, Masaoka N, Suetoh S, Kawami H, Miyaura K, Hayashi H (1993) Bull Chem Soc Jpn 66:1542CrossRefGoogle Scholar
  7. 7.
    Hayashi H, Sugiyama S, Masaoka N, Shigemoto N (1995) Ind Eng Chem Res 34:135CrossRefGoogle Scholar
  8. 8.
    Hayashi H, Sugiyama S, Moriga T, Masaoka N, Yamamoto A (1997) Stud Surf Sci Catal 108:421CrossRefGoogle Scholar
  9. 9.
    Hayashi H, Sugiyama S, Kokawa N, Kato K (1997) Appl Surf Sci 121/122:378CrossRefGoogle Scholar
  10. 10.
    Tsujino T, Ohigashi S, Sugiyama S, Kawashiro K, Hayashi H (1992) J Mol Catal 71:25CrossRefGoogle Scholar
  11. 11.
    Hayashi H, Sugiyama S, Shigemoto N, Miyaura K, Tsujino S, Kawashiro K, Urabe S (1993) Catal Lett 19:369CrossRefGoogle Scholar
  12. 12.
    Hayashi H, Sugiyama S, Katayama Y, Kawashiro K, Shigemoto N (1994) J Mol Catal 91:129CrossRefGoogle Scholar
  13. 13.
    Hayashi H, Sugiyama S, Katayama Y, Sakai K, Sugino M, Shigemoto N (1993) J Mol Catal 83:207CrossRefGoogle Scholar
  14. 14.
    Katayama Y (1994) Master Thesis of the University of Tokushima, JapanGoogle Scholar
  15. 15.
    Sugiyama S, Hirata Y, Nakagawa K, Sotowa K-I, Maehara K, Himeno Y, Ninomiya W (2008) J Catal 206:157CrossRefGoogle Scholar
  16. 16.
    Smits PCC, Kuster BFM, van der Wiele K, van der Baan HS (1986) Carbohydr Res 153:227CrossRefGoogle Scholar
  17. 17.
    Smits PCC, Kuster BFM, van der Wiele K, van der Baan HS (1987) Appl Catal 33:83CrossRefGoogle Scholar
  18. 18.
    Lindlar H, Dubis R (1966) In: Corey EJ (ed) Organic synthesis, vol 46. Wiley, New York, p 89Google Scholar
  19. 19.
    Stachurski J, Thomas JM (1988) Catal Lett 1:67CrossRefGoogle Scholar
  20. 20.
    Takehira K, Mimoun H, de Roch IS (1979) J Catal 58:155CrossRefGoogle Scholar
  21. 21.
    Cheng CH, Dooley KM, Proce GL (1989) J Catal 116:325CrossRefGoogle Scholar
  22. 22.
    Gronvol F, Rost E (1956) Acta Chem Scand 10:1620CrossRefGoogle Scholar
  23. 23.
    Ziemecki SB, Jones GA, Swartzfager DG, Harlow RL (1985) J Am Chem Soc 107:4547CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2009

Authors and Affiliations

  • Shigeru Sugiyama
    • 1
    • 2
  • Tetsuo Kikumoto
    • 3
  • Haruki Tanaka
    • 3
  • Keizo Nakagawa
    • 1
    • 2
  • Ken-Ichiro Sotowa
    • 1
    • 2
  • Keiko Maehara
    • 4
  • Yoshiyuki Himeno
    • 4
  • Wataru Ninomiya
    • 5
  1. 1.Department of Advanced Materials, Institute of Technology and ScienceThe University of TokushimaTokushimaJapan
  2. 2.Department of Geosphere Environment and Energy, Center for Frontier Research of EngineeringThe University of TokushimaTokushimaJapan
  3. 3.Department of Chemical Science and Technology Faculty of EngineeringThe University of TokushimaTokushimaJapan
  4. 4.Corporate Research LaboratoriesMitsubishi Rayon Co. LtdHiroshimaJapan
  5. 5.Research & Development Administration DepartmentMitsubishi Rayon Co. LtdTokyoJapan

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