Catalysis Letters

, 130:217 | Cite as

CeO2 Promoted Ni/Al2O3 Catalyst in Combined Steam and Carbon Dioxide Reforming of Methane for Gas to Liquid (GTL) Process

  • Kee Young Koo
  • Hyun-Seog Roh
  • Un Ho Jung
  • Wang Lai Yoon


The effect of ceria promotion over Ni/Al2O3 catalysts on the catalytic activity and coke formation was investigated in combined steam and carbon dioxide reforming of methane (CSCRM) to produce synthesis gas (H2/CO = 2) for gas to liquid (GTL) process. Ce-promoted Ni/Al2O3 catalysts were prepared by co-impregnation method. It has been found that the Ce promotion over Ni/Al2O3 catalyst is beneficial to catalytic activity and coke resistance. As a result, the catalyst promoted with 6 wt% Ce exhibits the highest activity as well as high coke resistance due to the improvement of Ni dispersion and high oxygen storage capacity of CeO2.


Combined steam and carbon dioxide reforming of methane Ni-Ce/Al2O3 Coke resistance Gas to liquid (GTL) 



The authors would like to acknowledge the financial support of KEMCO and GTL Technology Development Consortium (Korea National Oil Corp., Daelim Industrial Co., LTD, Doosan Mecatec Co., LTD, Hyundai Engineering Co., LTD and SK Energy Co. LTD) under “Energy & Resources Technology Development Programs” of the Ministry of Knowledge Economy, Republic of Korea.


  1. 1.
    Rostrup-Nielsen JR (1993) Catal Today 18:305CrossRefGoogle Scholar
  2. 2.
    Ross JRH, van Keulen ANJ, Seshan MES, Jegarty K (1996) Catal Today 30:193CrossRefGoogle Scholar
  3. 3.
    Roh H-S, Jun K-W, Dong W-S, Chang J-S, Park S-E, Joe Y-I (2002) J Mol Catal A 181:137CrossRefGoogle Scholar
  4. 4.
    Roh H-S, Jun K-W (2008) Catal Surv Asia 12:239CrossRefGoogle Scholar
  5. 5.
    Koh ACW, Chen L, Leong WK, Johnson BFG, Khimyak T, Lin J (2007) Int J Hydrogen Energy 32:725CrossRefGoogle Scholar
  6. 6.
    Song X, Guo Z (2006) Energy Conv Manag 47:560CrossRefGoogle Scholar
  7. 7.
    Choudhary VR, Mondal KC (2006) Appl Energy 83:1024CrossRefGoogle Scholar
  8. 8.
    Roh H-S, Koo KY, Jeong JH, Seo YT, Seo DJ, Seo YS, Yoon WL, Park SB (2007) Catal Lett 117:85CrossRefGoogle Scholar
  9. 9.
    Koo KY, Roh H-S, Seo YT, Seo DJ, Yoon WL, Park SB (2008) Int J Hydrogen Energy 33:2036CrossRefGoogle Scholar
  10. 10.
    Koo KY, Roh H-S, Seo YT, Seo DJ, Yoon WL, Park SB (2008) Appl Catal A 340:183CrossRefGoogle Scholar
  11. 11.
    Rostrup-Nielsen JR, Bak Hansen J-H (1993) J Catal 144:38CrossRefGoogle Scholar
  12. 12.
    Tomishige K, Chen Y, Fujimoto K (1999) J Catal 181:91CrossRefGoogle Scholar
  13. 13.
    Roh H-S, Koo KY, Joshi UD, Yoon WL (2008) Catal Lett 125:283CrossRefGoogle Scholar
  14. 14.
    Lucrédio AF, Jerkiewickz G, Assaf EM (2007) Appl Catal A 333:90CrossRefGoogle Scholar
  15. 15.
    Huang T-J, Lin H-J, Yu T-C (2005) Catal Lett 105:239CrossRefGoogle Scholar
  16. 16.
    Otsuka K, Ushiyama T, Yamanaka I (1993) Chem Lett 22:1517CrossRefGoogle Scholar
  17. 17.
    Laosiripojana N, Assabumrungrat S (2005) Appl Catal B 60:107CrossRefGoogle Scholar
  18. 18.
    Laosiripojana N, Assabumrungrat S (2005) Appl Catal A 290:200CrossRefGoogle Scholar
  19. 19.
    Roh H-S, Potdar HS, Jun K-W (2004) Catal Today 93–95:39CrossRefGoogle Scholar
  20. 20.
    Roh H-S, Potdar HS, Jun K-W, Kim J-W, Oh Y-S (2004) Appl Catal A 276:231CrossRefGoogle Scholar
  21. 21.
    Montoya JA, Romero-Pascual E, Gimon C, Angel PD, Monzon A (2000) Catal Today 63:71CrossRefGoogle Scholar
  22. 22.
    Roh H-S, Wang Y, King DL, Platon A, Chin Y-H (2006) Catal Lett 108:15CrossRefGoogle Scholar
  23. 23.
    Roh H-S, Platon A, Wang Y, King DL (2006) Catal Lett 110:1CrossRefGoogle Scholar
  24. 24.
    Jun K-W, Roh H-S, Chary KVR (2007) Catal Surv Asia 11:97CrossRefGoogle Scholar
  25. 25.
    Roh H-S, Wang Y, King DL (2008) Top Catal 49:32CrossRefGoogle Scholar
  26. 26.
    Wrobel G, Sohier MP, D’Huysser A, Bonnelle JP (1993) Appl Catal A 101:73CrossRefGoogle Scholar
  27. 27.
    Shan W, Luo M, Ying P, Shen W, Li C (2003) Appl Catal A 246:1CrossRefGoogle Scholar
  28. 28.
    Guo J, Lou H, Zhao H, Chai D, Zheng X (2004) Appl Catal A 273:75CrossRefGoogle Scholar
  29. 29.
    Santos ACSF, Damyanova S, Teizeira GNR, Mattos LV, Noronha FB, Passos FB, Bueno JMC (2005) Appl Catal A 290:123CrossRefGoogle Scholar
  30. 30.
    Rostrup-Nielsen JR (1984) In: Anderson JR, Boudart M (eds) Catalysis science and technology, vol 5. Springer, Berlin, p 1Google Scholar

Copyright information

© Springer Science+Business Media, LLC 2009

Authors and Affiliations

  1. 1.Strategic Technologies Research DivisionKorea Institute of Energy Research (KIER)Yuseong, DaejeonKorea
  2. 2.Department of Environmental EngineeringYonsei UniversityHeungeop, WonjuKorea

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