Catalysis Letters

, Volume 103, Issue 3–4, pp 219–223 | Cite as

Indications for Metal-support Interactions: The Case of CO2Adsorption on Cu/ZnO(0001)

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Abstract

Molecular beam scattering has been combined with TDS to provide consistent evidence for metal-support interactions (MSI). CO2 adsorbs on the Cu cluster and populated the perimeter of the clusters. The Cu-free areas of the support remain essentially clean. Hence, a synergistic effect such as MSI is present.

KEY WORDS

Metal Support Interaction adsorption dynamics adsorption probabilities adsorption kinetics metal oxide surfaces Zn–ZnO ZnO(0001) CO2 copper clusters molecular beam scattering Thermal Desorption Spectroscopy 
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Copyright information

© Springer Science+Business Media, Inc. 2005

Authors and Affiliations

  1. 1.Department of Chemistry, Biochemistry, and Molecular BiologyNorth Dakota State UniversityFargoUSA

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