Abstract
Streamwater chemistry was measured at 100-m intervals in all streams of the Hubbard Brook Valley, NH during ‘spring’ (May–July) and during ‘fall’ (October–December) 2001. Overall, streamwater chemistry was very similar during these two periods, but fall median concentrations were consistently higher than spring values, except for ANC, pH, NO3 − and PO4 3−, which had lower values in fall. Median concentrations for NH4 + were approximately the same in spring and fall. Stream chemistry varied throughout the Hubbard Brook Valley by elevation, channel length, drainage area and type of drainage, but most of the variability in stream chemistry was subtle and relatively small. Overall, there were relatively large (two- to 10-fold) changes in chemistry with longitudinal distance of wetted channel, elevation and/or size of drainage area in some streams and for some elements (e.g., H+, Aln+, DOC), but other chemical concentrations changed relatively little (e.g., Cl−, dissolved Si). The main Hubbard Brook, a fifth-order stream at the mouth of the Valley, was remarkably constant in chemistry throughout its length, except where human disturbance near the mouth changed the chemistry. Differences in vegetation, geologic substrates and wetland areas were related to changes in pattern of streamwater chemistry throughout the Valley.
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References
Bailey A.S., Hornbeck J.W., Campbell J.L. and Eagar C. 2003. Hydrometeorological Database for Hubbard Brook Experimental Forest: 1955–2000. USDA Forest ServiceNortheastern Research Station, Gen. Tech. Report NE-305, 36pp.
Bailey S.W. and Hornbeck J.W. 1992. Lithologic Composition and Rock Weathering Potential of ForestedGlacial-Till Soils. NE Station Research Paper NE-662, 7pp.
Barton C.C., Camerlo R.H. and Bailey S.W. 1997. Bedrock Geologic Map of Hubbard Brook Experimental Forest and Maps of Fractures and Geology in Roadcuts Along Interstate-93, Grafton County, New HampshireU.S. Geological Survey, Sheet 1, Scale 1:12,000; Sheet 2, Scale 1:200. Miscellaneous Investigations Series, Map I-2562.
E.S. Bernhardt G.E. Likens D.C. Buso C.T. Driscoll (2003) ArticleTitleIn-stream uptake dampens effects of major forest disturbance on watershed nitrogen export Proc. Natl. Acad. Sci. 100 IssueID18 10304–10308 Occurrence Handle10.1073/pnas.1233676100
F.H. Bormann G.E. Likens (1967) ArticleTitleNutrient cycling Science 155 IssueID3761 424–429
F.H. Bormann G.E. Likens (1979) ArticleTitleCatastrophic disturbance and the steady state in northern hardwood forests Amer. Sci. 67 IssueID6 660–669
F.H. Bormann T.G. Siccama G.E. Likens R.H. Whittaker (1970) ArticleTitleThe Hubbard Brook Ecosystem Study: composition and dynamics of the tree stratum Ecol. Monogr. 40 IssueID4 373–388 Occurrence Handle10.2307/1942336
I.C. Burke W.K. Lauenroth C.A. Wessman (1998) Progress in understanding biogeochemical cycles at regional to global scales M.L. Pace P.M. Groffman (Eds) Successes, Limitations, and Frontiers in Ecosystem Science Springer-Verlag New York Inc 165–194
Burton W.C., Walsh G.J. and Armstrong T.R. 2000. Bedrock Geology Map of the Hubbard Brook Experimental Forest. U.S. Geological Survey, Grafton County, New HampshireOpen File Report 00–45.
D.C. Buso G.E. Likens J.S. Eaton (2000) Chemistry of Precipitation, Stream Water and Lake Water from the Hubbard Brook Ecosystem Study: A Record of Sampling Protocols and Analytical Procedures USDA Forest ServiceNortheastern Research Station Newtown Square, PA 52
C.D. Canham J.J. Cole W.K. Lauenroth (Eds) (2003) Models in Ecosystem Science Princeton University Press Princeton and Oxford 476
N.F. Caraco J.J. Cole G.E. Likens G.M. Lovett K.C. Weathers (2003) ArticleTitleVariation in NO3 export from flowing waters of vastly different sizes: does one model fit all? Ecosystems 6 344–352 Occurrence Handle10.1007/s10021-002-0120-x
S.C. Carpenter (1998) The need for large-scale experiments to assess and predict the response of ecosystems to perturbation M.L. Pace P.M. Groffman (Eds) Successes, Limitations, and Frontiers in Ecosystem Science Springer-Verlag New York Inc 287–312
S.C. Carpenter (2002) ArticleTitleEcological futures: building an ecology of the long now Ecology 83 IssueID8 2069–2083
J.S. Clark S.R. Carpenter M. Barber S. Collins A. Dobson J. Foley D. Lodge M. Pascual R. Pielke SuffixJr. W. Pizer C. Pringle W. Reid K. Rose O. Sala W. Schlesinger D. Wall D. Wear (2001) ArticleTitleEcological forecasting: an emerging imperative Science 293 657–660 Occurrence Handle10.1126/science.293.5530.657
C.V. Cogbill J. Burk G. Motzkin (2003) ArticleTitleThe forests of presettlement New England, USA: spatial and compositional patterns based on town proprietor surveys J. Biogeogr. 29 1279–1304 Occurrence Handle10.1046/j.1365-2699.2002.00757.x
S.D. Cooper L. Barmuta O. Sarnelle K. Kratz S. Diehl (1997) ArticleTitleQuantifying spatial heterogeneity in streams J. North Amer. Benthol. Soc. 16 IssueID1 174–188 Occurrence Handle10.2307/1468250
M.B. Davis (1985) History of the vegetation on the Mirror Lake watershed G.E. Likens (Eds) An Ecosystem Approach to Aquatic Ecology: Mirror Lake and its Environment Springer-Verlag New York 53–65
M.B. Davis R.E. Moeller G.E. Likens J. Ford J. Sherman C. Goulden (1985) Paleoecology of Mirror Lake and its watershed G.E. Likens (Eds) An Ecosystem Approach to Aquatic Ecology: Mirror Lake and its Environment Springer-Verlag New York 410–429
L.C. Dent N.B. Grimm (1999) ArticleTitleSpatial heterogeneity of stream water nutrient concentrations over successional time Ecology 80 IssueID7 2283–2298 Occurrence Handle10.2307/176910
L.C. Dent N.B. Grimm S.G. Fisher (2001) ArticleTitleMultiscale effects of surface-subsurface exchange on stream water nutrient concentrations J. N. Am. Benthol. Soc. 20 162–181 Occurrence Handle10.2307/1468313
Federer C.A., Flynn L.D., Martin C.W., Hornbeck J.W. and Pierce R.S. 1990. Thirty years of hydrometeorologic data at the Hubbard Brook Experimental ForestNew Hampshire. USDA Forest ServiceGeneral Technical Report NE-141, 44pp.
S.G. Fisher J. Welter J. Schade J. Henry (2001) ArticleTitleLandscape challenges to ecosystem thinking: creative flood and drought in the American Southwest Scientia Marina 65 IssueIDSuppl. 2 181–192
N.B. Grimm S.G. Fisher W.L. Minckley (1981) ArticleTitleNitrogen and phosphorus dynamics in hot desert streams of southwestern USA Hydrobiologia 83 303–312 Occurrence Handle10.1007/BF00008281
R.O. Hall SuffixJr. K.H. Macneale E.S. Bernhardt M. Field G.E. Likens (2001) ArticleTitleBiogeochemical responses of two forest streams to a two-month calcium addition Freshwater Biol. 46 IssueID3 291–302 Occurrence Handle10.1046/j.1365-2427.2001.00660.x
N.M. Johnson G.E. Likens F.H. Bormann D.W. Fisher R.S. Pierce (1969) ArticleTitleA working model for the variation in stream water chemistry at the Hubbard Brook Experimental ForestNew Hampshire Water Resour. Res. 5 IssueID6 1353–1363
N.M. Johnson C.T. Driscoll J.S. Eaton G.E. Likens W.H. McDowell (1981) ArticleTitle“Acid rain,” dissolved aluminum and chemical weathering at the Hubbard Brook Experimental ForestNew Hampshire Geochim. Cosmoch. Acta 45 IssueID9 1421–1437 Occurrence Handle10.1016/0016-7037(81)90276-3
C.E. Johnson A.H. Johnson T.G. Huntington T.G. Siccama (1991a) ArticleTitleWhole-tree clear-cutting effects on soil horizons and organic-matter pools Soil Sci. Soc. Am. J. 55 497–502 Occurrence Handle10.2136/sssaj1991.03615995005500020034x
C.E. Johnson A.H. Johnson T.G. Siccama (1991b) ArticleTitleWhole-tree clear-cutting effects on exchangeable cations and soil acidity Soil Sci. Soc. Am. J. 55 502–508 Occurrence Handle10.2136/sssaj1991.03615995005500020035x
C.E. Johnson C.T. Driscoll T.G. Siccama G.E. Likens (2000) ArticleTitleElement fluxes and landscape position in a northern hardwood forest watershed-ecosystem Ecosystems 3 159–184 Occurrence Handle10.1007/s100210000017
Kim E. 1988. Radial growth patterns of tree species in relation to environmental factors. Ph.D. thesis. Yale University, 293pp.
G.B. Lawrence R.D. Fuller C.T. Driscoll (1986) ArticleTitleSpatial relationships of aluminum chemistry in the streams of the Hubbard Brook Experimental ForestNew Hampshire Biogeochemistry 2 IssueID2 115–135 Occurrence Handle10.1007/BF02180190
Likens G.E. 1992. The Ecosystem Approach: Its Use and Abuse. Excellence in Ecology, Vol. 3, Ecology Institute, Oldendorf/Luhe, Germany, 167pp.
G.E. Likens (1998) Limitations to intellectual progress in ecosystem science M.L. Pace P.M. Groffman (Eds) Successes, Limitations and Frontiers in Ecosystem Science Springer-Verlag New York 247–271
G.E. Likens (1999) ArticleTitleThe science of naturethe nature of science: long-term ecological studies at Hubbard Brook Proc. Am. Phil. Soc. 143 IssueID4 558–572
G.E. Likens (2004a) ArticleTitleBiogeochemistry: some opportunities and challenges for the future Water Air Soil Poll.: Focus 4 IssueID2–3 5–24 Occurrence Handle10.1023/B:WAFO.0000028341.75842.08
G.E. Likens (2004b) ArticleTitleSome perspectives on long-term biogeochemical research from the Hubbard Brook Ecosystem Study Ecology 85 IssueID9 2355–2362
G.E. Likens F.H. Bormann (1995) Biogeochemistry of a Forested Ecosystem EditionNumber2 Springer-Verlag New York 159
G.E. Likens M.B. Davis (1975) ArticleTitlePost-glacial history of Mirror Lake and its watershed in New HampshireUSA: an initial report Verh. Internat. Verein. Limnol. 19 IssueID2 982–993
G.E. Likens F.H. Bormann N.M. Johnson D.W. Fisher R.S. Pierce (1970) ArticleTitleEffects of forest cutting and herbicide treatment on nutrient budgets in the Hubbard Brook watershed-ecosystem Ecol. Monogr. 40 IssueID1 23–47 Occurrence Handle10.2307/1942440
G.E. Likens C.T. Driscoll D.C. Buso T.G. Siccama C.E. Johnson D.F. Ryan G.M. Lovett T. Fahey W.A. Reiners (1994) ArticleTitleThe biogeochemistry of potassium at Hubbard Brook Biogeochemistry 25 61–125 Occurrence Handle10.1007/BF00000881
G.E. Likens C.T. Driscoll D.C. Buso T.G. Siccama C.E. Johnson G.M. Lovett T.J. Fahey W.A. Reiners D.F. Ryan C.W. Martin S.W. Bailey (1998) ArticleTitleThe biogeochemistry of calcium at Hubbard Brook Biogeochemistry 41 IssueID2 89–173 Occurrence Handle10.1023/A:1005984620681
G.E. Likens C.T. Driscoll D.C. Buso M.J. Mitchell G.M. Lovett S.W. Bailey T.G. Siccama W.A. Reiners C. Alewell (2002a) ArticleTitleThe biogeochemistry of sulfur at Hubbard Brook Biogeochemistry 60 IssueID3 235–316 Occurrence Handle10.1023/A:1020972100496
G.E. Likens D.C. Buso J.W. Hornbeck (2002b) ArticleTitleVariation in chemistry of stream water and bulk deposition across the Hubbard Brook Valley, New HampshireUSA Verh. Internat. Verein. Limnol. 28 IssueID1 402–409
G.E. Likens D.C. Buso B.K. Dresser E.S. Bernhardt R.O. Hall SuffixJr. K.H. Macneale S.W. Bailey (2004) ArticleTitleBuffering an acidic stream in New Hampshire with a silicate mineral Restor. Ecol. 12 IssueID3 419–428 Occurrence Handle10.1111/j.1061-2971.2004.00357.x
B.D. Lindsey W.J. Gburek G.J. Folmar (2001) ArticleTitleWatershed scaling effect on base flow nitratevalley and ridge physiographic province J. Am. Water Resour. Assoc. 37 IssueID5 1103–1117
W. Lowe G.E. Likens (2005) ArticleTitleMoving headwater streams to the head of the class BioScience 55 IssueID3 100–101
J.B. Lyons W.A. Bothner R.H. Moench J.B. Thompson (1997) Bedrock Geologic Map of New Hampshire USGS Denver, CO
C.W. Martin G.E. Likens D.C. Buso (2000) ArticleTitleComparison of long-term precipitation chemistry measurements at the Hubbard Brook Experimental ForestNew Hampshire Water Air Soil Pollut. 120 IssueID3–4 359–379 Occurrence Handle10.1023/A:1005258723010
D.P. Mau T.C. Winter (1997) ArticleTitleEstimating ground-water recharge from streamflow hydrographs for a small mountain watershed in a temperate humid climate, New Hampshire, USA Ground Water 35 IssueID2 291–304 Occurrence Handle10.1111/j.1745-6584.1997.tb00086.x
M.E. McClain E.W. Boyer C.L. Dent S.E. Gergel N.B. Grimm P.M. Groffman S.C. Hart J.W. Harvey C.A. Johnston E. Mayorga W.H. McDowell G. Pinay (2003) ArticleTitleBiogeochemical hot spots and hot moments at the interface of terrestrial and aquatic ecosystems Ecosystems 6 301–312 Occurrence Handle10.1007/s10021-003-0161-9
McDowell W.H. 1982. Mechanisms controlling the organic chemistry of Bear Brook, New Hampshire. Ph.D. thesis. Cornell University, 152pp.
W.H. McDowell G.E. Likens (1988) ArticleTitleOrigin, composition, and flux of dissolved organic carbon in the Hubbard Brook Valley Ecol. Monogr. 58 IssueID3 177–195 Occurrence Handle10.2307/2937024
Merrens E.J. 1988. Effects of the 1938 hurricane on forest structure and growth rates in a northern hardwoods forest at Hubbard Brook, New Hampshire. Undergraduate Honors thesis, Department of Biological Sciences, Dartmouth College, 37pp.
Meyer J.L. 1978. Transport and transformation of phosphorus in a stream ecosystem. Ph.D. thesis, Cornell University, 226pp.
Palmer S.M. 2004. Spatial and temporal patterns in the biogeochemistry of aluminum at the Hubbard Brook Experimental Forest, New Hampshire. Ph.D. thesis, Syracuse University.
R.S. Pierce (1967) Evidence of overland flow on forest watersheds W.E. Sopper H.W. Lull (Eds) International Symposium on Forest Hydrology Proceedings Pergamon Press Oxford, England 247–253
P.A. Schwarz T.J. Fahey C.E. McCulloch (2003) ArticleTitleFactors controlling spatial variation of tree species abundance in a forested landscape Ecology 84 IssueID7 1862–1878
Sloane J. 1979. Nitrogen flux in small mountain streams in New Hampshire. M.S. thesis, Cornell University, 131 pp.
C.M. Tate (1990) ArticleTitlePatterns and controls of nitrogen in tallgrass prairie streams Ecology 71 IssueID5 2007–2018 Occurrence Handle10.2307/1937609
G.T. Trewartha (1954) Introduction to Climate McGraw-Hill Book Co New York, NY 402
H.M. Valett J.A. Morrice C.N. Dahm M.E. Campana (1996) ArticleTitleParent lithology, surface-groundwater exchangeand nitrate retention in headwater streams Limnol. Oceanogr. 41 IssueID2 333–345 Occurrence Handle10.4319/lo.1996.41.2.0333
R.H. Whittaker F.H. Bormann G.E. Likens T.G. Siccama (1974) ArticleTitleThe Hubbard Brook Ecosystem Study: forest biomass and production Ecol. Monogr. 44 IssueID2 233–254 Occurrence Handle10.2307/1942313
T.C. Winter (2001) ArticleTitleThe concept of hydrologic landscapes J. Am. Wat. Resourc. Assoc. 37 IssueID2 335–349
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Likens, G.E., Buso, D.C. Variation in Streamwater Chemistry Throughout the Hubbard Brook Valley. Biogeochemistry 78, 1–30 (2006). https://doi.org/10.1007/s10533-005-2024-2
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DOI: https://doi.org/10.1007/s10533-005-2024-2