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Theoretical investigation of interstellar C–C–O and C–O–C bonding backbone molecules

  • Emmanuel E. Etim
  • Prasanta Gorai
  • Ankan Das
  • Elangannan Arunan
Original Article

Abstract

There are numerous complex organic molecules containing carbon and oxygen atoms which show either C–C–O or C–O–C bonding backbone. This paper examines altogether 51 C–C–O and C–O–C bonding backbone molecules from ten different isomeric groups (C2H2O, C3H2O, C2H4O, C2H4O2, C3H4O, C2H6O, C2H6O2, C3H6O, C3H6O2, C3H8O) to summarize the present astronomical status of these molecules. Accurate calculations of enthalpy of formation of these molecules show that the isomers with C–C–O backbone are more stable than the C–O–C backbone. Interestingly, a detailed analysis of relevant astromolecules indicates that most of the observed astromolecules have the C–C–O backbone. As a matter of fact, of all the molecules examined in this study, 80% of the astronomically observed species have the C–C–O backbone while only 20% have the C–O–C backbone. In general, interstellar abundance of a molecule is controlled by some factors such as kinetics, formation and destruction pathways,thermodynamics etc. A proper consideration of these factors could explain the observed abundances of these molecules. All these possible key factors are discussed in this paper.

Keywords

Interstellar: molecules 

Notes

Acknowledgements

EEE acknowledges a research fellowship from the Indian Institute of Science, Bangalore. AD & PG are grateful to ISRO respond project (Grant No. ISRO/RES/2/402/16-17) for the partial financial support.

References

  1. Abplanalpa, M.J., Gozemc, S., Krylovc, A.I., Shingledeckerd, C.N., Herbst, E., Kaiser, R.I.: Proc. Natl. Acad. Sci. USA 113, 28 (2016) Google Scholar
  2. Belloche, A., Garrod, R.T., Muller, H.S.P., Menten, K.M., Comito, C., Schilke, P.: Astron. Astrophys. 499, 215–232 (2009) ADSCrossRefGoogle Scholar
  3. Cioslowski, J., Schimeczek, M., Liu, G., Stoyanov, V.: J. Comput. Phys. 113, 9377 (2000) Google Scholar
  4. Charnley, S.B., Rodgers, S.D.: In: Proceedings IAU Symposium No. 231 (2005) Google Scholar
  5. Churchwell, E., Winnewisser, G.: Astron. Astrophys. 45, 229 (1975) ADSGoogle Scholar
  6. Curtiss, L.A., Raghavachari, K., Redfern, P.C., Rassolov, V., Pople, J.A.: J. Comput. Phys. 109, 7764 (1998) Google Scholar
  7. Curtiss, L.A., Redfern, P.C., Raghavachari, K.: J. Comput. Phys. 126, 084108 (2007a) Google Scholar
  8. Curtiss, L.A., Redfern, P.C., Raghavachari, K.: J. Chem. Phys. 127, 124105 (2007b) ADSCrossRefGoogle Scholar
  9. Das, A., Majumdar, L., Sahu, D., Gorai, P., Sivaraman, B., Chakrabarti, S.K.: Astrophys. J. 808, 21 (2015) ADSCrossRefGoogle Scholar
  10. Das, A., Sahu, D., Majumdar, L., Chakrabarti, S.K.: Mon. Not. R. Astron. Soc. 455, 540 (2016) ADSCrossRefGoogle Scholar
  11. Dickens, J.E., Irvine, W.M., Ohishi, M., et al.: Astrophys. J. 489, 753 (1997) ADSCrossRefGoogle Scholar
  12. Dickens, J.E., Irvine, W.M., Nummelin, A., et al.: Spectrochim. Acta A 57, 643 (2001) ADSCrossRefGoogle Scholar
  13. Emel’yanenko, V.M., Verevkin, S.P., Varfolomeev, M.A.: J. Chem. Eng. Data 56, 4183–4187 (2011) CrossRefGoogle Scholar
  14. Etim, E.E., Gorai, P., Das, A., Charabati, S.K., Arunan, E.: Astrophys. J. 832, 144 (2016a) ADSCrossRefGoogle Scholar
  15. Etim, E.E., Arunan, E.: Eur. Phys. J. Plus 131, 448 (2016b) CrossRefGoogle Scholar
  16. Etim, E.E., Arunan, E.: Astrophys. Space Sci. 362, 4 (2017a) ADSCrossRefGoogle Scholar
  17. Fourikis, N., Sinclair, M.W., Robinson, B.J., Godfrey, P.D., Brown, R.D.: Aust. J. Phys. 27, 425 (1974) ADSCrossRefGoogle Scholar
  18. Frisch, M.J., Trucks, G.W., Schlegel, H.B., et al.: G09:RevC.01. Gaussian, Inc., Wallingford (2015) Google Scholar
  19. Fuchs, U., Winnewisser, G., Groner, P., De Lucia, F.C., Herbst, E.: Astrophys. J. Suppl. Ser. 144, 277–286 (2003) ADSCrossRefGoogle Scholar
  20. Fuchs, G.W., Fuchs, U., Giesen, T.F., Wyrowski, F.: Astron. Astrophys. 444, 521–530 (2005) ADSCrossRefGoogle Scholar
  21. Garrod, R.: Astron. Astrophys. 491, 239 (2008) ADSCrossRefGoogle Scholar
  22. Gilmore, W., Morris, M., Palmer, P., et al.: Astrophys. J. 204, 43 (1976) ADSCrossRefGoogle Scholar
  23. Gorai, P., Das, A., Das, A., Sivaraman, B., Etim, E.E., Chakrabarti, S.K.: Astrophys. J. 836, 70 (2017a) ADSCrossRefGoogle Scholar
  24. Gorai, P., Das, A., Majumdar, L., Sivaraman, B., Chakrabarti, S.K., Herbst, E.: Mol. Astrophys. 836, 70 (2017b) ADSCrossRefGoogle Scholar
  25. Hall, H.K. Jr., Baldt, J.H.: J. Am. Chem. Soc. 93, 140–145 (1971) CrossRefGoogle Scholar
  26. Haller, I., Pimentel, G.C.: J. Am. Chem. Soc. 84, 2855 (1962) CrossRefGoogle Scholar
  27. Hollis, J.M., Lovas, F.J., Jewell, P.R.: Astrophys. J. 540, 107 (2000) ADSCrossRefGoogle Scholar
  28. Hollis, J.M., Lovas, F.J., Jewell, P.R., Coudert, L.H.: Astrophys. J. 571, L59 (2002) ADSCrossRefGoogle Scholar
  29. Hollis, J.M., Jewell, P.R., Lovas, F.J., Remijan, A., Møllendal, H.: Astrophys. J. 610, L21 (2004) ADSCrossRefGoogle Scholar
  30. Hollis, J.M.: In: Proc. IAU Symposium No. 231 (2005) Google Scholar
  31. Hollis, J.M., Remijan, A.J., Jewell, P.R., Lovas, F.J.: Astrophys. J. 642, 933 (2006) ADSCrossRefGoogle Scholar
  32. Horn, A., Møllendal, H., Sekiguchi, O., et al.: Astrophys. J. 611, 1 (2004) CrossRefGoogle Scholar
  33. Hudson, R.L., Loeffler, M.J.: Astrophys. J. 773, 773–782 (2013) CrossRefGoogle Scholar
  34. Hudson, R.L., Loeffler, M.J., Yocum, K.M.: Astrophys. J. 835, 225 (2017) ADSCrossRefGoogle Scholar
  35. Ikeda, M., Ohishi, M., Nummelin, A., et al.: Astrophys. J. 560, 792 (2001) ADSCrossRefGoogle Scholar
  36. Irvine, W.M., Brown, R.D., Cragg, D.M., et al.: Astrophys. J. 335, L89 (1988) ADSCrossRefGoogle Scholar
  37. Martin, J.M.L., de Oliveira, G.: J. Chem. Phys. 111, 1843–1856 (1999) ADSCrossRefGoogle Scholar
  38. McGuire, B.A., Carroll, P.B., Loomis, R.A., Finneran, I.A., Jewell, P.R., Remijan, A.J., Blake, G.A.: Science 352, 1449–1552 (2016) ADSCrossRefGoogle Scholar
  39. Mehringer, D.M., Snyder, L.E., Miao, Y., Lovas, F.: Astrophys. J. 480, 71 (1997) ADSCrossRefGoogle Scholar
  40. Orlov, V.M., Krivoruchko, A.A., Misharev, A.D., Takhistov, V.V.: Bull. Acad. Sci. USSR, Div. Chem. Sci., 2404–2405 (1986) Google Scholar
  41. Pearson, J.C., Sastry, K.V.L.N., Herbst, E., De Lucia, F.C.: Astrophys. J. 480, 420 (1997) ADSCrossRefGoogle Scholar
  42. Petrie, S.: Astrophys. J. 454, L165 (1995) ADSCrossRefGoogle Scholar
  43. Peeters, Z., Rodgers, S.D., Charnley, S.B., Schriver-Mazzuoli, L., Schriver, A., Keane, J.V., Ehrenfreund, P.: Astron. Astrophys. 445, 197 (2006) ADSCrossRefGoogle Scholar
  44. Remijan, A., Snyder, L.E., Friedel, D.N., Liu, S.-Y., Shah, R.Y.: Astrophys. J. 590, 314 (2003) ADSCrossRefGoogle Scholar
  45. Sil, M., Gorai, P., Das, A., Bhat, B., Etim, E.E., Chakrabarti, S.K.: Astrophys. J. (2017, in press) Google Scholar
  46. Snyder, L.E., Buhl, D., Schwartz, P.R., et al.: Astrophys. J. 191, 79 (1974) ADSCrossRefGoogle Scholar
  47. Snyder, L.E., Lovas, F.J., Mehringer, D.M., et al.: Astrophys. J. 578, 245 (2002) ADSCrossRefGoogle Scholar
  48. Torres, M.A., Pitando-Martin, J., Martin, S., Morris, M.R.: Astrophys. J. 672, 352 (2008) ADSCrossRefGoogle Scholar
  49. Tercero, B., Kleiner, I., Cernicharo, J., Nguyen, H.V.L., Lopez, A., Munoz Caro, G.M.: Astrophys. J. Lett. 770, 13 (2013) ADSCrossRefGoogle Scholar
  50. Turner, B.E.: Astrophys. J. 213, L75 (1977) ADSCrossRefGoogle Scholar
  51. Turner, B.E., Apponi, A.J.: Astrophys. J. 561, L207 (2001) ADSCrossRefGoogle Scholar
  52. Ward, M.D., Price, S.D.: Astrophys. J. 741, 121 (2011) ADSCrossRefGoogle Scholar
  53. Zhou, L., Kaiser, R.I., Gao, L.G., et al.: Astrophys. J. 686, 1493 (2008) ADSCrossRefGoogle Scholar
  54. Zuckerman, B., Turner, B.E., Johnson, D.R., et al.: Astrophys. J. 196, 99 (1975) ADSCrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media B.V., part of Springer Nature 2017

Authors and Affiliations

  • Emmanuel E. Etim
    • 1
    • 2
  • Prasanta Gorai
    • 3
  • Ankan Das
    • 3
  • Elangannan Arunan
    • 2
  1. 1.Department of Chemical SciencesFederal University WukariTaraba StateNigeria
  2. 2.Inorganic and Physical Chemistry DepartmentIndian Institute of ScienceBangaloreIndia
  3. 3.Indian Centre for Space PhysicsKolkataIndia

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