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Adsorption

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Evaluation of the thermal regeneration of an amine-grafted mesoporous silica used for CO2/N2 separation

  • Rafaelle G. Santiago
  • Rafael M. Siqueira
  • Caiuã A. Alves
  • Enrique Vilarrasa-García
  • Débora A. S. Maia
  • Moisés Bastos-Neto
  • Diana C. S. de AzevedoEmail author
Article
  • 11 Downloads

Abstract

In view of the promising applicability of adsorption to the capture of CO2 from post-combustion gases, the use of mesoporous silica functionalized with 3-aminopropyltriethoxysilane (APTES) was studied as adsorbent in a fixed bed for CO2–N2 separation under thermal swings. Characterization of the adsorbent performed before and after functionalization indicated that amine grafting was successful. Additionally, CO2 adsorption on a magnetic suspension balance showed a significant increase in uptake of the APTES-functionalized sample over the support, mainly at low relative pressures. Relatively high values of adsorption enthalpy suggest the occurrence of chemical adsorption attributed to CO2 bonding with the amines. Breakthrough curves were measured for pure CO2, N2 and the CO2/N2 (15/75% v/v) mixture, which showed good agreement with respect to the uptake of the individual gases, as determined from gravimetric tests. Full CO2 desorption from the bed required a temperature rise, which suggests that these materials may be suitable for TSA cyclic processes. A temperature of 90 °C was enough for a complete regeneration of the adsorbent during the desorption phase under dynamic conditions. The material showed very stable behavior after 20 successive cycles.

Keywords

Silica APTES CO2 Adsorption TSA 

Notes

Acknowledgements

The authors acknowledge financial support from CNPq (Conselho Nacional de Desenvolvimento Científico e Tecnológico) and CAPES (Coordenação de Aperfeiçoamento de Pessoal de Nível Superior).

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  • Rafaelle G. Santiago
    • 1
  • Rafael M. Siqueira
    • 1
  • Caiuã A. Alves
    • 1
  • Enrique Vilarrasa-García
    • 1
  • Débora A. S. Maia
    • 1
  • Moisés Bastos-Neto
    • 1
  • Diana C. S. de Azevedo
    • 1
    Email author
  1. 1.Universidade Federal do Ceará, Departamento de Engenharia Química, Grupo de Pesquisa em Separações por Adsorção (GPSA)FortalezaBrazil

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