, Volume 17, Issue 1, pp 227–233 | Cite as

A TPD-MS study of the adsorption of ethanol/cyclohexane mixture on activated carbons

  • Camelia Matei GhimbeuEmail author
  • Roger Gadiou
  • Joseph Dentzer
  • Loïc Vidal
  • Cathie Vix-Guterl


The adsorption of ethanol/cyclohexane binary mixtures on different types of activated carbons was studied in this work by temperature programmed desorption coupled with mass spectroscopy (TPD-MS). The texture, morphology and surface chemistry of the carbons were evaluated by N2 adsorption, scanning electron microscopy (SEM) and TPD-MS techniques. The ethanol and cyclohexane TPD-MS desorption profiles showed that specific interactions between the carbon material and the adsorbate are involved during the adsorption. Most of the activated carbons adsorb strongly ethanol on the surface, leading to desorption temperatures above 100 °C. Only one carbon exhibits an affinity for cyclohexane. These observations were correlated to the different surface chemistry of the materials.


Activated carbon Temperature programmed desorption Ethanol Cyclohexane 


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  1. Figueiredo, J.L., Pereira, M.F.R., Freitas, M.M.A., Orfao, J.J.M.: Modification of the surface chemistry of activated carbons. Carbon 37, 1379–1389 (1999) CrossRefGoogle Scholar
  2. Furukawa, S.I., Goda, K., Zhang, Y., Nitta, T.: Molecular simulation study on the adsorption and diffusion of ethanol/water molecules in NaA zeolite crystal. J. Chem. Eng. Jpn. 37, 67–84 (2004) CrossRefGoogle Scholar
  3. Hershberger, J., Woodford, J.B., Erdemir, A., Frenske, G.R.: Friction and wear behaviour of near-frictionless carbon coatings in formulated gasolines. Surf. Coat. Technol. 183, 111–117 (2004) CrossRefGoogle Scholar
  4. Hu, Z.L., Chen, Z.H., Xia, J.T.: Study on surface film in wear of electrographite brushes against copper commutators for variable current and humidity. Wear 264, 11–17 (2008) CrossRefGoogle Scholar
  5. Kanyo, T., Konya, Z., Kukovecz, A., Berger, F., Dekany, I., Kiricsi, I.: Quantitative characterization of hydrophilic-hydrophobic properties of MWNTs surfaces. Langmuir 20, 1656–1661 (2004) CrossRefGoogle Scholar
  6. Kruk, M., Jaroniec, M., Gadkaree, K.P.: Nitrogen adsorption studies of novel synthetic active carbons. J. Colloid Interface Sci. 192, 250–256 (1997) CrossRefGoogle Scholar
  7. Magalhaes, F.D., Laurence, R.L., Conner, W.C.: Diffusion of cyclohexane and alkylcyclohexanes in silicalite. J. Phys. Chem. B 102, 2317–2324 (1998) CrossRefGoogle Scholar
  8. McKee, D.W., Savage, R.H., Gunnoe, G.: Chemicals factors in carbon brush wear. Wear 22, 193–214 (1972) CrossRefGoogle Scholar
  9. Munusamy, V., Gadiou, R., Anselme, K., Ghimbeu, C., Vix-Guterl, C., Orikasa, H., Kyotani, T., Ittisanronnachai, S.: The influence of surface chemistry and pore size on the adsorption of proteins on nanostructured carbon materials. Adv. Funct. Mater. 20, 2489–2499 (2010) CrossRefGoogle Scholar
  10. Perry, R., Gee, I.L.: Vehicle emissions in relation to fuel composition. Sci. Total Environ. 168, 149–156 (1995) Google Scholar
  11. Rietsch, J.-C., Dentzer, J., Dufour, A., Schnell, F., Vidal, L., Jacquemard, P., Gadiou, R., Vix-Guterl, C.: Characterizations of C/C composites and wear debris after heavy braking demands. Carbon 47, 85–93 (2009) CrossRefGoogle Scholar
  12. Robert, F., Csapo, E., Zaidi, H., Paulmier, D.: Influence of the current and environment on the superficial structure of a graphite electrical collector. Int. J. Mach. Tools Manuf. 35, 259–262 (1995) CrossRefGoogle Scholar
  13. Wilk, A., Moson, I.: The wave character of commutator wear in electrical machines. Wear 253, 935–945 (2002) CrossRefGoogle Scholar
  14. Xia, J.-T., Hu, Z.-L., Chen, Z.-H., Ding, G.Y.: Preparation of carbon brushes with thermosetting resin binder. Trans. Nonferr. Met. Soc. China 17, 1379–1384 (2009) CrossRefGoogle Scholar
  15. Yamamoto, T., Bekki, K., Sawa, K.: A study on brush wear under commutation arc in gasoline. In: Proceedings on the Forty-first IEEE Holm Conference on Electrical Contacts, pp. 323–329 (1995) CrossRefGoogle Scholar
  16. Yasar, I., Canakci, A., Arslan, A.: The effect of brush spring pressure on the wear behaviour of copper-graphite brushes with electrical current. Tribol. Int. 40, 1381–1386 (2007) CrossRefGoogle Scholar
  17. Yoichi, M., Satoshi, K., Shozo, I., Takeshi, M., Tetsushi, U.: Development of long life carbon brush. Denso Tech. Rev. 7, 84–88 (2002) Google Scholar
  18. Zhongliang, H., Zhenhua, C., Jintong, X., Guoyun, D.: Effect of PV factor on the wear of carbon brushes for micromotors. Wear 265, 336–340 (2008) CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2011

Authors and Affiliations

  • Camelia Matei Ghimbeu
    • 1
    Email author
  • Roger Gadiou
    • 1
  • Joseph Dentzer
    • 1
  • Loïc Vidal
    • 1
  • Cathie Vix-Guterl
    • 1
  1. 1.Institut de Science des Matériaux de MulhouseCNRS LRC 7228MulhouseFrance

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