Skip to main content
Log in

Adsorption of Chromium (VI) on Azadirachta Indica (Neem) Leaf Powder

  • Published:
Adsorption Aims and scope Submit manuscript

Abstract

A novel adsorbent was developed from mature leaves of the Neem tree (Azadirachta Indica) for removing metal ions from water. The adsorbent, in the form of fine powder, was found to be very effective in removing chromium (VI) from aqueous solution. The adsorption was carried out in a batch process taking different concentrations of the metal ion in aqueous solution with variation in adsorbent amount, pH, agitation time and temperature. The suitability of the adsorbent was tested with Langmuir and Freundlich isotherms and with various equilibrium kinetic data. A small amount of the Neem Leaf Powder (NLP) (1.6 g dm−3) could remove as much as 87% of Cr (VI) in 300 min from a solution of concentration 14.1 mg dm−3 at 300 K. The optimum range of pH for the adsorption process was 4.5–7.5 and since the natural pH of the Cr (VI) solution was 5.5, no addition of acid or alkali was necessary for achieving maximum adsorption. The adsorption coefficients indicated a high potentiality for the NLP to be used as an adsorbent for removing Cr (VI) from water.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  • Aksu, Z., U. Acikel, E. Kabasakal, and S. Tezer, “Equilibrium modeling of individual and simultaneous biosorption of chromium (VI) and Ni (II) onto dried activated sludge”, Water Res., 36, 3063–3073 (2002).

    CAS  Google Scholar 

  • ATSDR, “Chromium Fact Sheet, Agency for Toxic Substances and Disease Registry (ATSDR)”, USA (http://www.atsdr.cdc.gov), 2001.

  • Bailey, S.E., T.J. Olin, R.M. Bricka, and D.D. Adrian, “A Review of Potentially Low Cost Sorbents for Heavy Metals”, Walter Res., 33, 2469–2479 (1999).

    CAS  Google Scholar 

  • Bayat, B., “Comparative Study of Adsorption Properties of Turkish Fly Ashes. II. The Case of Chromium (VI) and Cadmium (II)”, J. Hazardous Materials, 95, 275–290 (2002).

    CAS  Google Scholar 

  • Chattopadhyay, R.R., R.N. Chattopadhyay, and S.K. Maitra, “Possible Mechanism of Anti-Inflammatory Activity of Azadirchta Indica Leaf Extract”, Indian J. Pharmacol, 25, 99–100 (1993).

    Google Scholar 

  • Chopra, R.N., S.L. Nayer, I.C. Chopra, Glossary of Indian Medicinal Plants, p. 31, C.S.I.R., New Delhi, 1956.

  • Chu, K.H., “Removal of Copper from Aqueous Solution by Chitosan in Prawn Shell: Adsorption Equilibrium and Kinetics”, J. Hazardous Materials, B90, 77–95 (2002).

    Google Scholar 

  • Cieslak-Golonka, M., “Toxic and Mutagenic Effects of Chromium (VI)”, Polyhedron, 15, 3667–3689 (1995).

    Google Scholar 

  • Dakiky, M., M. Khamis, A. Manassra, and M. Mereb, “Selective Adsorption of Chromium (VI) in Industrial Wastewater Using Low-Cost Abundantly Available Adsorbents”, Advances in Environmental Research, 6, 533–540 (2002).

    CAS  Google Scholar 

  • Daneshvar, N. D. Salari, and S. Aber, “Chromium Adsorption and Chromium (VI) Reduction to Trivalent Chromium in Aqueous Solutions by Soya Cake”, Journal of Hazardous Materials, B94, 49–61 (2002).

    Google Scholar 

  • Dantas, T.N. De Castro, A.A. Dantas Neto, and M.C.P. De A. Moura, “Removal of Chromium from Aqueous Solutions by Diatomite Treated with Microemulsion”, Water Res., 35, 2219–2224 (2001).

    CAS  Google Scholar 

  • Dutta, M., “Adsorption of Certain Beta-Lactam Antibiotics on Activated Carbon/Polymeric Resins: Equilibrium and Kinetic Studies”, Ph.D. thesis (unpublished), Gauhati University, India, 1999.

  • Gupta, V.K., M. Gupta, and S. Sharma, “Process Development for the Removal of Lead and Chromium from Aqueous Solutions Using Red Mud—An Aluminum Industry Waste”, Water Res., 35, 1125–1134 (2001).

    CAS  Google Scholar 

  • Hall, K.R., L.C. Eagleton, A. Acrivos., and T. Vermeulen, “Pore and Solid Diffusion Kinetics in Fixed Bed Adsorption under Constant Pattern Conditions”, Ind. Eng. Chem. Fund., 5, 212–219 (1966).

    CAS  Google Scholar 

  • Ho, Y.S. and G. Mckay, “A comparison of Chemisorption Kinetic Models Applied to Pollutant Removal on Various Sorbents”, Trans. IChemE., 76B, 332–340 (1998).

    Google Scholar 

  • Ho, Y.S. and G. Mckay, “Comparative Sorption Kinetic Studies of Dyes and Aromatic Compounds onto Fly Ash”, J. Environ. Sci. Health, A34, 1179–1204 (1999).

    Article  CAS  Google Scholar 

  • Khan, S.A., R. Rehman and M.A. Khan, “Adsorption of Cr (III), Cr (VI) and Ag (I) on Bentonite”, Waste Mgmt., 15, 271–282 (1995).

    CAS  Google Scholar 

  • Kraus, W., “Biologically Active Ingredients”, in The Neem Tree, H. Schmutterer (Ed.), pp.35–92, VCH, Weinheim, 1995.

    Google Scholar 

  • Langmuir, K., J. Chem. Soc., 40, 1361 (1918).

    CAS  Google Scholar 

  • Majumdar, A.M., A.S. Upadhyay, and A.M. Pradhan, “Effect of Azadirachta Indica Leaf Extract on Carbontetrachloride-Induced Hepatic Damage in Albino Rats”, Indian J. Pharm. Sci., 60, 363–367 (1998).

    Google Scholar 

  • Namasivayam, C. and R.T. Yamuna, “Adsorption of Chromium (VI) by a Low Cost Adsorbent: Biogas Slurry”, Chemosphere, 30, 561–578 (1995).

    CAS  Google Scholar 

  • National Research Council, Neem: A Tree for Solving Global Problems, Report of an adhoc panel of the Board on Science and Technology for International development, National Academy Press, D.C. Washington, 1992.

  • Neem Foundation, Chemical composition of Neem Tree, from the website http://www.neemfoundation.org, 1997.

  • Norseth, T., “The Carcinogenicity of Chromium and its Salts”, Br. J. Ind. Med., 43, 649–651 (1986).

    CAS  Google Scholar 

  • Panday, K.K, G. Prasad, and V.N. Singh, “Removal of Cr(VI) from Aqueous Solution by Adsorption on Fly Ash Wollastonites”, J. Chem. Technol. Biotechnol. A-Chemical Technology, 34, 367–374 (1984).

    Article  Google Scholar 

  • Rawat, N.S., “Neem Plantation for Better Pesticides for Reducing Poverty and for Protecting Environment in India”, Indian J. Environ. Protection, 14, 433–439 (1994).

    Google Scholar 

  • Sanches-Polo, M. and J. Rivera-Utrilla, “Adsorbent-Adsorbate Interactions in the Adsorption of Cd(II) and Hg(II) on Ozonized Activated Carbons”, Environ. Sci. Technol., 36, 3850–3854 (2002).

    Google Scholar 

  • Schmutterer, H., “The Tree and its Characteristics”, in The Neem Tree, H. Schmutterer (Ed.), PP.1–34, VCH, Weinheim, 1995.

    Google Scholar 

  • Sharma, D.C. and C.F. Forster, “Removal of Hexavalent Chromium Using Sphagnum Moss Peat”, Water Res., 27, 1201–1208 (1993).

    CAS  Google Scholar 

  • Sharma, D.C. and C.F. Forster, “The Treatment of Chromium Wastewaters Using the Sorptive Potential of Leaf Mold”, Bioresource Technol., 49, 31–40 (1994).

    CAS  Google Scholar 

  • Sharma, D.C. and C.F. Forster, “Removal of Hexavalent Chromium from Aqueous Solutions by Granular Activated Carbon”, Water SA, 22, 153–160 (1996).

    CAS  Google Scholar 

  • Skellon, J.H., S. Thorburn, J. Spence, S.N. Chatterjee (1962). The Fatty Acids of Neem Oil and their Reduction Products, Journal of Scientific Food Agriculture, 13, 639–643 (1962).

    CAS  Google Scholar 

  • Summers, R.S. and P.V. Roberts, “GAC Adsorption of Humic Substances II. Size Exclusion and Electrostatic Interactions”, J. Colloid. Interface. Sci., 122, 382–397 (1988).

    CAS  Google Scholar 

  • Thomas, W. John, “Crittenden, Barry”, in Adsorption Technology and Design, Butterworth, Heinemann, Oxford, 1998.

    Google Scholar 

  • US Department of Health and Human Services, Toxicological Profile for Chromium, Public Health Services Agency for Toxic Substances and Disease Registry, DC Washington, 1991.

  • Venugopal, P.V. and T.V. Venugopal, “Antidermatophytic Activity of Neem (Azadirachta indica) Leaves In Vitro”, Indian J. Pharmacol., 26, 141–143 (1994).

    Google Scholar 

  • Vogel, A.I., Textbook of Quantitative Inorganic Analysis, p. 791, 3rd edn., ELBS, 1969.

  • Weber, W.J. and J.C. Morris, “Kinetics of Adsorption on Carbon Solution”, J. San. Eng. Div. ASCE, 89, 31–59 (1963).

    Google Scholar 

  • WHO, Technical Report Series, No. 546 (Assessment of Carcinogenicity and Mutagenicity of Chemicals—Report of a WHO Scientific Group), World Health Organization, Geneva, 19 p. 1974.

  • Wu, Feng-Chin, Tseng, Ru-Ling, and Juang, Ruey-Shin. “Comparative Adsorption of Metal and Dye on Flake- and Bead-Types of Chitosans Prepared from Fishery Wastes”, J. Hazard. Materials, B73, 63–75 (2000).

    Google Scholar 

  • Yabe, Maria Josefa Santos and de Oliveira, Elisabeth. “Heavy Metals Removal in Industrial Effluents by Sequential Adsorbent Treatment”, Advances in Environmental Research, 7, 263–272 (2003).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Krishna G. Bhattacharyya.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sharma, A., Bhattacharyya, K.G. Adsorption of Chromium (VI) on Azadirachta Indica (Neem) Leaf Powder. Adsorption 10, 327–338 (2005). https://doi.org/10.1007/s10450-005-4818-x

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10450-005-4818-x

Keywords

Navigation