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Chromatographia

, Volume 82, Issue 4, pp 757–766 | Cite as

Melamine–Formaldehyde Aerogel Doped with Boron Nitride Nanosheets as the Coating of In-Tube Solid-Phase Microextraction

  • Chunying Li
  • Juanjuan Feng
  • Xiuqin Wang
  • Yu Tian
  • Xiangping Ji
  • Chuannan Luo
  • Min SunEmail author
Original
  • 49 Downloads
Part of the following topical collections:
  1. Recent Trends in Solid-Phase Extraction for Environmental, Food and Biological Sample Preparation

Abstract

To improve the performance of melamine–formaldehyde (MF) aerogel, boron nitride nanosheets (BNNs) were doped in it to get a new aerogel. The aerogel was prepared as a coating, and basalt fibers modified with it were filled in a polyetheretherketone tube for in-tube solid-phase microextraction. Its morphological structure was characterized by scanning electron microscopy. Connected with high performance liquid chromatography, it was investigated with several polycyclic aromatic hydrocarbons (PAHs) as model analytes. An online analytical method was established under the optimized conditions, including extraction volume, extraction flow rate, methanol content in sampling solution and desorption time. The method had wide linear ranges (0.016–15 µg L−1, 0.016–20 µg L−1, 0.030–20 µg L−1), satisfactory correlation coefficients (0.9968–0.9997) and low limits of detection (0.005–0.010 µg L−1). The relative standard deviations (RSDs, n = 3) of the method were in the ranges of 0.5–6.1% (intra-day) and 2.2–8.8% (inter-day). RSDs of preparation repeatability among three tubes ranged from 0.4 to 2.9%. Compared with MF aerogel coating and other materials, BNNs-doped MF aerogel showed better limits of detection, higher enrichment factors (1015–1846) and comparable extraction time, due to large specific surface area and π–π interaction with PAHs. The method was applied to detect PAHs in rainwater and a soil solution.

Keywords

Boron nitride nanosheets Melamine–formaldehyde aerogel Solid-phase microextraction High performance liquid chromatography Online analysis 

Notes

Acknowledgements

This research work was financially supported by the National Natural Science Foundation of China (NSFC, No. 21777054) and the Shandong Provincial Natural Science Foundation of China (No. ZR2017MB043).

Compliance with Ethical Standards

Conflict of interest

The author declares that he has no conflict of interest.

Ethical approval

This article does not contain any studies with human participants or animals performed by the authors.

Supplementary material

10337_2019_3707_MOESM1_ESM.docx (244 kb)
Supplementary material 1 (DOCX 244 KB)

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Chunying Li
    • 1
  • Juanjuan Feng
    • 1
  • Xiuqin Wang
    • 1
  • Yu Tian
    • 1
  • Xiangping Ji
    • 1
  • Chuannan Luo
    • 1
  • Min Sun
    • 1
    Email author
  1. 1.Key Laboratory of Interfacial Reaction & Sensing Analysis in Universities of Shandong, School of Chemistry and Chemical EngineeringUniversity of JinanJinanPeople’s Republic of China

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