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Fenton oxidation for effective removal of color and organic matter from denim cotton wastewater without biological treatment

  • Seval SözenEmail author
  • Tugba Olmez-Hanci
  • Masoomeh Hooshmand
  • Derin Orhon
Original Paper
  • 11 Downloads

Abstract

Denim is a cotton fabric specifically used to manufacture jeans. Denim processing generates complex effluents with high levels of pumice stone, color and chemical oxygen demand (COD). There is therefore a need for advanced treatment methods to limit pollution of natural waters. Here, we hypothesized that Fenton oxidation, a method using Fe2+ and H2O2, could replace the traditional step of activated sludge treatment. We studied a daily composite sample at laboratory scale for preliminary settling, chemical settling and Fenton oxidation. We found that pumice stone can be effectively controlled by preliminary settling with partial COD removal and limited color removal. Chemical treatment improved COD removal, but color reduction still remained partial. Fenton oxidation decreased color below visual detection after 5 min and COD decreased to 110 mg/L after 30 min. These findings surpassed the performances of activated sludge treatment.

Keywords

Fenton oxidation Denim wastewater Pumice stone Color removal COD removal Activated sludge process 

Notes

References

  1. APHA (2005) Standard methods for the examination of water and wastewater, 21st edn. American Water Works Association/Water Environment Federation, WashingtonGoogle Scholar
  2. Bilińska L, Blus K, Gmurek M, Ledakowicz S (2019) Coupling of electrocoagulation and ozone treatment for textile wastewater reuse. Chem Eng J 358:992–1001.  https://doi.org/10.1016/j.cej.2018.10.093 CrossRefGoogle Scholar
  3. Bolobajev J, Kattel E, Viisimaa M, Goi A, Trapido M, Tenno T, Dulova N (2014) Reuse of ferric sludge as an iron source for the Fenton-based process in wastewater treatment. Chem Eng J 255:8–13.  https://doi.org/10.1016/j.cej.2014.06.018 CrossRefGoogle Scholar
  4. Germirli Babuna F, Ubay Orhon D, Çokgör E, Insel G, Yaprakli B (1998) Modelling of activated sludge for textile wastewaters. Water Sci Technol 38(4–5):9–17.  https://doi.org/10.1016/S0273-1223(98)00492-2 CrossRefGoogle Scholar
  5. Holkar CR, Jadhav AJ, Pinjari DV, Mahamuni NM, Pandit AB (2016) A critical review on textile wastewater treatments: possible approaches. J Environ Manag 182:351–366.  https://doi.org/10.1016/j.jenvman.2016.07.090 CrossRefGoogle Scholar
  6. Hooshmand M (2019) Chemically enhanced activated sludge process for the biodegradation of denim processing wastewaters. Master thesis, Istanbul Technical UniversityGoogle Scholar
  7. ISO 6060 (1986) Water quality-determination of the chemical oxygen demand. International Standards Organization (ISO), BrusselsGoogle Scholar
  8. ISO 7887 (2011) Water quality—examination and determination of colou. International Standards Organization (ISO), BrusselsGoogle Scholar
  9. Lahkimi A, Chaouch M, Oturan N, Oturan MA (2007) Removal of textile dyes from water by electro-Fenton process. Environ Chem Lett 5:35–39.  https://doi.org/10.1007/s10311-006-0058-x CrossRefGoogle Scholar
  10. Manenti DR, Módenes AN, Soares PA, Espinoza-Quiñones FR, Boaventura RA, Bergamasco R, Vilar VJ (2014) Assessment of a multistage system based on electrocoagulation, solar photo-Fenton and biological oxidation processes for real textile wastewater treatment. Chem Eng J 252:120–130.  https://doi.org/10.1016/j.cej.2014.04.096 CrossRefGoogle Scholar
  11. Manu B (2007) Physico-chemical treatment of indigo dye wastewater. Color Technol 123(3):197–202.  https://doi.org/10.1111/j.1478-4408.2007.00080.x CrossRefGoogle Scholar
  12. Meerbergen K, Crauwels S, Willems KA, Dewil R, Van Impe J, Appels L, Lievens B (2017) Decolorization of reactive azo dyes using a sequential chemical and activated sludge treatment. J Biosci Bioeng 124(6):668–673.  https://doi.org/10.1016/j.jbiosc.2017.07.005 CrossRefGoogle Scholar
  13. Orhon D, Hanhan O, Görgün E, Sözen S (1998) A unified basis for the design of nitrogen removal activated sludge process—the Braunschweig exercise. Water Sci Technol 38(1):227–236.  https://doi.org/10.1016/S0273-1223(98)00408-9 CrossRefGoogle Scholar
  14. Orhon D, Taşli R, Sözen S (1999) Experimental basis of activated sludge treatment for industrial wastewaters-the state of the art. Water Sci Technol 40(1):1–11.  https://doi.org/10.1016/S0273-1223(99)00357-1 CrossRefGoogle Scholar
  15. Orhon D, Germirli Babuna F, Insel G (2001) Characterization and modelling of denim processing wastewaters for activated sludge. J Chem Technol Biot 76(9):919–931.  https://doi.org/10.1002/jctb.462 CrossRefGoogle Scholar
  16. Orhon D, Germirli Babuna F, Karahan O (2009) Industrial wastewater treatment by activated sludge. IWA Publishing, LondonCrossRefGoogle Scholar
  17. Oturan MA, Aaron J-J (2014) Advanced oxidation processes in water/wastewater treatment: principles and applications. A review. Crit Rev Environ Sci Technol 44:2577–2641.  https://doi.org/10.1080/10643389.2013.829765 CrossRefGoogle Scholar
  18. Paździor K, Bilińska L, Ledakowicz S (2018) A review of the existing and emerging technologies in the combination of AOPs and biological processes in industrial textile wastewater treatment. Chem Eng J.  https://doi.org/10.1016/j.cej.2018.12.057 Google Scholar
  19. Roshini PS, Gandhimathi R, Ramesh ST, Nidheesh PV (2017) Combined electro-Fenton and biological processes for the treatment of industrial textile effluent: mineralization and toxicity analysis. J Hazard Toxic Radioact Waste 21(4):04017016-1–04017016-8.  https://doi.org/10.1061/(asce)hz.2153-5515.0000370 CrossRefGoogle Scholar
  20. Shaban M, Abukhadra MR, Shahien MG, Ibrahim SS (2018) Novel bentonite/zeolite-NaP composite efficiently removes methylene blue and Congo red dyes. Environ Chem Lett 16(1):275–280.  https://doi.org/10.1007/s10311-015-0501-y CrossRefGoogle Scholar
  21. Shukla S, Oturan MA (2015) Dye removal using electrochemistry and semiconductor oxide nanotubes. Environ Chem Lett 13(2):157–172.  https://doi.org/10.1007/s10311-017-0658-7 CrossRefGoogle Scholar
  22. Sultan M (2017) Polyurethane for removal of organic dyes from textile wastewater. Environ Chem Lett 15(2):347–366.  https://doi.org/10.1007/s10311-016-0597-8 CrossRefGoogle Scholar
  23. Tarkwa JB, Oturan N, Acayanka E, Laminsi S, Oturan MA (2019) Photo-fenton oxidation of Orange G azo dye: process optimization and mineralization mechanism. Environ Chem Lett 17(1):473–479.  https://doi.org/10.1007/s10311-018-0773-0 CrossRefGoogle Scholar
  24. Töre GY, Güngör R (2011) COD fractionation based biological treatability assessment of segregated & recovered wastewater streams from denim processing plant. Desalin Water Treat 28(1–3):385–394.  https://doi.org/10.5004/dwt.2011.2770 CrossRefGoogle Scholar
  25. Varghese AG, Paul SA, Latha MS (2019) Remediation of heavy metals and dyes from wastewater using cellulose-based adsorbents. Environ Chem Lett 17(2):867–877.  https://doi.org/10.1007/s10311-018-00843-z CrossRefGoogle Scholar
  26. Verma P, Samanta SK (2018) Microwave-enhanced advanced oxidation processes for the degradation of dyes in water. Environ Chem Lett 16(3):969–1007.  https://doi.org/10.1007/s10311-018-0739-2 CrossRefGoogle Scholar
  27. Verma AK, Dash RR, Bhunia P (2012) A review on chemical coagulation/flocculation technologies for removal of colour from textile wastewaters. J Environ Manag 93(1):154–168.  https://doi.org/10.1016/j.jenvman.2011.09.012 CrossRefGoogle Scholar
  28. Wang WL, Cai YZ, Hu HY, Chen J, Wang J, Xue G, Wu QY (2019) Advanced treatment of bio-treated dyeing and finishing wastewater using ozone-biological activated carbon: a study on the synergistic effects. Chem Eng J 359:168–175.  https://doi.org/10.1016/j.cej.2018.11.059 CrossRefGoogle Scholar
  29. Yukseler H, Uzal N, Sahinkaya E, Kitis M, Dilek FB, Yetis U (2017) Analysis of the best available techniques for wastewaters from a denim manufacturing textile mill. J Environ Manag 203:1118–1125.  https://doi.org/10.1016/j.jenvman.2017.03.041 CrossRefGoogle Scholar

Copyright information

© Springer Nature Switzerland AG 2019

Authors and Affiliations

  1. 1.Environmental Engineering Department, Faculty of Civil EngineeringIstanbul Technical UniversityMaslakTurkey
  2. 2.ENVIS Energy and Environmental Systems Research and Development LtdITU ARI TechnocityMaslakTurkey
  3. 3.Environmental Engineering Department, Faculty of Civil and Environmental EngineeringNear East UniversityNicosia, North CyprusTurkey

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