Environmental Chemistry Letters

, Volume 15, Issue 1, pp 125–149 | Cite as

Occurrence and methods to remove arsenic and fluoride contamination in water

  • Sadia Bibi
  • Muhammad Aqeel Kamran
  • Jawairia Sultana
  • Abida FarooqiEmail author


Groundwater contamination with arsenic and fluoride has affected over 300 million people worldwide. Ingestion of arsenic and fluoride for extended period of time or at high concentration causes severe health effects. Arsenic can cause thickening and discoloration of the skin, cardiovascular disorders, cancer and skin lesions. Excessive intake of fluoride leads to dental and skeletal fluorosis and bone deformities. This report reviews the distribution of arsenic and fluoride contamination, their sources, mobilization and associated health risks. Remediation technologies to remove arsenic and fluoride are presented.


Arsenic Fluoride Contamination Health hazard Treatment technologies 


  1. Abdullah M, Fasola M, Muhammad A, Malik SA, Boston N, Bokhari H, Kamran MA, Shafqat MN, Alamdar A, Khan M, Ali N, Eqani SAMAS (2015) Avian feathers as a non-destructive bio-monitoring tool of trace metals signatures: a case study from severely contaminated areas. Chemosphere 119:553–561Google Scholar
  2. Ahmed MF (2001) An overview of arsenic removal technologies in Bangladesh and India. In: Proceedings of BUET-UNU international workshop on technologies for arsenic removal from drinking water, Dhaka, pp 5–7Google Scholar
  3. Ajisha MAT, Rajagopal K (2015) Fluoride removal study using pyrolyzed Delonix regia pod, an unconventional adsorbent. J Environ Sci Technol 12:223–236Google Scholar
  4. Alagumuthu G, Rajan M (2010) Equilibrium and kinetics of adsorption of fluoride onto zirconium impregnated cashew nut shell carbon. Chem Eng 158:451–457Google Scholar
  5. Ali I, Alothman ZA, Sanagi MM (2015) Green synthesis of iron nano-impregnated adsorbent for fast removal of fluoride from water. J Mol Liq 211:457–465Google Scholar
  6. Ali S, Thakur SK, Sarkar A, Shekhar S (2016) Worldwide contamination of water by fluoride. Environ Chem Lett 14:291–315Google Scholar
  7. Alvarez-Silva M, Uribe-Salas A, Nava-Alonso F, Pérez-Garibay R (2009) Adsorption of As(V) onto goethite: experimental statistical optimization. Natural Arsenic in Groundwater of Latin America. In: Bundschuh J, Bhattacharya P (eds) Arsenic in the environment, vol 1. pp 527–534Google Scholar
  8. Amin MN, Kaneco S, Kitagawa T, Begum A, Katsumata H, Suzuki T (2006) Removal of arsenic in aqueous solutions by adsorption onto waste rice husk. Ind Eng Chem Res 45:8105–8110Google Scholar
  9. Amna Ali N, Masood S, Mukhtar T, Kamran MA, Rafique M, Munis MFH, Chaudhary HJ (2015) Differential effects of cadmium and chromium on growth, photosynthetic activity, and metal uptake of Linum usitatissimum in association with Glomus intraradices. Environ Monit Assess 187:1–11Google Scholar
  10. Anawar HM, Akai J, Sakugawa H (2004) Mobilization of arsenic from subsurface sediments by effect of bicarbonate ions in groundwater. Chemosphere 54:753–762Google Scholar
  11. Angelone M, Cremisini C, Piscopo V, Proposito M, Spaziani F (2009) Influence of hydrostratigraphy and structural setting on the arsenic occurrence in groundwater of the Cimino-Vico volcanic area (central Italy). Hydrogeology 17:901–914Google Scholar
  12. Aoudj S, Khelifa A, Drouiche N, Belkada R, Miroud D (2015) Simultaneous removal of chromium(VI) and fluoride by electrocoagulation–electroflotation: application of a hybrid Fe–Al anode. Chem Eng 267:153–162Google Scholar
  13. Appleyard S, Angeloni J, Watkins R (2006) Arsenic-rich groundwater in an urban area experiencing drought and increasing population density, Perth, Australia. Appl Geochem 21:83–97Google Scholar
  14. Archer J, Hudson-Edwards K, Preston D, Howarth R, Linge K (2005) Aqueous exposure and uptake of arsenic by riverside communities affected by mining contamination in the Río Pilcomayo basin, Bolivia. Mineral Mag 69:719–736Google Scholar
  15. Armienta M, Micete S, Flores-Valverde E (2009) Feasibility of arsenic removal from contaminated water using indigenous limestone. Natural Arsenic in Groundwater of Latin America. In: Bundschuh J, Bhattacharya P (eds) Arsenic in the environment, vol 1. p 505e510Google Scholar
  16. Asante KA, Agusa T, Subramanian A, Ansa-Asare OD, Biney CA, Tanabe S (2007) Contamination status of arsenic and other trace elements in drinking water and residents from Tarkwa, a historic mining township in Ghana. Chemosphere 66:1513–1522Google Scholar
  17. Ayoob S, Gupta A (2009) Performance evaluation of alumina cement granules in removing fluoride from natural and synthetic waters. Chem Eng 150:485–491Google Scholar
  18. Ayoob S, Gupta A, Bhakat P, Bhat VT (2008a) Investigations on the kinetics and mechanisms of sorptive removal of fluoride from water using alumina cement granules. Chem Eng 140:6–14Google Scholar
  19. Ayoob S, Gupta A, Bhat VT (2008b) A conceptual overview on sustainable technologies for the defluoridation of drinking water. Crit Rev Environ Sci Technol 38:401–470Google Scholar
  20. Baig JA, Kazi TG, Shah AQ, Kandhro GA, Afridi HI, Khan S (2012) Arsenic speciation and other parameters of surface and ground water samples of Jamshoro, Pakistan. Int J Environ Anal Chem 92:28–42Google Scholar
  21. Baig SA, Sheng T, Sun C, Xue X, Tan L, Xu X (2014) Arsenic removal from aqueous solutions using Fe3O4-HBC composite: effect of calcination on adsorbents performance. PloS one 9(6):e100704. doi: 10.1371/journal.pone.0100704 Google Scholar
  22. Baig SA, Sheng T, Hu Y, Xu J, Xu X (2015) Arsenic removal from natural water using low cost granulated adsorbents: a review. CLEAN Soil Air Water 43:13–26Google Scholar
  23. Baikousi M, Georgiou Y, Daikopoulos C, Bourlinos AB, Filip J, Zbořil R (2015) Synthesis and characterization of robust zero valent iron/mesoporous carbon composites and their applications in arsenic removal. Carbon 93:636–647Google Scholar
  24. Berg M, Tran HC, Nguyen TC, Pham HV, Schertenleib R, Giger W (2001) Arsenic contamination of groundwater and drinking water in Vietnam: a human health threat. Environ Sci Technol 35:2621–2626Google Scholar
  25. Bharali RK, Bhattacharyya KG (2015a) Biosorption of fluoride on Neem (Azadirachta indica) leaf powder. J Environ Chem Eng 3:662–669Google Scholar
  26. Bharali RK, Bhattacharyya KG (2015b) Biosorption of fluoride on Neem (Azadirachta indica) leaf powder. J Environ Chem Eng 3:662–669Google Scholar
  27. Bhattacharjee S, Chakravarty S, Maity S, Dureja V, Gupta K (2005) Metal contents in the groundwater of Sahebgunj district, Jharkhand, India, with special reference to arsenic. Chemosphere 58:1203–1217Google Scholar
  28. Bhaumik M, Noubactep C, Gupta VK, McCrindle RI, Maity A (2015) Polyaniline/Fe 0 composite nanofibers: an excellent adsorbent for the removal of arsenic from aqueous solutions. Chem Eng 271:135–146Google Scholar
  29. Bibi S, Husain SZ, Malik RN (2008) Pollen analysis and heavy metals detection in honey samples from seven selected countries. Pak J Bot 40:507–516Google Scholar
  30. Bibi S, Farooqi A, Hussain K, Haider N (2015a) Evaluation of industrial based adsorbents for simultaneous removal of arsenic and fluoride from drinking water. J Clean Prod 87:882–896Google Scholar
  31. Bibi S, Farooqi A, Ramzan M, Javed A (2015b) Health risk of arsenic in the alluvial aquifers of Lahore and Raiwind, Punjab Province, Pakistan: an investigation for safer well water. Toxicol Environ Chem 97:888–907Google Scholar
  32. Bissen M, Frimmel FH (2003) Arsenic—a review. Part I: occurrence, toxicity, speciation, mobility. Acta Hydrochim Hydrobiol 31:9–18Google Scholar
  33. Biswas K, Gupta K, Goswami A, Ghosh UC (2010) Fluoride removal efficiency from aqueous solution by synthetic iron(III)–aluminum(III)–chromium(III) ternary mixed oxide. Desalination 255:44–51Google Scholar
  34. Boddu VM, Abburi K, Talbott JL, Smith ED, Haasch R (2008) Removal of arsenic(III) and arsenic(V) from aqueous medium using chitosan-coated biosorbent. Water Res 42:633–642Google Scholar
  35. Borah L, Dey N (2009) Removal of fluoride from low TDS water using low grade coal. Ind J Chem Technol 16:361Google Scholar
  36. Brown KG, Ross GL (2002) Arsenic, drinking water, and health: a position paper of the American Council on Science and Health. Regul Toxicol Pharmacol 36:162–174Google Scholar
  37. Buamah R, Oduro C, Sadik M (2016) Fluoride removal from drinking water using regenerated aluminum oxide coated media. J Environ Chem Eng 4:250–258Google Scholar
  38. Bundschuh J, García M, Alvarez M (2007) Arsenic and heavy metal removal by phytofiltration and biogenic sulfide precipitation a comparative study from Poopó Lake basin, Bolivia. Abstract vol 3rd international groundwater conference IGC-2007, water, environment and agriculture–present problems and future challenges, p152Google Scholar
  39. Bundschuh J, Litter M, Ciminelli VS, Morgada ME, Cornejo L, Hoyos SG (2010) Emerging mitigation needs and sustainable options for solving the arsenic problems of rural and isolated urban areas in Latin America: a critical analysis. Water Res 44:5828–5845Google Scholar
  40. Cai H, Chen G, Peng CY, Zhang Z, Dong Y, Shang G (2015) Removal of fluoride from drinking water using tea waste loaded with Al/Fe oxides: a novel, safe and efficient biosorbent. Appl Surf Sci 328:34–44Google Scholar
  41. Camacho LM, Gutiérrez M, Alarcón-Herrera MT, Villalba MdL, Deng S (2011) Occurrence and treatment of arsenic in groundwater and soil in northern Mexico and southwestern USA. Chemosphere 83:211–225Google Scholar
  42. Chaturvedi A, Yadava K, Pathak K, Singh V (1990) Defluoridation of water by adsorption on fly ash. Water Air Soil Pollut 49:51–61Google Scholar
  43. Chen CC, Chung YC (2006) Arsenic removal using a biopolymer chitosan sorbent. J Environ Sci Health A 41:645–658Google Scholar
  44. Chen W, Parette R, Zou J, Cannon FS, Dempsey BA (2007) Arsenic removal by iron-modified activated carbon. Water Res 41:1851–1858Google Scholar
  45. Chen Y, Graziano JH, Parvez F, Liu M, Slavkovich V, Kalra T (2011) Arsenic exposure from drinking water and mortality from cardiovascular disease in Bangladesh: prospective cohort study. BMJ Br Med 342:2431Google Scholar
  46. Chen ML, Sun Y, Huo CB, Liu C, Wang JH (2015) Akaganeite decorated graphene oxide composite for arsenic adsorption/removal and its proconcentration at ultra-trace level. Chemosphere 130:52–58Google Scholar
  47. Chen L, Zhang KS, He JY, Xu WH, Huang XJ, Liu JH (2016) Enhanced fluoride removal from water by sulphate doped hydroxyapatite hierarchical hollow microspheres. Chem Eng 285:616–624Google Scholar
  48. Chwirka J, Thompson BM, Stomp JM III (2000) Removing arsenic from groundwater. J Am Water Works Assoc 92:79–88Google Scholar
  49. Çiftçi TD, Henden E (2015) Nickel/nickel boride nanoparticles coated resin: a novel adsorbent for arsenic(III) and arsenic(V) removal. Powder Technol 269:470–480Google Scholar
  50. Clifford DA, Ghurye G (2002) Metal-oxide adsorption, ion exchange, and coagulation-microfiltration for arsenic removal from water. Marcel Dekker, New YorkGoogle Scholar
  51. Cornejo L, Lienqueo H, Arenas M, Acarapi J, Contreras D, Yanez J (2008) In field arsenic removal from natural water by zero-valent iron assisted by solar radiation. Environ Pollut 156:827–831Google Scholar
  52. Craig L, Stillings LL, Decker DL, Thomas JM (2015) Comparing activated alumina with indigenous laterite and bauxite as potential sorbents for removing fluoride from drinking water in Ghana. Appl Geochem 56:50–66Google Scholar
  53. Cui J, Jing C, Che D, Zhang J, Duan S (2015) Groundwater arsenic removal by coagulation using ferric(III) sulfate and polyferric sulfate: a comparative and mechanistic study. J Environ Sci 32:42–53Google Scholar
  54. Czerniczyniec M, Farías S, Magallanes J, Cicerone D (2007) Arsenic(V) adsorption onto biogenic hydroxyapatite: solution composition effects. Water Air Soil Pollut 180:75–82Google Scholar
  55. Dai M, Xia L, Song S, Peng C, Lopez-Valdivieso A (2016) Adsorption of As(V) inside the pores of porous hematite in water. J Hazard Mater 307:312–317Google Scholar
  56. Dash SS, Sahu MK, Sahu E, Patel RK (2015) Fluoride removal from aqueous solutions using cerium loaded mesoporous zirconium phosphate. New J Chem 39:7300–7308Google Scholar
  57. Dechnik J, Janiak C, De S (2016) Aluminium fumarate metal-organic framework: a super adsorbent for fluoride from water. J Hazard Mater 303:10–20Google Scholar
  58. Deng H, Yu X (2015) Fluoride removal from drinking water by zirconium-impregnated fibrous protein. Desalin Water Treat 54:1594–1603Google Scholar
  59. Dey S, Goswami S, Ghosh UC (2004) Hydrous ferric oxide (HFO) a scavenger for fluoride from contaminated water. Water Air Soil Pollut 158:311–323Google Scholar
  60. Dodd MC, Vu ND, Ammann A, Le VC, Kissner R, Pham HV (2006) Kinetics and mechanistic aspects of As(III) oxidation by aqueous chlorine, chloramines, and ozone: relevance to drinking water treatment. Environ Sci Technol 40:3285–3292Google Scholar
  61. Dong S, Wang Y (2016) Characterization and adsorption properties of a lanthanum-loaded magnetic cationic hydrogel composite for fluoride removal. Water Res 88:852–860Google Scholar
  62. Duarte AA, Oliveira SL, Amorim MT (2011) Arsenic removal from drinking water by advanced filtration processes. In: XIV IWRA World Water Congress. IWRA-CD RomGoogle Scholar
  63. Elwakeel KZ, Guibal E (2015) Arsenic(V) sorption using chitosan/Cu (OH)2 and chitosan/CuO composite sorbents. Carbohydr Polym 134:190–204Google Scholar
  64. Emdadul HM, Sabur MA, Mahamud-Ul-Hoque M, Safiullah S (2016) Competition of various ions present in shallow aquifer water in respect of arsenic removal by hydrated ferric oxide. Asian J Water Environ Pollut 12:25–33Google Scholar
  65. Escobar MO, Hue N, Cutler W (2016) Recent developments on arsenic: contamination and remediation. Recent Res Dev Bioenerg 4:1–32Google Scholar
  66. Eskandarpour A, Onyango MS, Ochieng A, Asai S (2008) Removal of fluoride ions from aqueous solution at low pH using schwertmannite. J Hazard Mater 152:571–579Google Scholar
  67. Fan X, Parker D, Smith M (2003) Adsorption kinetics of fluoride on low cost materials. Water Res 37:4929–4937Google Scholar
  68. Fan L, Zhang S, Zhang X, Zhou H, Lu Z, Wang S (2015) Removal of arsenic from simulation wastewater using nano-iron/oyster shell composites. J Environ Manag 156:109–114Google Scholar
  69. Fang F, Jia Y, Wu PY, Zhang QY, Jiang YP, Zhou SS (2015) Facile one-pot preparation of goethite/parabutlerite nanocomposites and their removal properties and mechanism toward As(V) ions. Appl Surf Sci 324:355–362Google Scholar
  70. Farrah H, Slavek J, Pickering WF (1987) Fluoride interactions with hydrous aluminum oxides and alumina. Soil Res 25:55–69Google Scholar
  71. Fewtrell L, Kaufmann RB, Kay D, Enanoria W, Haller L, Colford JM Jr (2005) Water, sanitation, and hygiene interventions to reduce diarrhoea in less developed countries: a systematic review and meta-analysis. Lancet Infect Dis 5:42–52Google Scholar
  72. Fields K, Chen AS, Wang L, Sorg TJ, Cincinnati O, Columbus O (2000a) Arsenic removal from drinking water by iron removal plants. National Risk Management Research Laboratory, Office of Research and Development, US Environmental Protection AgencyGoogle Scholar
  73. Fields KA, Chen AS, Wang L (2000b) Arsenic removal from drinking water by coagulation/filtration and lime softening plants. National Risk Management Research Laboratory, Office of Research and Development, US Environmental Protection AgencyGoogle Scholar
  74. Flora S, Mittal M (2009) Co-exposure to arsenic and fluoride on oxidative stress, glutathione linked enzymes, biogenic amines and DNA damage in mouse brain. J Neurol Sci 285:198–205Google Scholar
  75. Fox DI, de Lima Stebbins DM, Alcantar N (2016) Combining ferric salt and cactus mucilage for arsenic removal from water. Environ Sci Technol 50(5):2507–2513Google Scholar
  76. Frankenberger JW Jr, Arshad M (2002) Volatilization of arsenic. Environ Chem Arsen 363–380Google Scholar
  77. Gai W-Z, Deng Z-Y, Shi Y (2015) Fluoride removal from water using high-activity aluminum hydroxide prepared by the ultrasonic method. RSC Adv 5:84223–84231Google Scholar
  78. Gallard H, von Gunten U (2002) Chlorination of natural organic matter: kinetics of chlorination and of THM formation. Water Res 36:65–74Google Scholar
  79. García-Sánchez A, Moyano A, Mayorga P (2005) High arsenic contents in groundwater of central Spain. Environ Geol 47:847–854Google Scholar
  80. Ge Q, Han G, Chung T-S (2016) Effective As(III) removal by a multi-charged hydroacid complex draw solute facilitated forward osmosis-membrane distillation (FO-MD) processes. Environ Sci Technol 50(5):2363–2370Google Scholar
  81. Gebel TW (1999) Arsenic and drinking water contamination. Science 283:1458Google Scholar
  82. Ghorai S, Pant K (2005) Equilibrium, kinetics and breakthrough studies for adsorption of fluoride on activated alumina. Sep Purif Technol 42:265–271Google Scholar
  83. Gogoi S, Dutta RK (2016) Fluoride removal by hydrothermally modified limestone powder using phosphoric acid. J Environ Chem Eng 4:1040–1049Google Scholar
  84. Goldberg S, Johnston CT (2001) Mechanisms of arsenic adsorption on amorphous oxides evaluated using macroscopic measurements, vibrational spectroscopy, and surface complexation modeling. J Colloid Interface Sci 234:204–216Google Scholar
  85. Guo H, Yang S, Tang X, Li Y, Shen Z (2008) Groundwater geochemistry and its implications for arsenic mobilization in shallow aquifers of the Hetao Basin, Inner Mongolia. Sci Total Environ 393:131–144Google Scholar
  86. Guo L, Ye P, Wang J, Fu F, Wu Z (2015a) Three-dimensional Fe3O4-graphene macroscopic composites for arsenic and arsenate removal. J Hazard Mater 298:28–35Google Scholar
  87. Guo Z, Dong D, Hua X, Zhang L, Zhu S, Lan X, Liang D (2015b) Cr and As decrease lindane sorption on river solids. Environ Chem Lett 13(1):111–116Google Scholar
  88. Guzmán A, Nava JL, Coreño O, Rodríguez I, Gutiérrez S (2016a) Arsenic and fluoride removal from groundwater by electrocoagulation using a continuous filter-press reactor. Chemosphere 144:2113–2120Google Scholar
  89. Guzmán A, Nava JL, Coreño O, Rodríguez I, Gutiérrez S (2016b) Arsenic and fluoride removal from groundwater by electrocoagulation using a continuous filter-press reactor. Chemosphere 144:2113–2120Google Scholar
  90. Handa BK (1975) Geochemistry and genesis of fluoride‐containing ground waters in india. Ground Water 13:275–281Google Scholar
  91. Harrison PT (2005) Fluoride in water: a UK perspective. J Fluor Chem 126:1448–1456Google Scholar
  92. Hartley W, Dickinson NM, Riby P, Lepp NW (2009) Arsenic mobility in brownfield soils amended with green waste compost or biochar and planted with Miscanthus. Environ Pollut 157:2654–2662Google Scholar
  93. He J, Zhang K, Wu S, Cai X, Chen K, Li Y (2016a) Performance of novel hydroxyapatite nanowires in treatment of fluoride contaminated water. J Hazard Mater 303:119–130Google Scholar
  94. He Z, Lan H, Gong W, Liu R, Gao Y, Liu H (2016b) Coagulation behaviors of aluminum salts towards fluoride: significance of aluminum speciation and transformation. Separat Purifi Technol 165:137–144Google Scholar
  95. Hem JD (1985) Study and interpretation of the chemical characteristics of natural water, vol 2254. Department of the Interior, US Geological SurveyGoogle Scholar
  96. Hlavay J, Polyák K (2005) Determination of surface properties of iron hydroxide-coated alumina adsorbent prepared for removal of arsenic from drinking water. J Colloid Interface Sci 284:71–77Google Scholar
  97. Hu C, Chen Q, Liu H, Qu J (2015a) Coagulation of methylated arsenic from drinking water: influence of methyl substitution. J Hazard Mater 293:97–104Google Scholar
  98. Hu X, Ding Z, Zimmerman AR, Wang S, Gao B (2015b) Batch and column sorption of arsenic onto iron-impregnated biochar synthesized through hydrolysis. Water Res 68:206–216Google Scholar
  99. Huang JW, Poynton CY, Kochian LV, Elless MP (2004) Phytofiltration of arsenic from drinking water using arsenic-hyperaccumulating ferns. Environ Sci Technol 38:3412–3417Google Scholar
  100. Huang PP, Cao CY, Wei F, Sun YB, Song WG (2015a) MgAl layered double hydroxides with chloride and carbonate ions as interlayer anions for removal of arsenic and fluoride ions in water. RSC Adv 5:10412–10417Google Scholar
  101. Huang Y, Miyauchi K, Inoue C, Endo G (2015b) Development of suitable hydroponics system for phytoremediation of arsenic-contaminated water using an arsenic hyperaccumulator plant Pteris vittata. Biosci Biotechnol Biochem 80(3):614–618Google Scholar
  102. Hug SJ, Canonica L, Wegelin M, Gechter D, von Gunten U (2001) Solar oxidation and removal of arsenic at circumneutral pH in iron containing waters. Environ Sci Technol 35:2114–2121Google Scholar
  103. Husain SZ, Malik RN, Javaid M, Bibi S (2008) Ethonobotanical properties and uses of medicinal plants of Morgah biodiversity park, Rawalpindi. Pak J Bot 40(189):7–1911Google Scholar
  104. Husain M, Chavan FI, Abhale B (2015) Use of Maize husk fly ash as an adsorbent for removal of fluoride. Int Res J Eng TechnolGoogle Scholar
  105. Hussam A, Munir AK (2007) A simple and effective arsenic filter based on composite iron matrix: development and deployment studies for groundwater of Bangladesh. J Environ Sci Health A 42:1869–1878Google Scholar
  106. Ike M, Miyazaki T, Yamamoto N, Sei K, Soda S (2008) Removal of arsenic from groundwater by arsenite-oxidizing bacteria. Water Sci Technol 58:1095–1100Google Scholar
  107. Islam M, Patel R (2007) Evaluation of removal efficiency of fluoride from aqueous solution using quick lime. J Hazard Mater 143:303–310Google Scholar
  108. Islam M, Patel R (2011) Thermal activation of basic oxygen furnace slag and evaluation of its fluoride removal efficiency. Chem Eng 169:68–77Google Scholar
  109. Islam FS, Gault AG, Boothman C, Polya DA, Charnock JM, Chatterjee D (2004) Role of metal reducing bacteria in arsenic release from Bengal delta sediments. Nature 430:68–71Google Scholar
  110. Ismail ZZ, AbdelKareem HN (2015) Sustainable approach for recycling waste lamb and chicken bones for fluoride removal from water followed by reusing fluoride-bearing waste in concrete. Waste Manag 45:66–75Google Scholar
  111. Jain C, Singh R (2012) Technological options for the removal of arsenic with special reference to South East Asia. J Environ Manag 107:1–18Google Scholar
  112. Jasrotia S, Kansal A, Mehra A (2015) Performance of aquatic plant species for phytoremediation of arsenic-contaminated water. Appl Water Sci. doi: 10.1007/s13201-015-0300-4 Google Scholar
  113. Jiang JQ (2015) The role of coagulation in water treatment. Curr Opin Chem Eng 8:36–44Google Scholar
  114. Jiang L, Xiao S, Chen J (2015) Removal behavior and mechanism of Co(II) on the surface of Fe–Mn binary oxide adsorbent. Coll Surf A Physicochem Eng Asp 479:1–10Google Scholar
  115. Jin H, Ji Z, Yuan J, Li J, Liu M, Xu C (2015a) Research on removal of fluoride in aqueous solution by alumina-modified expanded graphite composite. J Alloy Compd 620:361–367Google Scholar
  116. Jin Z, Jia Y, Luo T, Kong L-T, Sun B, Shen W (2015b) Efficient removal of fluoride by hierarchical MgO microspheres: Performance and mechanism study. Appl Surf Sci 357:1080–1088Google Scholar
  117. Kagne S, Jagtap S, Dhawade P, Kamble S, Devotta S, Rayalu S (2008) Hydrated cement: a promising adsorbent for the removal of fluoride from aqueous solution. J Hazard Mater 154:88–95Google Scholar
  118. Kamble SP, Jagtap S, Labhsetwar NK, Thakare D, Godfrey S, Devotta S (2007) Defluoridation of drinking water using chitin, chitosan and lanthanum-modified chitosan. Chem Eng 129:173–180Google Scholar
  119. Kamble SP, Dixit P, Rayalu SS, Labhsetwar NK (2009) Defluoridation of drinking water using chemically modified bentonite clay. Desalination 249:687–693Google Scholar
  120. Kameda T, Oba J, Yoshioka T (2015) Kinetics and equilibrium studies on Mg–Al oxide for removal of fluoride in aqueous solution and its use in recycling. J Environ Manag 156:252–256Google Scholar
  121. Kamran MA, Mufti R, Mubariz N, Syed JH, Bano A, Javed MT, Chaudhary HJ (2014) The potential of the flora from different regions of Pakistan in phytoremediation: a review. Environ Sci Pollut Res 21:801–812Google Scholar
  122. Kamran MA, Syed JH, Eqani SAMAS, Munis MFH, Chaudhary HJ (2015) Effect of plant growth-promoting rhizobacteria inoculation on cadmium (Cd) uptake by Eruca sativa. Environ Sci Pollut Res 22:9275–9283Google Scholar
  123. Kamran MA, Eqani SAMAS, Bibi S, Xu RK, Monis MFH, Katsoyiannis A, Bokhari H, Chaudhary HJ (2016a) Bioaccumulation of nickel by E. sativa and role of plant growth promoting rhizobacteria (PGPRs) under nickel stress. Ecotoxicol Environ Saf 126:256–263Google Scholar
  124. Kamran MA, Bibi S, Xu RK, Hussain S, Mehmood K, Chaudhary HJ (2016b) Phyto-extraction of chromium and influence of plant growth promoting bacteria to enhance plant growth. J Geochem Explor. doi: 10.1016/j.gexplo.2016.09.005 CrossRefGoogle Scholar
  125. Kanel SR, Manning B, Charlet L, Choi H (2005) Removal of arsenic(III) from groundwater by nanoscale zero-valent iron. Environ Sci Technol 39:1291–1298Google Scholar
  126. Kang D, Yu X, Tong S, Ge M, Zuo J, Cao C (2013) Performance and mechanism of Mg/Fe layered double hydroxides for fluoride and arsenate removal from aqueous solution. Chem Eng 228:731–740Google Scholar
  127. Kang D, Tong S, Yu X, Ge M (2015) Template-free synthesis of 3D hierarchical amorphous aluminum oxide microspheres with broccoli-like structure and their application in fluoride removal. RSC Adv 5:19159–19165Google Scholar
  128. Kanyora A, Kinyanjui T, Kariuki S, Njogu M (2015) Fluoride removal capacity of regenerated bone char in treatment of drinking water. Asian J Nat Appl Sci 4:1Google Scholar
  129. Kar S, Maity JP, Jean J-S, Liu C-C, Nath B, Yang H-J (2010) Arsenic-enriched aquifers: Occurrences and mobilization of arsenic in groundwater of Ganges Delta Plain, Barasat, West Bengal, India. Appl Geochem 25:1805–1814Google Scholar
  130. Katsoyiannis IA, Zouboulis AI, Jekel M (2004) Kinetics of bacterial As(III) oxidation and subsequent As(V) removal by sorption onto biogenic manganese oxides during groundwater treatment. Ind Eng Chem Res 43:486–493Google Scholar
  131. Katsoyiannis IA, Voegelin A, Zouboulis AI, Hug SJ (2015) Enhanced As(III) oxidation and removal by combined use of zero valent iron and hydrogen peroxide in aerated waters at neutral pH values. J Hazard Mater 297:1–7Google Scholar
  132. Kaygusuz H, Uzaşçı S, Erim FB (2015) Removal of fluoride from aqueous solution using aluminum alginate beads. CLEAN Soil Air Water 43:724–730Google Scholar
  133. Kinniburgh DG, Kosmus W (2002) Arsenic contamination in groundwater: some analytical considerations. Talanta 58:165–180Google Scholar
  134. Ko I, Davis AP, Kim JY, Kim KW (2007) Arsenic removal by a colloidal iron oxide coated sand. J Environ Eng 133:891–898Google Scholar
  135. Kobya M, Ozyonar F, Demirbas E, Sik E, Oncel M (2015) Arsenic removal from groundwater of Sivas-Şarkişla Plain, Turkey by electrocoagulation process: comparing with iron plate and ball electrodes. J Environ Chem Eng 3:1096–1106Google Scholar
  136. Kouras A, Katsoyiannis I, Voutsa D (2007) Distribution of arsenic in groundwater in the area of Chalkidiki, Northern Greece. J Hazard Mater 147:890–899Google Scholar
  137. Ku Y, Chiou HM (2002) The adsorption of fluoride ion from aqueous solution by activated alumina. Water Air Soil Pollut 133:349–361Google Scholar
  138. Kurttio P, Pukkala E, Kahelin H, Auvinen A, Pekkanen J (1999) Arsenic concentrations in well water and risk of bladder and kidney cancer in Finland. Environ Health Perspect 107:705Google Scholar
  139. Larios R, Fernández-Martínez R, Silva V, Rucandio I (2013) Chemical availability of arsenic and heavy metals in sediments from abandoned cinnabar mine tailings. Environ Earth Sci 68:535–546Google Scholar
  140. Lee H, Kim D, Kim J, Ji MK, Han YS, Park YT (2015) As(III) and As(V) removal from the aqueous phase via adsorption onto acid mine drainage sludge (AMDS) alginate beads and goethite alginate beads. J Hazard Mater 292:146–154Google Scholar
  141. Leist M, Casey R, Caridi D (2000) The management of arsenic wastes: problems and prospects. J Hazard Mater 76:125–138Google Scholar
  142. Lescano MR, Passalía C, Zalazar CS, Brandi RJ (2015) Arsenic sorption onto titanium dioxide, granular ferric hydroxide and activated alumina: batch and dynamic studies. J Environ Sci Health A 50:424–431Google Scholar
  143. Li Y-H, Wang S, Cao A, Zhao D, Zhang X, Xu C (2001) Adsorption of fluoride from water by amorphous alumina supported on carbon nanotubes. Chem Phys Lett 350:412–416Google Scholar
  144. Li Y-H, Wang S, Zhang X, Wei J, Xu C, Luan Z (2003) Adsorption of fluoride from water by aligned carbon nanotubes. Mater Res Bull 38:469–476Google Scholar
  145. Liao VHC, Chu YJ, Su YC, Hsiao SY, Wei CC, Liu CW (2011) Arsenite-oxidizing and arsenate-reducing bacteria associated with arsenic-rich groundwater in Taiwan. J Contam Hydrol 123:20–29Google Scholar
  146. Liu R, Zhu L, He Z, Lan H, Liu H, Qu J (2015) Simultaneous removal of arsenic and fluoride by freshly-prepared aluminum hydroxide. Coll Surf A Physicochem Eng Asp 466:147–153Google Scholar
  147. Luu TTG, Sthiannopkao S, Kim KW (2009) Arsenic and other trace elements contamination in groundwater and a risk assessment study for the residents in the Kandal Province of Cambodia. Environ Int 35:455–460Google Scholar
  148. Luzi S, Berg M, Pham T, Pham H, Schertenleib R (2004) Household sand filters for arsenic removal. Swiss Federal Institute for Environmental Science and Technology (EAWAG), Duebendorf, SwitzerlandGoogle Scholar
  149. Maheshwari R (2006a) Fluoride in drinking water and its removal. J Hazard Mater 137:456–463Google Scholar
  150. Maheshwari R (2006b) Fluoride in drinking water and its removal. J Hazard Mater 137(1):456–463Google Scholar
  151. Mahramanlioglu M, Kizilcikli I, Bicer I (2002) Adsorption of fluoride from aqueous solution by acid treated spent bleaching earth. J Fluor Chem 115:41–47Google Scholar
  152. Maiti A, Basu JK, De S (2011) Chemical treated laterite as promising fluoride adsorbent for aqueous system and kinetic modeling. Desalination 265:28–36Google Scholar
  153. Malakootian M, Javdan M, Iranmaneshc F (2015) Fluoride removal study from aqueous solutions using Jajarm bauxite: case study on Koohbanan water. Fluoride 48:113–122Google Scholar
  154. Malik AH, Khan ZM, Mahmood Q, Nasreen S, Bhatti ZA (2009) Perspectives of low cost arsenic remediation of drinking water in Pakistan and other countries. J Hazard Mater 168:1–12Google Scholar
  155. Mandal S (2015) Development of new adsorbent materials for the removal of arsenic (III) and chromium (VI) from water and its mathematical modelling (Doctoral dissertation)Google Scholar
  156. Mandal BK, Suzuki KT (2002) Arsenic round the world: a review. Talanta 58:201–235Google Scholar
  157. Mariappan R, Vairamuthu R, Ganapathy A (2015) Use of chemically activated cotton nut shell carbon for the removal of fluoride contaminated drinking water: kinetics evaluation. Chin J Chem Eng 23:710–721Google Scholar
  158. Martin DF, O’Donnell L, Martin BB, Alldredge R (2007) Removal of aqueous arsenic using iron attached to immobilized ligands (IMLIGs). J Environ Sci Health A 42:97–102Google Scholar
  159. McArthur J, Ravenscroft P, Safiulla S, Thirlwall M (2001) Arsenic in groundwater: testing pollution mechanisms for sedimentary aquifers in Bangladesh. Water Resour Res 37:109–117Google Scholar
  160. McNeill LS, Edwards M (1997) Arsenic removal during precipitative softening. J Environ Eng 123:453–460Google Scholar
  161. Meenakshi S, Viswanathan N (2007) Identification of selective ion-exchange resin for fluoride sorption. J Colloid Interface Sci 308:438–450Google Scholar
  162. Mehta D, Mondal P, George S (2016) Utilization of marble waste powder as a novel adsorbent for removal of fluoride ions from aqueous solution. J Environ Chem Eng 4(1):932–942Google Scholar
  163. Melidis P (2015) Fluoride removal from aluminium finishing wastewater by hydroxyapatite. Environ Process 2:205–213Google Scholar
  164. Mendoza-Castillo DI, Rojas-Mayorga CK, García-Martínez IP, Pérez-Cruz MA, Hernández-Montoya V, Bonilla-Petriciolet A (2015) Removal of heavy metals and arsenic from aqueous solution using textile wastes from denim industry. Int J Environ Sci Technol 12:1657–1668Google Scholar
  165. Milton AH, Smith W, Dear K, Ng J, Sim M, Ranmuthugala G (2007) A Randomised intervention trial to assess two arsenic mitigation options in Bangladesh. J Environ Sci Health A 42:1897–1908Google Scholar
  166. Min LL, Yuan ZH, Zhong LB, Liu Q, Wu RX, Zheng YM (2015) Preparation of chitosan based electrospun nanofiber membrane and its adsorptive removal of arsenate from aqueous solution. Chem Eng 267:132–141Google Scholar
  167. Mittal M, Flora S (2006) Effects of individual and combined exposure to sodium arsenite and sodium fluoride on tissue oxidative stress, arsenic and fluoride levels in male mice. Chem Biol Interact 162:128–139Google Scholar
  168. Mkandawire M, Dudel EG (2005) Accumulation of arsenic in Lemna gibba L. (duckweed) in tailing waters of two abandoned uranium mining sites in Saxony, Germany. Sci Total Environ 336:81–89Google Scholar
  169. Mohan D, Pittman CU Jr (2007) Arsenic removal from water/wastewater using adsorbents: a critical review. J Hazard Mater 142:1–53Google Scholar
  170. Mohan D, Singh KP, Singh VK (2008) Wastewater treatment using low cost activated carbons derived from agricultural by products a case study. J Hazard Mater 152:1045–1053Google Scholar
  171. Mohapatra M, Anand S, Mishra B, Giles DE, Singh P (2009) Review of fluoride removal from drinking water. J Environ Manag 91:67–77Google Scholar
  172. Mohseni-Bandpi A, Kakavandi B, Kalantary RR, Azari A, Keramati A (2015) Development of a novel magnetite–chitosan composite for the removal of fluoride from drinking water: adsorption modeling and optimization. RSC Adv 5:73279–73289Google Scholar
  173. Mondal P, Majumder C, Mohanty B (2006) Laboratory based approaches for arsenic remediation from contaminated water: recent developments. J Hazard Mater 137:464–479Google Scholar
  174. Mondal NK, Bhaumik R, Datta JK (2015) Removal of fluoride by aluminum impregnated coconut fiber from synthetic fluoride solution and natural water. Alex Eng 54:1273–1284Google Scholar
  175. Morillo D, Uheida A, Pérez G, Muhammed M, Valiente M (2015) Arsenate removal with 3-mercaptopropanoic acid-coated superparamagnetic iron oxide nanoparticles. J Colloid Interface Sci 438:227–234Google Scholar
  176. Mukherjee A, Sengupta MK, Hossain MA, Ahamed S, Das B, Nayak B (2006) Arsenic contamination in groundwater: a global perspective with emphasis on the Asian scenario. J Health Popul Nutr 24:142–163Google Scholar
  177. Mwangi CK, Mwangi IW, Wanjau RN, Swaleh S, Ram M, Ngila JC (2016) Remediation of fluoride laden water by complexation with triethylamine modified maize tasselsGoogle Scholar
  178. Newman DK, Ahmann D, Morel FM (1998) A brief review of microbial arsenate respiration. Geomicrobiol J 15:255–268Google Scholar
  179. Nguyen CM, Bang S, Cho J, Kim KW (2009) Performance and mechanism of arsenic removal from water by a nanofiltration membrane. Desalination 245:82–94Google Scholar
  180. Nitzsche KS, Lan VM, Trang PTK, Viet PH, Berg M, Voegelin A (2015a) Arsenic removal from drinking water by a household sand filter in Vietnam: effect of filter usage practices on arsenic removal efficiency and microbiological water quality. Sci Total Environ 502:526–536Google Scholar
  181. Nitzsche KS, Weigold P, Lösekann-Behrens T, Kappler A, Behrens S (2015b) Microbial community composition of a household sand filter used for arsenic, iron, and manganese removal from groundwater in Vietnam. Chemosphere 138:47–59Google Scholar
  182. Nordstrom DK, Alpers CN (1999) Negative pH, efflorescent mineralogy, and consequences for environmental restoration at the Iron Mountain Superfund site, California. Proc Natl Acad Sci 96:3455–3462Google Scholar
  183. Oguz E (2005) Adsorption of fluoride on gas concrete materials. J Hazard Mater 117:227–233Google Scholar
  184. Oremland RS, Stolz JF (2003) The ecology of arsenic. Science 300:939–944Google Scholar
  185. Ouzounis K, Katsoyiannis I, Zouboulis A, Mitrakas M (2015) Is the coagulation-filtration process with Fe(III) efficient for As(III) removal from groundwaters. Sep Sci Technol 50:1587–1592Google Scholar
  186. Öztel MD, Akbal F, Altaş L (2015a) Arsenite removal by adsorption onto iron oxide-coated pumice and sepiolite. Environ Earth Sci 73:4461–4471Google Scholar
  187. Öztel MD, Akbal F, Altaş L (2015b) Arsenite removal by adsorption onto iron oxide-coated pumice and sepiolite. Environ Earth Sci 73:4461–4471Google Scholar
  188. Padungthon S, German M, Wiriyathamcharoen S, SenGupta AK (2015) Polymeric anion exchanger supported hydrated Zr(IV) oxide nanoparticles: a reusable hybrid sorbent for selective trace arsenic removal. React Funct Polym 93:84–94Google Scholar
  189. Parmar S, Singh V (2015) Phytoremediation approaches for heavy metal pollution: a review. J Plant Sci Res 2:139Google Scholar
  190. Parmar HS, Patel JB, Sudhakar P, Koshy V (2006) Removal of fluoride from water with powdered corn cobs. J Environ Sci Eng 48:135–138Google Scholar
  191. Pokhrel D, Viraraghavan T (2006) Arsenic removal from an aqueous solution by a modified fungal biomass. Water Res 40:549–552Google Scholar
  192. Pokhrel D, Viraraghavan T (2008) Arsenic removal from an aqueous solution by modified A. niger biomass: batch kinetic and isotherm studies. J Hazard Mater 150:818–825Google Scholar
  193. Pokhrel D, Viraraghavan T, Braul L (2005) Evaluation of treatment systems for the removal of arsenic from groundwater. Pract Period Hazard Toxic Radioact Waste Manag 9:152–157Google Scholar
  194. Pokhrel D, Bhandari B, Viraraghavan T (2009) Arsenic contamination of groundwater in the Terai region of Nepal: an overview of health concerns and treatment options. Environ Int 35:157–161Google Scholar
  195. Polya D, Gault A, Diebe N, Feldman P, Rosenboom J, Gilligan E (2005) Arsenic hazard in shallow Cambodian groundwaters. Mineral Mag 69:807–823Google Scholar
  196. Popat K, Anand P, Dasare B (1994) Selective removal of fluoride ions from water by the aluminium form of the aminomethylphosphonic acid-type ion exchanger. React Polym 23:23–32Google Scholar
  197. Prabhu SM, Meenakshi S (2015) A dendrimer-like hyper branched chitosan beads toward fluoride adsorption from water. Int J Biol Macromol 78:280–286Google Scholar
  198. Qi J, Zhang G, Li H (2015) Efficient removal of arsenic from water using a granular adsorbent: Fe–Mn binary oxide impregnated chitosan bead. Biores Technol 193:243–249Google Scholar
  199. Qiao J, Cui Z, Sun Y, Hu Q, Guan X (2014) Simultaneous removal of arsenate and fluoride from water by Al–Fe (hydr) oxides. Front Environ Sci Eng 8:169–179Google Scholar
  200. Rasool A, Xiao T, Farooqi A, Shafeeque M, Liu Y, Kamran MA, Katsoyiannis IA, Eqani SAMAS (2016a) Quality of tube well water intended for irrigation and human consumption with special emphasis on arsenic contamination at the area of Punjab, Pakistan. Environ Geochem Health 1–17Google Scholar
  201. Rasool A, Farooqi A, Xiao T, Masood S, Kamran MA (2016b) Elevated levels of arsenic and trace metals in drinking water of Tehsil Mailsi, Punjab, Pakistan. J Geochem Explor 169:89–99Google Scholar
  202. Ravančić ME, Habuda-Stanić M (2015) Equilibrium and kinetics studies for the adsorption of fluoride onto commercial activated carbons using fluoride ion-selective electrode. Int Electrochem Sci 10:8137–8149Google Scholar
  203. Riahi F, Bagherzadeh M, Hadizadeh Z (2015) Modification of Fe3O4 superparamagnetic nanoparticles with zirconium oxide; preparation, characterization and its application toward fluoride removal. RSC Adv 5:72058–72068Google Scholar
  204. Rittle KA, Drever JI, Colberg PJ (1995) Precipitation of arsenic during bacterial sulfate reduction. Geomicrobiol J 13:1–11Google Scholar
  205. Rojas-Mayorga CK, Silvestre-Albero J, Aguayo-Villarreal IA, Mendoza-Castillo D, Bonilla-Petriciolet A (2015) A new synthesis route for bone chars using CO2 atmosphere and their application as fluoride adsorbents. Microporous Mesoporous Mater 209:38–44Google Scholar
  206. Romero L, Alonso H, Campano P, Fanfani L, Cidu R, Dadea C (2003) Arsenic enrichment in waters and sediments of the Rio Loa (Second Region, Chile). Appl Geochem 18:1399–1416Google Scholar
  207. Rowland HA, Omoregie EO, Millot R, Jimenez C, Mertens J, Baciu C (2011) Geochemistry and arsenic behaviour in groundwater resources of the Pannonian Basin (Hungary and Romania). Appl Geochem 26:1–17Google Scholar
  208. Ruiz-Payan A, Ortiz M, Duarte-Gardea M (2005) Determination of fluoride in drinking water and in urine of adolescents living in three counties in Northern Chihuahua Mexico using a fluoride ion selective electrode. Microchemical 81:19–22Google Scholar
  209. Sahoo PK, Kim K (2013) A review of the arsenic concentration in paddy rice from the perspective of geoscience. Geoscience 17(1):107–122Google Scholar
  210. Sancha AM (2006) Review of coagulation technology for removal of arsenic: case of Chile. J Health Popul Nutr 24:267Google Scholar
  211. Sánchez J, Butter B, Rivas BL, Basáez L, Santander P (2015) Electrochemical oxidation and removal of arsenic using water-soluble polymers. J Appl Electrochem 45:151–159Google Scholar
  212. Santini JM, Sly LI, Wen A, Comrie D, Wulf-Durand PD, Macy JM (2002) New arsenite-oxidizing bacteria isolated from australian gold mining environments-phylogenetic relationships. Geomicrobiology 19:67–76Google Scholar
  213. Saqib ANS, Waseem A, Khan AF, Mahmood Q, Khan A, Habib A et al (2013) Arsenic bioremediation by low cost materials derived from Blue Pine (Pinus wallichiana) and Walnut (Juglans regia). Ecol Eng 51:88–94Google Scholar
  214. Sathish RS, Raju N, Raju G, Nageswara Rao G, Kumar KA, Janardhana C (2007) Equilibrium and kinetic studies for fluoride adsorption from water on zirconium impregnated coconut shell carbon. Sep Sci Technol 42:769–788Google Scholar
  215. Schreiber M, Simo J, Freiberg P (2000) Stratigraphic and geochemical controls on naturally occurring arsenic in groundwater, eastern Wisconsin, USA. Hydrogeology 8:161–176Google Scholar
  216. Sehaqui H, Mautner A, de Larraya UP, Pfenninger N, Tingaut P, Zimmermann T (2016) Cationic cellulose nanofibers from waste pulp residues and their nitrate, fluoride, sulphate and phosphate adsorption properties. Carbohydr Polym 135:334–340Google Scholar
  217. Sevcenco A-M, Paravidino M, Vrouwenvelder JS, Wolterbeek HT, van Loosdrecht MC, Hagen WR (2015) Phosphate and arsenate removal efficiency by thermostable ferritin enzyme from Pyrococcus furiosus using radioisotopes. Water Res 76:181–186Google Scholar
  218. Shih YJ, Huang RL, Huang YH (2015) Adsorptive removal of arsenic using a novel akhtenskite coated waste goethite. J Clean Prod 87:897–905Google Scholar
  219. Singh TP, Majumder C (2015) Removal of fluoride from industrial waste water by using living plant (Ipomoea aquatica). Meteorites 28:30Google Scholar
  220. Sivabalan R, Rengaraj S, Arabindoo B, Murugesan V (2003) Cashewnut sheath carbon: a new sorbent for defluoridation of water. Ind J Chem Technol 10:217–222Google Scholar
  221. Sklari S, Pagana A, Nalbandian L, Zaspalis V (2015) Ceramic membrane materials and process for the removal of As(iii)/As(v) ions from water. J Water Process Eng 5:42–47Google Scholar
  222. Smedley P, Kinniburgh D (2002) A review of the source, behaviour and distribution of arsenic in natural waters. Appl Geochem 17:517–568Google Scholar
  223. Song K, Kim W, Suh CY, Shin D, Ko KS, Ha K (2013) Magnetic iron oxide nanoparticles prepared by electrical wire explosion for arsenic removal. Powder Technol 246:572–574Google Scholar
  224. Stüben D, Berner Z, Chandrasekharam D, Karmakar J (2003) Arsenic enrichment in groundwater of West Bengal, India: geochemical evidence for mobilization of As under reducing conditions. Appl Geochem 18:1417–1434Google Scholar
  225. Suriyaraj S, Bhattacharyya A, Selvakumar R (2015) Hybrid Al2O3/bio-TiO2 nanocomposite impregnated thermoplastic polyurethane (TPU) nanofibrous membrane for fluoride removal from aqueous solutions. RSC Adv 5:26905–26912Google Scholar
  226. Sylvester P, Westerhoff P, Möller T, Badruzzaman M, Boyd O (2007) A hybrid sorbent utilizing nanoparticles of hydrous iron oxide for arsenic removal from drinking water. Environ Eng Sci 24:104–112Google Scholar
  227. Taleb K, Markovski J, Milosavljević M, Marinović-Cincović M, Rusmirović J, Ristić M (2015) Efficient arsenic removal by cross-linked macroporous polymer impregnated with hydrous iron oxide: material performance. Chem Eng 279:66–78Google Scholar
  228. Tang D, Zhang G (2016) Efficient removal of fluoride by hierarchical Ce–Fe bimetal oxides adsorbent: thermodynamics, kinetics and mechanism. Chem Eng 283:721–729Google Scholar
  229. Teimouri A, Nasab SG, Habibollahi S, Fazel-Najafabadi M, Chermahini AN (2015) Synthesis and characterization of a chitosan/montmorillonite/ZrO2 nanocomposite and its application as an adsorbent for removal of fluoride. RSC Adv 5:6771–6781Google Scholar
  230. Teixeira MC, Ciminelli VS (2005) Development of a biosorbent for arsenite: structural modeling based on X-ray spectroscopy. Environ Sci Technol 39:895–900Google Scholar
  231. Thakre D, Rayalu S, Kawade R, Meshram S, Subrt J, Labhsetwar N (2010) Magnesium incorporated bentonite clay for defluoridation of drinking water. J Hazard Mater 180:122–130Google Scholar
  232. Thirunavukkarasu O, Viraraghavan T, Subramanian K (2003) Arsenic removal from drinking water using granular ferric hydroxide. Water Sa 29:161–170Google Scholar
  233. Tokunaga S, Wasay SA, Park SW (1997) Removal of arsenic (V) ion from aqueous solutions by lanthanum compounds. Water Sci Technol 35:71–78Google Scholar
  234. Tor A, Danaoglu N, Arslan G, Cengeloglu Y (2009) Removal of fluoride from water by using granular red mud: batch and column studies. J Hazard Mater 164:271–278Google Scholar
  235. Tournassat C, Charlet L, Bosbach D, Manceau A (2002) Arsenic(III) oxidation by birnessite and precipitation of manganese(II) arsenate. Environ Sci Technol 36:493–500Google Scholar
  236. Tressaud A (2006) Fluorine and the environment: agrochemicals, archaeology, green chemistry and water, vol 2. Elsevier, AmsterdamGoogle Scholar
  237. Trois C, Cibati A (2015) South African sands as a low cost alternative solution for arsenic removal from industrial effluents in permeable reactive barriers: column tests. Chem Eng 259:981–989Google Scholar
  238. Turner BD, Binning P, Stipp S (2005) Fluoride removal by calcite: evidence for fluorite precipitation and surface adsorption. Environ Sci Technol 39:9561–9568Google Scholar
  239. Twidwell L, Robins R, Hohn J (2005) The removal of arsenic from aqueous solution by coprecipitation with iron(III). In: Reddy RG, Ramachandran V (eds) Proceedings arsenic metallurgy: fundamentals and applications, pp 3–24Google Scholar
  240. Ungureanu G, Santos S, Boaventura R, Botelho C (2015) Arsenic and antimony in water and wastewater: overview of removal techniques with special reference to latest advances in adsorption. J Environ Manag 151:326–342Google Scholar
  241. Van Vinh N, Zafar M, Behera S, Park H-S (2015) Arsenic(III) removal from aqueous solution by raw and zinc-loaded pine cone biochar: equilibrium, kinetics, and thermodynamics studies. Int J Environ Sci Technol 12:1283–1294Google Scholar
  242. Vences-Alvarez E, Velazquez-Jimenez LH, Chazaro-Ruiz LF, Diaz-Flores PE, Rangel-Mendez JR (2015) Fluoride removal in water by a hybrid adsorbent lanthanum–carbon. J Colloid Interface Sci 455:194–202Google Scholar
  243. Violante A, Gaudio SD (2007) Coprecipitation of arsenate with metal oxides. 2. Nature, mineralogy, and reactivity of iron(III) precipitates. Environ Sci Technol 41:8275–8280Google Scholar
  244. Violante A, Pigna M (2009) Coprecipitation of arsenate with metal oxides. 3. Nature, mineralogy, and reactivity of iron(III): aluminum precipitates. Environ Sci Technol 43:1515–1521Google Scholar
  245. Violante A, Ricciardella M (2006) Coprecipitation of arsenate with metal oxides: nature, mineralogy, and reactivity of aluminum precipitates. Environ Sci Technol 40:4961–4967Google Scholar
  246. Viswanathan N, Meenakshi S (2009) Role of metal ion incorporation in ion exchange resin on the selectivity of fluoride. J Hazard Mater 162:920–930Google Scholar
  247. Vithanage M, Bhattacharya P (2015) Fluoride in the environment: sources, distribution and defluoridation. Environ Chem Lett 13:131–147Google Scholar
  248. Vivek Vardhan C, Srimurali M (2016) Defluoridation of drinking water using a novel sorbent: lanthanum-impregnated green sand. Desalin Water Treat 57:202–212Google Scholar
  249. Vu TA, Le GH, Dao CD, Dang LQ, Nguyen KT, Nguyen QK (2015) Arsenic removal from aqueous solutions by adsorption using novel MIL-53 (Fe) as a highly efficient adsorbent. RSC Adv 5:5261–5268Google Scholar
  250. Waghmare SS, Arfin T (2015) Fluoride removal from water by various techniques: review. Int J Innov Sci Eng Technol 2:560–571Google Scholar
  251. Waghmare SS, Arfin T, Manwar N, Lataye DH, Labhsetwar N, Rayalu S (2015) Preparation and characterization of polyalthia longifolia based alumina as a novel adsorbent for removing fluoride from drinking water. Asian J Adv Basic Sci 4:12–24Google Scholar
  252. Wang S, Zhao X (2009) On the potential of biological treatment for arsenic contaminated soils and groundwater. J Environ Manag 90:2367–2376Google Scholar
  253. Wang L, Condit WE, Chen AS, Sorg TJ (2004) Technology selection and system design US EPA arsenic removal technology demonstration program round 1: National Risk Management Research Laboratory, Office of Research and Development, US Environmental Protection AgencyGoogle Scholar
  254. Wang SG, Ma Y, Shi YJ, Gong WX (2009) Defluoridation performance and mechanism of nano-scale aluminum oxide hydroxide in aqueous solution. J Chem Technol Biotechnol 84:1043–1050Google Scholar
  255. Wang J, Kang D, Yu X, Ge M, Chen Y (2015a) Synthesis and characterization of Mg–Fe–La trimetal composite as an adsorbent for fluoride removal. Chem Eng 264:506–513Google Scholar
  256. Wang S, Gao B, Zimmerman AR, Li Y, Ma L, Harris WG (2015b) Removal of arsenic by magnetic biochar prepared from pinewood and natural hematite. Biores Technol 175:391–395Google Scholar
  257. Wen Z, Dai C, Zhu Y, Zhang Y (2015) Arsenate removal from aqueous solutions using magnetic mesoporous iron manganese bimetal oxides. RSC Adv 5:4058–4068Google Scholar
  258. Williams M, Fordyce F, Paijitprapapon A, Charoenchaisri P (1996) Arsenic contamination in surface drainage and groundwater in part of the southeast Asian tin belt, Nakhon Si Thammarat Province, southern Thailand. Environ Geol 27:16–33Google Scholar
  259. Xie X, Ellis A, Wang Y, Xie Z, Duan M, Su C (2009) Geochemistry of redox-sensitive elements and sulfur isotopes in the high arsenic groundwater system of Datong Basin, China. Sci Total Environ 407:3823–3835Google Scholar
  260. Xiong X, Liu J, He W, Xia T, He P, Chen X (2007) Dose-effect relationship between drinking water fluoride levels and damage to liver and kidney functions in children. Environ Res 103:112–116Google Scholar
  261. Yadav AK, Kaushik C, Haritash AK, Kansal A, Rani N (2006) Defluoridation of groundwater using brick powder as an adsorbent. J Hazard Mater 128:289–293Google Scholar
  262. Yao R, Meng F, Zhang L, Ma D, Wang M (2009) Defluoridation of water using neodymium-modified chitosan. J Hazard Mater 165:454–460Google Scholar
  263. Yin H, Kong M, Tang W (2015a) Removal of fluoride from contaminated water using natural calcium-rich attapulgite as a low-cost adsorbent. Water Air Soil Pollut 226:1–11Google Scholar
  264. Yin H, Kong M, Tang W (2015b) Removal of fluoride from contaminated water using natural calcium-rich attapulgite as a low-cost adsorbent. Water Air Soil Pollut 226:1–11Google Scholar
  265. Yu L, Ma Y, Ong CN, Xie J, Liu Y (2015) Rapid adsorption removal of arsenate by hydrous cerium oxide–graphene composite. RSC Adv 5:64983–64990Google Scholar
  266. Zazouli MA, Mahvi AH, Mahdavi Y, Balarakd D, Sari T (2015) Isothermic and kinetic modeling of fluoride removal from water by means of the natural biosorbents sorghum and canola. Fluoride 48:37–44Google Scholar
  267. Zehhaf A, Benyoucef A, Quijada C, Taleb S, Morallón E (2015) Algerian natural montmorillonites for arsenic(III) removal in aqueous solution. Int J Environ Sci Technol 12:595–602Google Scholar
  268. Zhang J, Zhu YG, Zeng DL, Cheng WD, Qian Q, Duan GL (2008) Mapping quantitative trait loci associated with arsenic accumulation in rice (Oryza sativa). New Phytol 177:350–356Google Scholar
  269. Zhao X, Wang J, Wu F, Wang T, Cai Y, Shi Y (2010) Removal of fluoride from aqueous media by Fe3O4@ Al (OH)3 magnetic nanoparticles. J Hazard Mater 173:102–109Google Scholar
  270. Zhou Y, Yu C, Shan Y (2004) Adsorption of fluoride from aqueous solution on La3+ impregnated cross-linked gelatin. Sep Purif Technol 36:89–94Google Scholar
  271. Zhu J, Lin X, Wu P, Zhou Q, Luo X (2015) Fluoride removal from aqueous solution by Al(III)–Zr(IV) binary oxide adsorbent. Appl Surf Sci 357:91–100Google Scholar
  272. Zouboulis AI, Katsoyiannis IA (2005) Recent advances in the bioremediation of arsenic-contaminated groundwaters. Environ Int 31:213–219Google Scholar

Copyright information

© Springer International Publishing Switzerland 2016

Authors and Affiliations

  • Sadia Bibi
    • 1
    • 2
    • 5
  • Muhammad Aqeel Kamran
    • 3
  • Jawairia Sultana
    • 4
  • Abida Farooqi
    • 5
    Email author
  1. 1.Key Laboratory of Tibetan environmental Changes and Land surface Processes, Institute of Tibetan Plateau ResearchChinese Academy of SciencesBeijingPeople’s Republic of China
  2. 2.University of Chinese Academy of SciencesBeijingPeople’s Republic of China
  3. 3.State Key Laboratory of Soil and Sustainable Agriculture, Institute of Soil ScienceChinese Academy of SciencesNanjingPeople’s Republic of China
  4. 4.Ecoinformatics and Watershed Ecology LaboratoryUniversity of AdelaideAdelaideAustralia
  5. 5.Environmental hydro geochemistry laboratory, Department of Environmental SciencesQuaid-i-Azam UniversityIslamabadPakistan

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