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Environmental Chemistry Letters

, Volume 13, Issue 3, pp 341–346 | Cite as

Efficient lead sorption from wastewater by carbon nanofibers

  • Yehya M. Ahmed
  • Abdullah Al-Mamun
  • Ma’an Fahmi R. Al Khatib
  • Ahmad Tariq Jameel
  • Mohammed Abdul Hakeem Abdul Rahman AlSaadi
Original Paper

Abstract

Wastewater from many industries contains toxic metal ions, which should be removed before water is released into the environment. Many adsorbents have been developed to remove metals, but their efficiency should be improved by, e.g., increasing surface area. Here, we tested the use of carbon nanofibers synthesized on the surface of activated carbon, to remove lead ions (Pb2+). We studied the effect of carbon nanofiber dose, pH, contact time and agitation speed on the sorption capacity. The best conditions were with nanofiber dose of 0.25 g/L, pH of 5.5, contact time of 60 min and agitation speed of 200 rpm. The nanocomposite product was also used for the removal of lead from industrial wastewater. We also found a successful removal of 67 % of lead ions from semiconductor wastewater sample.

Keywords

Powdered activated carbon Carbon nanofibers Optimization Sorption capacity Semiconductor industrial wastewater 

Notes

Acknowledgments

The authors are grateful to The Ministry of Higher Education, Government of Malaysia, for funding this project by the Fundamental Research Grant Scheme with Grant No. FRGS 0106-42 administrated by the Ministry.

References

  1. Abdel-Ghani NT, Elchaghaby GA (2007) Influence of operating conditions on the removal of Cu, Zn, Cd and Pb ions from wastewater by adsorption. Int J Environ Sci Technol 4:451–456CrossRefGoogle Scholar
  2. Acharya J, Sahu JN, Mohanty CR, Meikap BC (2009) Removal of lead (II) from wastewater by activated carbon developed from Tamarind Wood by zinc chloride activation. Chem Eng J 149:249–262CrossRefGoogle Scholar
  3. Ahmed YM, Al-Mamun AA, Muyibi SA, Al-Khatib MFR, Jameel AT, AlSaadi MA (2009) The formation of carbon nanofibers on powdered activated carbon impregnated with nickel. AIP Conf Proc 1136(1):519–522CrossRefGoogle Scholar
  4. Alam M (2009) The factors affecting the performance of activated carbon prepared from oil palm empty fruit bunches for adsorption of phenol. Chem Eng J 155(1–2):191–198CrossRefGoogle Scholar
  5. Alam Z, Muyibi S, Toramae J (2007) Statistical optimization of adsorption processes for removal of 2, 4-dichlorophenol by activated carbon derived from oil palm empty fruit bunches. J Environ Sci 19(6):674–677CrossRefGoogle Scholar
  6. Allen T (1997) Particle size measurement, 5th edn. Chapman & Hall, HockessinGoogle Scholar
  7. Ameen E, Muyibi S, Alam M, Kabashi N, Abdkarim M (2010) Preparation and characterization of powdered activated carbon from empty fruit bunch. Southeast Asian Water Environ 4:147Google Scholar
  8. Anwar J, Shafique U, Zaman W, Salman M, Dar A, Anwar S (2010) Removal of Pb(II) and Cd(II) from water by adsorption on peels of banana. Bioresour Technol 101:1752–1755CrossRefGoogle Scholar
  9. Chen C, Wang X (2006) Adsorption of Ni (II) from aqueous solution using oxidized multiwall carbon nanotubes. Ind Eng Chem Res 45(26):9144–9149CrossRefGoogle Scholar
  10. Chen CW, Kao CM, Chen CF, Dong CD (2007) Distribution and accumulation of heavy metals in the sediments of Kaohsiung Harbor, Taiwan. Chemosphere 66:1431–1440CrossRefGoogle Scholar
  11. Cooney DO (1999) Adsorption design for wastewater treatment, 1st edn. CRC Press, Boca RatonGoogle Scholar
  12. Deans JR, Dixon BG (1992) Uptake of Pb2+ and Cu2+ by novel biopolymers. Water Res 26:469–472CrossRefGoogle Scholar
  13. Fan Y, Cheng H, Wei Y, Su G, Shen Z (2000) Tailoring the diameters of vapor-grown carbon nanofibers. Carbon 38:921–927CrossRefGoogle Scholar
  14. Faur-Brasquet C, Reddad Z, Kadirvelu K, Cloirec PL (2002) Modeling the adsorption of metal ions (Cu2+, Ni2+, Pb2+) onto ACCs using surface complexation models. Appl Surf Sci 196:356–365CrossRefGoogle Scholar
  15. Gueu S, Yao B, Adouby K, Ado G (2007) Kinetics and thermodynamics study of lead adsorption on to activated carbons from coconut and seed hull of the palm tree. Int J Environ Sci Technol 4(1):11–17CrossRefGoogle Scholar
  16. Gundogdu A, Ozdes D, Duran C, Bulut VN, Soylak M, Senturk HB (2009) Biosorption of Pb(II) ions from aqueous solution by pine bark (Pinusbrutia ten). Chem Eng J 153:62–69CrossRefGoogle Scholar
  17. Imamoglu M, Tekir O (2006) Removal of copper (II) and lead (II) ions from aqueous solutions by adsorption on activated carbon from a new precursor hazelnut husks. Desalination 228:108–113CrossRefGoogle Scholar
  18. Issabayeva G, Aroua MK, Sulaiman NMN (2006) Removal of lead from aqueous solutions on palm shell activated carbon. Bioresour Technol 97:2350–2355CrossRefGoogle Scholar
  19. Kuo C, Lin H (2009) Adsorption of aqueous cadmium (II) onto modified multi-walled carbon nanotubes following microwave/chemical treatment. Desalination 249(2):792–796CrossRefGoogle Scholar
  20. Li K, Wang X (2009) Adsorptive removal of Pb(II) by activated carbon prepared from Spartinaalterni flora: equilibrium, kinetics and thermodynamics. Bioresour Technol 100:2810–2815CrossRefGoogle Scholar
  21. Li YH, Wang S, Wei J, Zhang X, Xu C, Luan Z, Wu D, Wei B (2002) Lead adsorption on carbon nanotubes. Chem Phys Lett 357:263–266CrossRefGoogle Scholar
  22. Li Y, Ding J, Luan Z, Di Z, Zhu Y, Xu C (2003) Competitive adsorption of Pb2+, Cu2+ and Cd2+ ions from aqueous solutions by multiwalled carbon nanotubes. Carbon 41(14):2787–2792CrossRefGoogle Scholar
  23. Machida M, Yamazaki R, Aikawa M, Tatsumoto H (2005) Role of minerals in carbonaceous adsorbents for removal of Pb(II) ions from aqueous solution. Sep Purif Technol 46:88–94CrossRefGoogle Scholar
  24. Mamun AA, Ma’an FR, Zahirah AK, Yehya MA, Mohammed ARS, Alam MZ, Muyibi SA, Faris IA, Azni I (2009) Optimization of arsenic adsorption from water by carbon nanofibers grown on powdered activated carbon impregnated with nickel. J Appl Sci 9:3180–3183CrossRefGoogle Scholar
  25. Mamun AA, Ahmed YM, Muyibi SA, Al-Khatib MFR, Jameel AT, AlSaadi MA (2013) Synthesis of carbon nanofibers on impregnated powdered activated carbon as cheap substrate. Arabian J Chem (in press)Google Scholar
  26. Meena AK, Kadirvelu K, Mishraa GK, Rajagopal C, Nagar PN (2008) Adsorption of Pb(II) and Cd(II) metal ions from aqueous solutions by mustard husk. J Hazard Mater 150:619–625CrossRefGoogle Scholar
  27. Nadeem R, Ansari TM, Akhtar K, Khalid M (2009) Pb(II) sorption by pyrolysed Pongamia pinnata pods carbon (PPPC). Chem Eng J 152:54–63CrossRefGoogle Scholar
  28. Okoro IA, Ejike EN (2007) Sorption models of Pb(II) removal from aqueous solution using common edible fruit wastes. Eur J Sci Res 17:270–276Google Scholar
  29. Randhawa NS, Murmu N, Tudu S, Sau DC (2014) Iron oxide waste to clean arsenic contaminated water. Environ Chem Lett 12(4):517–522CrossRefGoogle Scholar
  30. Rao GP, Lu C, Su F (2007) Sorption of divalent metal ions from aqueous solution by carbon nanotubes: a review. Sep Purif Technol 58:224–231CrossRefGoogle Scholar
  31. Ruparelia JP, Duttagupta SP, Chatterjee AK, Mukherji S (2008) Potential of carbon nanomaterials for removal of heavy metals from water. Desalination 232:145–156CrossRefGoogle Scholar
  32. Sekar M, Sakthi V, Rengaraj S (2004) Kinetics equilibrium adsorption study of lead(II) onto activated carbon prepared from coconut shell. J Colloid Interface Sci 279:307–313CrossRefGoogle Scholar
  33. Singh CK, Sahu JN, Mahalik KK, Mohanty CR, Mohan RB, Meikap BC (2008) Studies on the removal of Pb(II) from wastewater by activated carbon developed from Tamarind wood activated with sulphuric acid. J Hazard Mater 153:221–228CrossRefGoogle Scholar
  34. Wu D, Li Y, Shi Y, Fang Z, Chang L (2000) Effects of the calcinations conditions on the mechanical properties of PCoMo/Al2O3 hydrotreating catalyst. Chem Eng Sci 57:3495–3504CrossRefGoogle Scholar
  35. Wu CH, Shr JF, Wu CF, Hsieh CT (2008) Adsorption energy distribution of carbon tetrachloride on carbon nanofiber arrays prepared by template synthesis. Phys E 40:814–821CrossRefGoogle Scholar
  36. Xu D, Tan X, Chen C, Wang X (2008) Removal of Pb(II) from aqueous solution by oxidized multiwalled carbon nanotubes. J Hazard Mater 154(1–3):407–416CrossRefGoogle Scholar
  37. Zhang MK, Liu ZY, Wang H (2010) Use of single extraction methods to predict bioavailability of heavy metals in polluted soils to rice. Commun Soil Sci Plant Anal 41(7):820–831CrossRefGoogle Scholar

Copyright information

© Springer International Publishing Switzerland 2015

Authors and Affiliations

  1. 1.Department of Civil Engineering, Faculty of Architecture and Built EnvironmentLimkokwing University of Creative TechnologyCyberjayaMalaysia
  2. 2.Nanoscience and Nanotechnology Research Group NANORG, Faculty of EngineeringInternational Islamic University Malaysia (IIUM)Kuala LumpurMalaysia
  3. 3.Department of Chemical Engineering, Faculty of Engineering, Nanotechnology and Catalysts Research Center (NANOCAT)University of MalayaKuala LumpurMalaysia

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