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Metal valorization from the waste produced in the manufacturing of Co/Mo catalysts: leaching and selective precipitation

  • Mohammed F. Hamza
  • Jean-Claude Roux
  • Eric GuibalEmail author
ORIGINAL ARTICLE
  • 82 Downloads

Abstract

Two different strategies have been designed for the acid and alkaline leaching steps of hydrodesulphurization catalysts. Tests have been performed on out-of-range catalysts issued from catalyst manufacturing process. Experimental conditions have been screened for these different processes considering the effects of concentration, temperature, solid/liquid ratio, etc. The best conditions have been used for producing two leachates that were treated by precipitation for recovery of valuable metals such as cobalt and molybdenum. Post-treatments have also been designed for the selective separation of Co from Mo: X-ray diffraction analyses on selective precipitates (as sulfide) confirm the purity of produced materials. Two flow sheets are proposed that allow selectively recovering more than 95% of the valuable metals.

Keywords

Hydrodesulfurization catalyst Co and Mo selective recovery Alkaline leaching Acidic leaching Sulfide precipitation 

Notes

Acknowledgements

Authors acknowledge the financial support of French Government (Institut Français d’Egypte, French Embassy in Egypt) through the fellowship granted to M.F. Hamza.

Supplementary material

10163_2018_811_MOESM1_ESM.docx (4 mb)
Supplementary material 1 (DOCX 4073 KB)

References

  1. 1.
    Mohapatra D, Park KH (2007) Selective recovery of Mo, Co and Al from spent Co/Mo/gamma-Al2O3 catalyst: Effect of calcination temperature. J Environ Sci Health Part A Toxic/Hazard Subst Environ Eng 42(4):507–515CrossRefGoogle Scholar
  2. 2.
    Le H-L, Yamasue E, Okumura H, Ishihara KN (2014) Improving sustainable recovery of metals from waste printed circuit boards by the primary copper smelter process. J Mater Cycles Waste Manag 16(2):298–305CrossRefGoogle Scholar
  3. 3.
    Huang K, Inoue K, Harada H, Kawakita H, Ohto K (2011) Leaching of heavy metals by citric acid from fly ash generated in municipal waste incineration plants. J Mater Cycles Waste Manag 13(2):118–126CrossRefGoogle Scholar
  4. 4.
    Rudnik E, Pierzynka M, Handzlik P (2016) Ammoniacal leaching and recovery of copper from alloyed low-grade e-waste. J Mater Cycles Waste Manag 18(2):318–328CrossRefGoogle Scholar
  5. 5.
    Navarro R, Guzman J, Saucedo I, Revilla J, Guibal E (2007) Vanadium recovery from oil fly ash by leaching, precipitation and solvent extraction processes. Waste Manag (Oxford) 27(3):425–438CrossRefGoogle Scholar
  6. 6.
    Liu J, Qiu ZF, Yang J, Cao LM, Zhang W (2016) Recovery of Mo and Ni from spent acrylonitrile catalysts using an oxidation leaching-chemical precipitation technique. Hydrometallurgy 164:64–70CrossRefGoogle Scholar
  7. 7.
    Pinto ISS, Soares H (2012) Selective leaching of molybdenum from spent hydrodesulphurisation catalysts using ultrasound and microwave methods. Hydrometallurgy 129:19–25CrossRefGoogle Scholar
  8. 8.
    Barik SP, Park KH, Parhi PK, Park JT (2012) Direct leaching of molybdenum and cobalt from spent hydrodesulphurization catalyst with sulphuric acid. Hydrometallurgy 111:46–51CrossRefGoogle Scholar
  9. 9.
    Szymczycha-Madeja A (2011) Kinetics of Mo, Ni, V and Al leaching from a spent hydrodesulphurization catalyst in a solution containing oxalic acid and hydrogen peroxide. J Hazard Mater 186(2–3):2157–2161CrossRefGoogle Scholar
  10. 10.
    Ruiz V, Meux E, Schneider M, Georgeaudl V (2011) Hydrometallurgical treatment for valuable metals recovery from spent CoMo/Al2O3 catalyst. 2. Oxidative leaching of an unroasted catalystc using H2O2. Ind Eng Chem Res 50(9):5307–5315CrossRefGoogle Scholar
  11. 11.
    Kim HI, Park KH, Mishra D (2009) Sulfuric acid baking and leaching of spent Co-Mo/Al2O3 catalyst. J Hazard Mater 166(2–3):1540–1544CrossRefGoogle Scholar
  12. 12.
    Lai YC, Lee WJ, Huang KL, Wu CM (2008) Metal recovery from spent hydrodesulfurization catalysts using a combined acid-leaching and electrolysis process. J Hazard Mater 154(1–3):588–594CrossRefGoogle Scholar
  13. 13.
    Wu Y, Wang B, Zhang Q, Li R, Sun C, Wang W (2014) Recovery of rare earth elements from waste fluorescent phosphors: Na2O2 molten salt decomposition. J Mater Cycles Waste Manag 16(4):635–641CrossRefGoogle Scholar
  14. 14.
    Zhang X, Xie Y, Lin X, Li H, Cao H (2013) An overview on the processes and technologies for recycling cathodic active materials from spent lithium-ion batteries. J Mater Cycles Waste Manage 15(4):420–430CrossRefGoogle Scholar
  15. 15.
    Zhang P, Ma Y, Xie F (2013) Impacts of ultrasound on selective leaching recovery of heavy metals from metal-containing waste sludge. J Mater Cycles Waste Manag 15(4):530–538CrossRefGoogle Scholar
  16. 16.
    Pinto ISS, Soares HMVM (2013) Recovery of molybdates from an alkaline leachate of spent hydrodesulphurisation catalyst - proposal of a nearly-closed process. J Cleaner Prod 52:481–487CrossRefGoogle Scholar
  17. 17.
    Alonso F, Ramirez S, Ancheyta J, Mavil M (2008) Alternatives for recovering of metals from heavy hydrocarbons spent hydrotreating catalysts a case of study. Rev Int Contamin Amb 24(2):55–69Google Scholar
  18. 18.
    Zeng L, Cheng CY (2009) A literature review of the recovery of molybdenum and vanadium from spent hydrodesulphurisation catalysts Part I: metallurgical processes. Hydrometallurgy 98(1–2):1–9CrossRefGoogle Scholar
  19. 19.
    Gaballah I, Djona M, Mugica JC, Solozobal R (1994) Valuable metals recovery from spent catalysts by selective chlorination. Resour Conserv Recycl 10(1–2):87–96CrossRefGoogle Scholar
  20. 20.
    Li J, Liang C, Ma C (2015) Bioleaching of gold from waste printed circuit boards by Chromobacterium violaceum. J Mater Cycles Waste Manag 17(3):529–539CrossRefGoogle Scholar
  21. 21.
    Vemic M, Bordas F, Comte S, Guibaud G, Lens PNL, van Hullebusch ED (2016) Recovery of molybdenum, nickel and cobalt by precipitation from the acidic leachate of a mineral sludge. Environ Technol 37(17):2231–2242CrossRefGoogle Scholar
  22. 22.
    Chen T, Lei C, Yan B, Xiao XM (2014) Metal recovery from the copper sulfide tailing with leaching and fractional precipitation technology. Hydrometallurgy 147:178–182CrossRefGoogle Scholar
  23. 23.
    Fernandes A, Afonso JC, Dutra AJB (2013) Separation of nickel(II), cobalt(II) and lanthanides from spent Ni-MH batteries by hydrochloric acid leaching, solvent extraction and precipitation. Hydrometallurgy 133:37–43CrossRefGoogle Scholar
  24. 24.
    Cibati A, Cheng KY, Morris C, Ginige MP, Sahinkaya E, Pagnanelli F, Kaksonen AH (2013) Selective precipitation of metals from synthetic spent refinery catalyst leach liquor with biogenic H2S produced in a lactate-fed anaerobic baffled reactor. Hydrometallurgy 139:154–161CrossRefGoogle Scholar
  25. 25.
    Zhang H, He P-J, Shao L-M, Li X-J (2008) Leaching behavior of heavy metals from municipal solid waste incineration bottom ash and its geochemical modeling. J Mater Cycles Waste Manag 10(1):7–13CrossRefGoogle Scholar
  26. 26.
    Fernandes A, Afonso JC, Dutra AJB (2012) Hydrometallurgical route to recover nickel, cobalt and cadmium from spent Ni-Cd batteries. J Power Sources 220:286–291CrossRefGoogle Scholar
  27. 27.
    Pinto ISS, Sadeghi SM, Izatt NE, Soares H (2015) Recovery of metals from an acid leachate of spent hydrodesulphurization catalyst using molecular recognition technology. Chem Eng Sci 138:353–362CrossRefGoogle Scholar
  28. 28.
    Zawierucha I, Kozlowski C, Malina G (2013) Removal of toxic metal ions from landfill leachate by complementary sorption and transport across polymer inclusion membranes. Waste Manag (Oxford) 33(10):2129–2136CrossRefGoogle Scholar
  29. 29.
    Soukand U, Kangsepp P, Kakum R, Tenno T, Mathiasson L, Hogland W (2010) Selection of adsorbents for treatment of leachate: batch studies of simultaneous adsorption of heavy metals. J Mater Cycles Waste Manag 12(1):57–65CrossRefGoogle Scholar
  30. 30.
    Habashi F (1997) Handbook of extractive metallurgy. Wiley-VCH, WeinheimGoogle Scholar
  31. 31.
    Niemela M, Pitkaaho S, Ojala S, Keiski RL, Peramaki P (2012) Microwave-assisted aqua regia digestion for determining platinum, palladium, rhodium and lead in catalyst materials. Microchem J 101:75–79CrossRefGoogle Scholar
  32. 32.
    Portela L, Grange P, Delmon B (1995) XPS and NO adsorption studies on alumina-supported Co-Mo catalysts sulfided by different procedures. J Catal 156(2):243–254CrossRefGoogle Scholar
  33. 33.
    Valverde IM Jr, Paulino JF, Afonso JC (2008) Hydrometallurgical route to recover molybdenum, nickel, cobalt and aluminum from spent hydrotreating catalysts in sulphuric acid medium. J Hazard Mater 160(2–3):310–317CrossRefGoogle Scholar
  34. 34.
    Erust C, Akcil A, Bedelova Z, Anarbekov K, Baikonurova A, Tuncuk A (2016) Recovery of vanadium from spent catalysts of sulfuric acid plant by using inorganic and organic acids: Laboratory and semi-pilot tests. Waste Manag (Oxford) 49:455–461CrossRefGoogle Scholar
  35. 35.
    Nguyen TH, Lee MS (2015) Development of a hydrometallurgical process for the recovery of calcium molybdate and cobalt oxalate powders from spent hydrodesulphurization (HDS) catalyst. J Cleaner Prod 90:388–396CrossRefGoogle Scholar
  36. 36.
    Aydogan S, Aras A, Ucar G, Erdemoglu M (2007) Dissolution kinetics of galena in acetic acid solutions with hydrogen peroxide. Hydrometallurgy 89(3–4):189–195CrossRefGoogle Scholar
  37. 37.
    Tanda BC, Eksteen JJ, Oraby EA (2018) Kinetics of chalcocite leaching in oxygenated alkaline glycine solutions. Hydrometallurgy 178:264–273CrossRefGoogle Scholar
  38. 38.
    Chander S (1982) Atmospheric-pressure leaching of nickeliferous laterites in acidic media. Trans Indian Inst Met 35(4):366–371MathSciNetGoogle Scholar
  39. 39.
    Terekhov DS, Emmanuel NV (2013) Direct extraction of nickel and iron from laterite ores using the carbonyl process. Miner Eng 54:124–130CrossRefGoogle Scholar
  40. 40.
    Schortmann WE, DeSesa MA (1958) Kinetics of the dissolution of uranium dioxide in carbonate-bicarbonate solutions. In:; National Lead Co., Inc. Raw Materials Development Lab., Winchester, Mass. page(s): 17, Medium: XGoogle Scholar
  41. 41.
    Beverly RG, Charles WD (1958) Pilot Plant alkaline leaching of uranium ores. US Government Printing OfficeGoogle Scholar
  42. 42.
    Sohn HY, Wadsworth ME (1979) Rate processes of extractive metallurgy. Springer US, New YorkCrossRefGoogle Scholar
  43. 43.
    Aly MM, Hamza MF (2013) A Review: studies on uranium removal using different techniques. Overview J Dispers Sci Technol 34(2):182–213CrossRefGoogle Scholar
  44. 44.
    Merritt RC (1971) The Extractive Metallurgy of Uranium. Colorado School of Mines Research Institute, [GoldenGoogle Scholar
  45. 45.
    Ferella F, Ognyanova A, De Michelis I, Taglieri G, Veglio F (2011) Extraction of metals from spent hydrotreating catalysts: Physico-mechanical pre-treatments and leaching stage. J Hazard Mater 192(1):176–185Google Scholar
  46. 46.
    Svehla G (1996) Vogel’s qualitative inorganic analysis. Addison Wesley Longman Ltd, HarlowGoogle Scholar
  47. 47.
    Lewis AE (2010) Review of metal sulphide precipitation. Hydrometallurgy 104(2):222–234CrossRefGoogle Scholar
  48. 48.
    Luther GW, Rickard DT, Theberge S, Olroyd A (1996) Determination of metal (bi)sulfide stability constants of Mn2+, Fe2+, Co2+, Ni2+, Cu2+, and Zn2+ by voltammetric methods. Environ Sci Technol 30(2):671–679CrossRefGoogle Scholar
  49. 49.
    Bhattacharyya D, Jumawan AB, Grieves RB (1979) Separation of toxic heavy metals by sulfide precipitation. Sep Sci Technol 14(5):441–452CrossRefGoogle Scholar
  50. 50.
    Shapiro L (1975) Rapid analysis of silicate, carbonate, and phosphate rocks. In: U.S. Geol. Surv. Bull., Vol. 76, pIII, Report Number 1401, pp. 88Google Scholar
  51. 51.
    Baes CF Jr, Mesmer RE (1976) Hydrolysis of cations. Wiley, New YorkGoogle Scholar

Copyright information

© Springer Japan KK, part of Springer Nature 2018

Authors and Affiliations

  1. 1.C2MA, IMT Mines Ales, Univ. MontpellierAlèsFrance
  2. 2.Nuclear Materials AuthorityCairoEgypt

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