Fast pyrolysis of Vietnamese waste biomass: relationship between biomass composition, reaction conditions, and pyrolysis products, and a strategy to use a biomass mixture as feedstock for bio-oil production

  • Thanh Long Duong
  • Dong Truc Nguyen
  • Huynh Hung My Nguyen
  • Binh Minh Quoc Phan
  • Huu Luong Nguyen
  • Thuan Minh HuynhEmail author


Four types of Vietnamese waste biomass were investigated for bio-oil production using the fast pyrolysis technology. Feedstock chemical composition, product yields, and bio-oil physical properties have been systematically compared. The chemical composition and properties of Vietnamese resources of biomass are similar to those of the other biomass. The experimental results showed that all obtained bio-oils fulfilled the specifications for pyrolysis liquid defined as ASTM D7544-12 Standard. The biomass composition has strong impact on product yields, especially bio-oil formation. Higher contents of the three main components in the feedstock (i.e., cellulose, hemicellulose, and lignin) lead to a higher yield of bio-oil, whereas its high ash content caused a decrease in the bio-oil yield. As a result, the bio-oil yields from feedstock are in the following order: bagasse > corn cob > rice husk > rice straw. In addition, pyrolysis conditions (e.g., temperature and nitrogen flowrate), but not biomass preparation (e.g., material particle size), influence the bio-oil yield and its properties, as well. However, it has been found that this influence for rice husk and rice straw feedstocks is more prominent than for bagasse and corn cob. Finally, a strategy for an efficient usage of various waste resources for future biorefineries was proposed.


Bio-oil Biomass resources Biorefineries Correlation Fast pyrolysis 



Vietnam National Oil and Gas Group and Vietnam Ministry of Industry and Trade are acknowledged for the financial support.


  1. 1.
    Dai L, Fan L, Duan D, Ruan R, Wang Y, Liu Y, Zhou Y, Yu Z, Liu Y, Jiang L (2017) Production of hydrocarbon-rich bio-oil from soapstock via fast microwave-assisted catalytic pyrolysis. J Anal App Pyrolysis 125:356–362. CrossRefGoogle Scholar
  2. 2.
    Phan BMQ, Duong LT, Nguyen VD, Tran BT, Nguyen MHH, Nguyen LH, Nguyen DA, Luu LC (2014) Evaluation of the production potential of bio-oil from Vietnamese biomass resources by fast pyrolysis. Biomass Bioenergy 62:74–81. CrossRefGoogle Scholar
  3. 3.
    Demirbaş A (2001) Biomass resource facilities and biomass conversion processing for fuels and chemicals. Energy Convers Manag 42:1357–1378. CrossRefGoogle Scholar
  4. 4.
    Bridgwater AV (1999) Principles and practice of biomass fast pyrolysis processes for liquids. J Anal Appl Pyrolysis 51:3–22. CrossRefGoogle Scholar
  5. 5.
    Akhtar J, Amin ND (2012) A review on operating parameters for optimum liquid oil yield in biomass pyrolysis. Renew Sustain Energy Rev 16:5101–5109. CrossRefGoogle Scholar
  6. 6.
    Scott DS, Majerski P, Piskorz J, Radlein D (1999) A second look at fast pyrolysis of biomass—the RTI process. J Anal Appl Pyrolysis 51:23–37. CrossRefGoogle Scholar
  7. 7.
    Czernik S, Bridgwater AV (2004) Overview of applications of biomass fast pyrolysis oil. Energy Fuels 18:590–598. CrossRefGoogle Scholar
  8. 8.
    Karr MB (1956) Corn cob absorbent and method of producing the same. 2733145 US PatentsGoogle Scholar
  9. 9.
    ASTM D7544 (2012) Standard specification for pyrolysis liquid biofuel. IHSGoogle Scholar
  10. 10.
    Lehto JO, Solantausta A, Kytö Y, Matti K, David C (2013) Fuel oil quality and combustion of fast pyrolysis bio-oils. VTT. ISBN 978-951-38-7930-3.
  11. 11.
    Elliott DC, Meier D, Oasmaa A, van de Beld B, Bridgwater AV, Marklund M (2017) Results of the international energy agency round robin on fast pyrolysis bio-oil production. Energy Fuels. Google Scholar
  12. 12.
    Fukuda S (2015) Pyrolysis investigation for bio-oil production from various biomass feedstocks in Thailand. Int J Green Energy 12:215–224. CrossRefGoogle Scholar
  13. 13.
    Jenkins BM, Baxter LL, Miles TR Jr, Miles TR (1998) Combustion properties of biomass. Fuel Process Technol 54:17–46. CrossRefGoogle Scholar
  14. 14.
    Demirbas A (2004) Effect of temperature and particle size on bio-char yield from pyrolysis of agricultural residues. J Anal Appl Pyrolysis 72:243–248. CrossRefGoogle Scholar
  15. 15.
    Tsaia WT, Lee MK, Chang YM (2007) Fast pyrolysis of rice husk: product yields and composition. Bioresour Technol 98:22–28. CrossRefGoogle Scholar
  16. 16.
    Worasuwannarak N, Taro S, Wiwut T (2007) Pyrolysis behaviors of rice straw, rice husk, and corncob by TG-MS technique. J Anal Appl Pyrolysis 78:265–271. CrossRefGoogle Scholar
  17. 17.
    Demirbas A (2003) Trace metal concentrations in ashes from various types of biomass species. Energy Sources 25:743–751. CrossRefGoogle Scholar
  18. 18.
    Fahmi R, Bridgwater AV, Donnison I, Yates N, Jones JM (2008) The effect of lignin and inorganic species in biomass on pyrolysis oil yields, quality and stability. Fuel 87:1230–1240. CrossRefGoogle Scholar
  19. 19.
    Nowakowski DJ, Woodbridge CR, Jones JM (2008) Phosphorus catalysis in the pyrolysis behaviour of biomass. J Anal App Pyrolysis 83:197–204. CrossRefGoogle Scholar
  20. 20.
    Venderbosch RH (2015) A critical view on catalytic pyrolysis of biomass. ChemSusChem 8:1306–1316. CrossRefGoogle Scholar
  21. 21.
    Johansson AC, Wiinikka H, Sandström L, Marklund M, Öhrman OGW, Narvesjö J (2016) Characterization of pyrolysis products produced from different Nordic biomass types in a cyclone pilot plant. Fuel Process Tech 146:9–19. CrossRefGoogle Scholar
  22. 22.
    Oasmaa A, Peacocke AOC (2010) Properties and fuel use of biomass derived fast pyrolysis liquids. Julkaisija–Utgivare. ISBN 978-951-38-7384-4.
  23. 23.
    Choi HS, Choi YS, Park HC (2012) Fast pyrolysis characteristics of lignocellulosic biomass with varying reaction conditions. Renew Energy 42:131–135. CrossRefGoogle Scholar
  24. 24.
    Xu R, Ferrante L, Briens C, Berruti F (2011) Bio-oil production by flash pyrolysis of sugarcane residues and post treatments of the aqueous phase. J Anal Appl Pyrolysis 91:263–272. CrossRefGoogle Scholar
  25. 25.
    Ateş F, Pütün E, Pütün AE (2004) Fast pyrolysis of sesame stalk: yields and structural analysis of bio-oil. J Anal Appl Pyrolysis 71:779–790. CrossRefGoogle Scholar
  26. 26.
    Onay O, Kockar OM (2003) Slow, fast and flash pyrolysis of rapeseed. Renew Energy 28:2417–2433. CrossRefGoogle Scholar
  27. 27.
    Park HJ, Dong JI, Jeon JK, Park YK, Yoo KS, Kim SS, Kim J, Kim S (2008) Effects of the operating parameters on the production of bio-oil in the fast pyrolysis of Japanese larch. Chem Eng J 143:124–132. CrossRefGoogle Scholar
  28. 28.
    Scott DS, Piskorz J, Bergougnou MA, Graham R, Overend RP (1988) The role of temperature in the fast pyrolysis of cellulose and wood. Ind Eng Chem Res 27:8–15. CrossRefGoogle Scholar
  29. 29.
    Chan WCR, Kelbon M, Brockett BK (1988) Single-particle biomass pyrolysis: correlations of reaction products with process conditions. Ind Eng Chem Res 27:2261–2275. CrossRefGoogle Scholar
  30. 30.
    Kalgo AS (2011) The development and optimisation of a fast pyrolysis process for bio-oil production. Aston University, BirminghamGoogle Scholar
  31. 31.
    Fuentes ME, Nowakowski DJ, Kubacki ML, Cove JM, Bridgeman TG, Jones JM (2008) Survey of influence of biomass mineral matter in thermochemical conversion of short rotation willow coppice. J Energy Inst 81:234–241. CrossRefGoogle Scholar

Copyright information

© Springer Japan KK, part of Springer Nature 2019

Authors and Affiliations

  • Thanh Long Duong
    • 1
  • Dong Truc Nguyen
    • 1
  • Huynh Hung My Nguyen
    • 1
  • Binh Minh Quoc Phan
    • 1
  • Huu Luong Nguyen
    • 1
  • Thuan Minh Huynh
    • 1
    Email author
  1. 1.Vietnam Petroleum InstituteHo Chi Minh CityViet Nam

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