Recovery of rare-earth elements from neodymium magnets using molten salt electrolysis

SPECIAL FEATURE: ORIGINAL ARTICLE 3rd 3R International Scientific Conference (3rd 3RINCs 2016)

Abstract

Rare-earth elements are used in neodymium magnets, and these elements are critical to Japanese industry. In this study, we focused on the electrochemical behavior of neodymium magnets for the recovery of rare-earth elements using molten salt electrolysis. The influence of the rare-earth elemental composition of the neodymium magnets on their anodic polarization behavior and oxidation mechanism was studied. The use of potentiostatic electrolysis enabled selective leaching of rare-earth elements from neodymium magnets in the potential range from −1.8 to −0.8 V. The oxidation potential limits the oxidation stage, enabling rare-earth elements to be leached from mixed neodymium magnets simultaneously.

Keywords

Rare-earth elements Neodymium magnet Electrochemistry Molten salt 

Notes

Acknowledgements

This work was supported by the Environment Research and Technology Development Fund of the Ministry of the Environment, Japan 3K143005, JSPS KAKENHI Grant No. 24656457, Japan Oil, Gas and Metals National Corporation, the Hori Sciences and Arts Foundation, and the Tokai Foundation for Technology.

References

  1. 1.
    Rabatho JP, Tongamp W, Takasaki Y, Haga K, Shibayama A (2013) Recovery of Nd and Dy from rare earth magnetic waste sludge by hydrometallurgical process. J Mater Cycles Waste Manag 15:171–178CrossRefGoogle Scholar
  2. 2.
    Hoogerstraete TV, Wellens S, Verachtert K, Binnemans K (2013) Removal of transition metals from rare earths by solvent extraction with an undiluted phosphonium ionic liquid: separations relevant to rare-earth magnet recycling. Green Chem 15:919–927CrossRefGoogle Scholar
  3. 3.
    Kikuchi Y, Matsumiya M, Kawakami S (2014) Extraction of rare earth ions from Nd–Fe–B magnet wastes with TBP in tricaprylmethylammonium nitrate. Solv Extr Res Dev Jpn 21:137–145CrossRefGoogle Scholar
  4. 4.
    Itakura T, Sasai R, Itoh H (2006) Resource recovery from Nd–Fe–B sintered magnet by hydrothermal treatment. J Alloy Compd 408–412:1382–1385CrossRefGoogle Scholar
  5. 5.
    Takeda O, Okabe TH, Umetsu Y (2006) Recovery of neodymium from a mixture of magnet scrap and other scrap. J Alloy Compd 408–412:387–390CrossRefGoogle Scholar
  6. 6.
    Okabe TH, Takeda O, Fukuda K, Umetsu Y (2003) Direct extraction and recovery of neodymium metal from magnet scrap. Mater Trans 44:798–801CrossRefGoogle Scholar
  7. 7.
    Sekimoto H, Kubo T, Yamaguchi K (2014) Development of a new recycling process for neodymium permanent magnet using B2O3 flux. J MMIJ 130:494–500 (in Japanese) CrossRefGoogle Scholar
  8. 8.
    Hoshi H, Miyamoto Y, Furusawa K (2014) Technique for separating rare earth elements from R–Fe–B magnets by carbothermal reduction method. J Jpn Inst Met Mater 78:258–266 (in Japanese) CrossRefGoogle Scholar
  9. 9.
    Takeda O, Nakano K, Sato Y (2014) Recycling of rare earth magnet waste by removing rare earth oxide with molten fluoride. Mater Trans 55:334–341CrossRefGoogle Scholar
  10. 10.
    Itoh M, Miura K, Machida K (2009) Novel rare earth recovery process on Nd–Fe–B magnet scrap by selective chlorination using NH4Cl. J Alloy Compd 477:484–487CrossRefGoogle Scholar
  11. 11.
    Saito T, Sato H, Ozawa S, Yu J, Motegi T (2003) The extraction of Nd from waste Nd–Fe–B alloys by the glass slag method. J Alloy Compd 353:189–193CrossRefGoogle Scholar
  12. 12.
    Kamimoto Y, Yoshimura G, Itoh T, Kuroda K, Ichino R (2015) Leaching of rare earth elements from neodymium magnet using electrochemical method. TMRS-J 40:343–346Google Scholar

Copyright information

© Springer Japan 2016

Authors and Affiliations

  1. 1.Green Mobility Research Institute, Institutes of Innovation for Future SocietyNagoya UniversityNagoyaJapan
  2. 2.Graduated School of EngineeringNagoya UniversityNagoyaJapan
  3. 3.Institute of Materials and Systems for SustainabilityNagoya UniversityNagoyaJapan

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