Leaching behavior of heavy metals from municipal solid waste incineration bottom ash and its geochemical modeling

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Abstract

With the increase in the number of municipal solid waste incineration (MSWI) plants constructed in China recently, great attention has been paid to the heavy metal leaching toxicity of MSWI residues. In this study, the effects of various parameters, including extractant, leaching time, liquid-to-solid ratio, leachate pH, and heavy metal content, on the release properties of Cd, Cr, Cu, Ni, Pb, and Zn from MSWI bottom ash were investigated. Partial least-squares analysis was employed to highlight the interrelationships between the factors and response variables. Both experimental research and geochemical modeling using Visual MINTEQ software were conducted to study the pH-dependent leaching behavior of these metals in fresh and weathered bottom ash, considering precipitation/dissolution and surface complexation reactions (adsorption by hydrous ferric oxide and amorphous aluminum oxide/hydroxide). The results showed that leachate pH was the predominant factor influencing heavy metal leachability. The leaching of Cu, Pb, and Zn was mainly controlled by precipitation/dissolution reactions, whereas surface complexation had some effect on the leaching of Cr, Cd, and Ni for certain pH ranges. The modeling results aggreed well with the experimental results.

Key words

Municipal solid waste Bottom ash Heavy metals Leaching Visual MINTEQ modeling Partial least-squares analysis 
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Copyright information

© Springer Japan 2008

Authors and Affiliations

  • Hua Zhang
    • 1
  • Pin-Jing He
    • 1
  • Li-Ming Shao
    • 1
  • Xin-Jie Li
    • 1
  1. 1.State Key Laboratory of Pollution Control and Resources Reuse, College of Environmental Science and EngineeringTongji UniversityShanghaiChina

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